Crystal structure and electrical conductivity of Nd5–xSmxMo3O16 solid solutions
Samarium substitution for neodymium in the Nd 5 Mo 3 O 16 compound has been studied by X-ray diffraction, scanning electron microscopy, and IR spectroscopy. The results demonstrate that fluorite-like Nd 5– x Sm x Mo 3 O 16 solid solutions exist in the range x ≤ 2. The electrical conductivity of the...
Gespeichert in:
| Veröffentlicht in: | Inorganic materials 2015-10, Vol.51 (10), p.1033-1038 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 1038 |
|---|---|
| container_issue | 10 |
| container_start_page | 1033 |
| container_title | Inorganic materials |
| container_volume | 51 |
| creator | Chebyshev, K. A. Get’man, E. I. Pasechnik, L. V. Ardanova, L. I. Korotina, D. V. |
| description | Samarium substitution for neodymium in the Nd
5
Mo
3
O
16
compound has been studied by X-ray diffraction, scanning electron microscopy, and IR spectroscopy. The results demonstrate that fluorite-like Nd
5–
x
Sm
x
Mo
3
O
16
solid solutions exist in the range
x
≤ 2. The electrical conductivity of the solid solutions increases with increasing samarium content in the range
x
= 0–1. Structure refinement by the Rietveld method for Nd
4
SmMo
3
O
16
has shown that the Nd(2) coordination polyhedron in this solid solution is distorted more severely than that in the structure of Nd
5
Mo
3
O
16
. |
| doi_str_mv | 10.1134/S0020168515100040 |
| format | Article |
| fullrecord | <record><control><sourceid>springer</sourceid><recordid>TN_cdi_springer_journals_10_1134_S0020168515100040</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10_1134_S0020168515100040</sourcerecordid><originalsourceid>FETCH-LOGICAL-s1130-ab1e4375b20a993a3b3fc1d08f36cf7731bd76b31f4a560bb8fd7265ea254e983</originalsourceid><addsrcrecordid>eNplkEtOwzAQhi0EEqFwAHa5QGAmjh1niSpeUqFChXXkJ3IVYmQnqN1xB27ISUgEOzYzi-_XP6OPkHOEC0RaXW4ASkAuGDIEgAoOSIYcREGxLg9JNuNi5sfkJKXtHGGiycjTMu7TILs8DXHUwxhtLnuT287qIXo9AR16MxH_4Yd9Hlz-aNj359du87Z7CHSNPE-h82ae4-BDn07JkZNdsmd_e0Febq6fl3fFan17v7xaFWl6GAqp0Fa0ZqoE2TRUUkWdRgPCUa5dXVNUpuaKoqsk46CUcKYuObOyZJVtBF2Q8rc3vUffv9rYbsMY--lki9DOUtp_UugPz7pVyw</addsrcrecordid><sourcetype>Publisher</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Crystal structure and electrical conductivity of Nd5–xSmxMo3O16 solid solutions</title><source>Springer Nature - Complete Springer Journals</source><creator>Chebyshev, K. A. ; Get’man, E. I. ; Pasechnik, L. V. ; Ardanova, L. I. ; Korotina, D. V.</creator><creatorcontrib>Chebyshev, K. A. ; Get’man, E. I. ; Pasechnik, L. V. ; Ardanova, L. I. ; Korotina, D. V.</creatorcontrib><description>Samarium substitution for neodymium in the Nd
5
Mo
3
O
16
compound has been studied by X-ray diffraction, scanning electron microscopy, and IR spectroscopy. The results demonstrate that fluorite-like Nd
5–
x
Sm
x
Mo
3
O
16
solid solutions exist in the range
x
≤ 2. The electrical conductivity of the solid solutions increases with increasing samarium content in the range
x
= 0–1. Structure refinement by the Rietveld method for Nd
4
SmMo
3
O
16
has shown that the Nd(2) coordination polyhedron in this solid solution is distorted more severely than that in the structure of Nd
5
Mo
3
O
16
.</description><identifier>ISSN: 0020-1685</identifier><identifier>EISSN: 1608-3172</identifier><identifier>DOI: 10.1134/S0020168515100040</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Chemistry ; Chemistry and Materials Science ; Industrial Chemistry/Chemical Engineering ; Inorganic Chemistry ; Materials Science</subject><ispartof>Inorganic materials, 2015-10, Vol.51 (10), p.1033-1038</ispartof><rights>Pleiades Publishing, Ltd. 2015</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-s1130-ab1e4375b20a993a3b3fc1d08f36cf7731bd76b31f4a560bb8fd7265ea254e983</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0020168515100040$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0020168515100040$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Chebyshev, K. A.</creatorcontrib><creatorcontrib>Get’man, E. I.</creatorcontrib><creatorcontrib>Pasechnik, L. V.</creatorcontrib><creatorcontrib>Ardanova, L. I.</creatorcontrib><creatorcontrib>Korotina, D. V.</creatorcontrib><title>Crystal structure and electrical conductivity of Nd5–xSmxMo3O16 solid solutions</title><title>Inorganic materials</title><addtitle>Inorg Mater</addtitle><description>Samarium substitution for neodymium in the Nd
5
Mo
3
O
16
