Sintering properties of ZnO-TiO2 composite

In this study, we investigated the structural transformation of ZnO-TiO2 composite ceramics with different molar compositions, sintering temperatures, and sintering environments. The 1:1 mole ratio sample was sintered at different temperatures of 600°C, 700°C, 900°C, and 1000°C in air. The phase tra...

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Hauptverfasser: Sutharsini, U., Kopika, P., Mohanapriya, K., Janani, A., Thanihaichelvan, M., Ng, C. K., Ramasenderan, Narendran
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creator Sutharsini, U.
Kopika, P.
Mohanapriya, K.
Janani, A.
Thanihaichelvan, M.
Ng, C. K.
Ramasenderan, Narendran
description In this study, we investigated the structural transformation of ZnO-TiO2 composite ceramics with different molar compositions, sintering temperatures, and sintering environments. The 1:1 mole ratio sample was sintered at different temperatures of 600°C, 700°C, 900°C, and 1000°C in air. The phase transformations were studied using X-ray diffraction (XRD) spectroscopy. At 900°C and above, composite peaks of ZnTiO3 and Zn2TiO4, and the tetragonal rutile phase of TiO2 began to develop. Then, samples with different molar ratios of ZnO and TiO2 (9:1, 8:2, 7:3, 6:4, 5:5) were sintered at 1000°C in air and vacuum. At the sintering temperature of 1000°C, composite peaks of ZnTiO3 and Zn2TiO4 were present in all molar ratios in both air-sintered and vacuum-sintered samples. However, the pure peaks corresponding to TiO2 vanished in the air-sintered samples, while pure peaks corresponding to ZnO and TiO2 were present in the vacuum-sintered samples.
doi_str_mv 10.1063/5.0229374
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subjects Phase transitions
Sintering
Titanium dioxide
Zinc oxide
title Sintering properties of ZnO-TiO2 composite
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