compound has been studied by X-ray diffraction, scanning electron microscopy, and IR spectroscopy. The results demonstrate that fluorite-like Nd
5–
x
Sm
x
Mo
3
O
16
solid solutions exist in the range
x
≤ 2. The electrical conductivity of the solid solutions increases with increasing samarium content in the range
x
= 0–1. Structure refinement by the Rietveld method for Nd
4
SmMo
3
O
16
has shown that the Nd(2) coordination polyhedron in this solid solution is distorted more severely than that in the structure of Nd
5
Mo
3
O
16
.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Inorganic Chemistry</subject><subject>Materials Science</subject><issn>0020-1685</issn><issn>1608-3172</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNplkEtOwzAQhi0EEqFwAHa5QGAmjh1niSpeUqFChXXkJ3IVYmQnqN1xB27ISUgEOzYzi-_XP6OPkHOEC0RaXW4ASkAuGDIEgAoOSIYcREGxLg9JNuNi5sfkJKXtHGGiycjTMu7TILs8DXHUwxhtLnuT287qIXo9AR16MxH_4Yd9Hlz-aNj359du87Z7CHSNPE-h82ae4-BDn07JkZNdsmd_e0Febq6fl3fFan17v7xaFWl6GAqp0Fa0ZqoE2TRUUkWdRgPCUa5dXVNUpuaKoqsk46CUcKYuObOyZJVtBF2Q8rc3vUffv9rYbsMY--lki9DOUtp_UugPz7pVyw</recordid><startdate>20151007</startdate><enddate>20151007</enddate><creator>Chebyshev, K. A.</creator><creator>Get’man, E. I.</creator><creator>Pasechnik, L. V.</creator><creator>Ardanova, L. I.</creator><creator>Korotina, D. V.</creator><general>Pleiades Publishing</general><scope/></search><sort><creationdate>20151007</creationdate><title>Crystal structure and electrical conductivity of Nd5–xSmxMo3O16 solid solutions</title><author>Chebyshev, K. A. ; Get’man, E. I. ; Pasechnik, L. V. ; Ardanova, L. I. ; Korotina, D. V.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-s1130-ab1e4375b20a993a3b3fc1d08f36cf7731bd76b31f4a560bb8fd7265ea254e983</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Inorganic Chemistry</topic><topic>Materials Science</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Chebyshev, K. A.</creatorcontrib><creatorcontrib>Get’man, E. I.</creatorcontrib><creatorcontrib>Pasechnik, L. V.</creatorcontrib><creatorcontrib>Ardanova, L. I.</creatorcontrib><creatorcontrib>Korotina, D. V.</creatorcontrib><jtitle>Inorganic materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chebyshev, K. A.</au><au>Get’man, E. I.</au><au>Pasechnik, L. V.</au><au>Ardanova, L. I.</au><au>Korotina, D. V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Crystal structure and electrical conductivity of Nd5–xSmxMo3O16 solid solutions</atitle><jtitle>Inorganic materials</jtitle><stitle>Inorg Mater</stitle><date>2015-10-07</date><risdate>2015</risdate><volume>51</volume><issue>10</issue><spage>1033</spage><epage>1038</epage><pages>1033-1038</pages><issn>0020-1685</issn><eissn>1608-3172</eissn><abstract>Samarium substitution for neodymium in the Nd
5
Mo
3
O
16
compound has been studied by X-ray diffraction, scanning electron microscopy, and IR spectroscopy. The results demonstrate that fluorite-like Nd
5–
x
Sm
x
Mo
3
O
16
solid solutions exist in the range
x
≤ 2. The electrical conductivity of the solid solutions increases with increasing samarium content in the range
x
= 0–1. Structure refinement by the Rietveld method for Nd
4
SmMo
3
O
16
has shown that the Nd(2) coordination polyhedron in this solid solution is distorted more severely than that in the structure of Nd
5
Mo
3
O
16
.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0020168515100040</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0020-1685 |
| ispartof | Inorganic materials, 2015-10, Vol.51 (10), p.1033-1038 |
| issn | 0020-1685 1608-3172 |
| language | eng |
| recordid | cdi_springer_journals_10_1134_S0020168515100040 |
| source | Springer Nature - Complete Springer Journals |
| subjects | Chemistry Chemistry and Materials Science Industrial Chemistry/Chemical Engineering Inorganic Chemistry Materials Science |
| title | Crystal structure and electrical conductivity of Nd5–xSmxMo3O16 solid solutions |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-01T18%3A40%3A20IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-springer&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Crystal%20structure%20and%20electrical%20conductivity%20of%20Nd5%E2%80%93xSmxMo3O16%20solid%20solutions&rft.jtitle=Inorganic%20materials&rft.au=Chebyshev,%20K.%20A.&rft.date=2015-10-07&rft.volume=51&rft.issue=10&rft.spage=1033&rft.epage=1038&rft.pages=1033-1038&rft.issn=0020-1685&rft.eissn=1608-3172&rft_id=info:doi/10.1134/S0020168515100040&rft_dat=%3Cspringer%3E10_1134_S0020168515100040%3C/springer%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |