Isolation and characterization of lignin from black liquor of arecanut leaf sheath (Areca catechu L.) with hydrochloric acid and phosphoric acid
Most of the Arecanut Leaf Sheath (ALS) was burned and disposed of as waste, in which lignin, including a major cell wall component of ALS, has potency as a green chemical. Up to now, there is a limited report on lignin extraction and isolation from ALS. Hence, this research used kraft pulping with d...
Gespeichert in:
Hauptverfasser: | , , , , , , |
---|---|
Format: | Tagungsbericht |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
container_end_page | |
---|---|
container_issue | 1 |
container_start_page | |
container_title | |
container_volume | 2973 |
creator | Ridho, Muhammad Rasyidur Madyaratri, Elvara Windra Agustiany, Erika Ayu Solihat, Nissa Nurfajrin Nawawi, Deded Sarip Juliana, Ika Fatriasari, Widya |
description | Most of the Arecanut Leaf Sheath (ALS) was burned and disposed of as waste, in which lignin, including a major cell wall component of ALS, has potency as a green chemical. Up to now, there is a limited report on lignin extraction and isolation from ALS. Hence, this research used kraft pulping with different percentages of active alkaline (17 and 19%) and sulfidity (20%) as a delignification method for lignin extraction from ALS. And this study aimed to describe the effect of the variation of inorganic acids (HCl and H3PO4) in the lignin isolation process on lignin characterization. Furthermore, the characterization of isolated lignin entails moisture content, yield, purity, ash content, thermogravimetry analysis (TGA), Fourier transform infrared spectroscopy (FTIR), and PyGCMS. Interestingly, acid precipitation had a critical effect on lignin yield, where HCl obtained a higher yield (38-40%) than H3PO4 (14-15%). The result showed that less active alkali resulted in higher lignin purity by both acid precipitation, AIL of 19.11 and 15.69 % for each 17 and 19% active alkali (AA) by HCl precipitation and 40.74 and 30.62 % by H3PO4. Less AA also obtained less residue by TGA analysis and a lower s/g ratio by Py-GCMS. Nevertheless, the difference of acids (HCl or H3PO4) does not show any difference in terms of s/g ratio, but they impact the purity and thermal properties of produced lignin. FTIR spectrum showed that all isolated lignin has a similar functional group to commercial lignin. Therefore, the lignin produced can be influenced by the use of various active alkalis in the pulping process and various acids in the lignin isolation process. |
doi_str_mv | 10.1063/5.0184445 |
format | Conference Proceeding |
fullrecord | <record><control><sourceid>proquest_scita</sourceid><recordid>TN_cdi_scitation_primary_10_1063_5_0184445</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2956429052</sourcerecordid><originalsourceid>FETCH-LOGICAL-p1685-3fb3322ce53e5afcf19516531c88272d5b8f09873994ebba6dfbfbd0e3d154853</originalsourceid><addsrcrecordid>eNo1kMtKxDAUhoMoOI4ufIOAGxVac22T5TB4GRhwo-CupGliM3aaTtIi41P4yHYuLg4HvvNzfvgAuMYoxSijDzxFWDDG-AmYYM5xkmc4OwUThCRLCKMf5-AixhVCROa5mIDfRfSN6p1voWorqGsVlO5NcD8H6C1s3GfrWmiDX8OyUfprJJvBh91NBaNVO_SwMcrCWBvV1_B2tqNQq97oeoDL9A5-u5HX2yp4XTc-OA2VdtW-sqt9HOefXYIzq5poro57Ct6fHt_mL8ny9Xkxny2TDmeCJ9SWlBKiDaeGK6stlhxnnGItBMlJxUthkRQ5lZKZslRZZUtbVsjQCnMmOJ2Cm8PfLvjNYGJfrPwQ2rGyIJJnjEjEyZi6P6Sidv3eSNEFt1ZhW2BU7IwXvDgap39Tf3RX</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>conference_proceeding</recordtype><pqid>2956429052</pqid></control><display><type>conference_proceeding</type><title>Isolation and characterization of lignin from black liquor of arecanut leaf sheath (Areca catechu L.) with hydrochloric acid and phosphoric acid</title><source>AIP Journals Complete</source><creator>Ridho, Muhammad Rasyidur ; Madyaratri, Elvara Windra ; Agustiany, Erika Ayu ; Solihat, Nissa Nurfajrin ; Nawawi, Deded Sarip ; Juliana, Ika ; Fatriasari, Widya</creator><contributor>Kristak, Lubos ; Lubis, Muhammad Adly Rahandi ; Lee, Seng Hua ; Antov, Petar</contributor><creatorcontrib>Ridho, Muhammad Rasyidur ; Madyaratri, Elvara Windra ; Agustiany, Erika Ayu ; Solihat, Nissa Nurfajrin ; Nawawi, Deded Sarip ; Juliana, Ika ; Fatriasari, Widya ; Kristak, Lubos ; Lubis, Muhammad Adly Rahandi ; Lee, Seng Hua ; Antov, Petar</creatorcontrib><description>Most of the Arecanut Leaf Sheath (ALS) was burned and disposed of as waste, in which lignin, including a major cell wall component of ALS, has potency as a green chemical. Up to now, there is a limited report on lignin extraction and isolation from ALS. Hence, this research used kraft pulping with different percentages of active alkaline (17 and 19%) and sulfidity (20%) as a delignification method for lignin extraction from ALS. And this study aimed to describe the effect of the variation of inorganic acids (HCl and H3PO4) in the lignin isolation process on lignin characterization. Furthermore, the characterization of isolated lignin entails moisture content, yield, purity, ash content, thermogravimetry analysis (TGA), Fourier transform infrared spectroscopy (FTIR), and PyGCMS. Interestingly, acid precipitation had a critical effect on lignin yield, where HCl obtained a higher yield (38-40%) than H3PO4 (14-15%). The result showed that less active alkali resulted in higher lignin purity by both acid precipitation, AIL of 19.11 and 15.69 % for each 17 and 19% active alkali (AA) by HCl precipitation and 40.74 and 30.62 % by H3PO4. Less AA also obtained less residue by TGA analysis and a lower s/g ratio by Py-GCMS. Nevertheless, the difference of acids (HCl or H3PO4) does not show any difference in terms of s/g ratio, but they impact the purity and thermal properties of produced lignin. FTIR spectrum showed that all isolated lignin has a similar functional group to commercial lignin. Therefore, the lignin produced can be influenced by the use of various active alkalis in the pulping process and various acids in the lignin isolation process.</description><identifier>ISSN: 0094-243X</identifier><identifier>EISSN: 1551-7616</identifier><identifier>DOI: 10.1063/5.0184445</identifier><identifier>CODEN: APCPCS</identifier><language>eng</language><publisher>Melville: American Institute of Physics</publisher><subject>Black liquor ; Catechu ; Fourier transforms ; Functional groups ; G ratio ; Hydrochloric acid ; Hydrogen chloride ; Infrared analysis ; Infrared spectroscopy ; Inorganic acids ; Kraft process (woodpulp) ; Lignin ; Moisture content ; Phosphoric acid ; Pulping ; Purity ; Sheaths ; Thermodynamic properties ; Thermogravimetry</subject><ispartof>AIP Conference Proceedings, 2024, Vol.2973 (1)</ispartof><rights>Author(s)</rights><rights>2024 Author(s). Published by AIP Publishing.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://pubs.aip.org/acp/article-lookup/doi/10.1063/5.0184445$$EHTML$$P50$$Gscitation$$H</linktohtml><link.rule.ids>309,310,314,780,784,789,790,794,4512,23930,23931,25140,27924,27925,76384</link.rule.ids></links><search><contributor>Kristak, Lubos</contributor><contributor>Lubis, Muhammad Adly Rahandi</contributor><contributor>Lee, Seng Hua</contributor><contributor>Antov, Petar</contributor><creatorcontrib>Ridho, Muhammad Rasyidur</creatorcontrib><creatorcontrib>Madyaratri, Elvara Windra</creatorcontrib><creatorcontrib>Agustiany, Erika Ayu</creatorcontrib><creatorcontrib>Solihat, Nissa Nurfajrin</creatorcontrib><creatorcontrib>Nawawi, Deded Sarip</creatorcontrib><creatorcontrib>Juliana, Ika</creatorcontrib><creatorcontrib>Fatriasari, Widya</creatorcontrib><title>Isolation and characterization of lignin from black liquor of arecanut leaf sheath (Areca catechu L.) with hydrochloric acid and phosphoric acid</title><title>AIP Conference Proceedings</title><description>Most of the Arecanut Leaf Sheath (ALS) was burned and disposed of as waste, in which lignin, including a major cell wall component of ALS, has potency as a green chemical. Up to now, there is a limited report on lignin extraction and isolation from ALS. Hence, this research used kraft pulping with different percentages of active alkaline (17 and 19%) and sulfidity (20%) as a delignification method for lignin extraction from ALS. And this study aimed to describe the effect of the variation of inorganic acids (HCl and H3PO4) in the lignin isolation process on lignin characterization. Furthermore, the characterization of isolated lignin entails moisture content, yield, purity, ash content, thermogravimetry analysis (TGA), Fourier transform infrared spectroscopy (FTIR), and PyGCMS. Interestingly, acid precipitation had a critical effect on lignin yield, where HCl obtained a higher yield (38-40%) than H3PO4 (14-15%). The result showed that less active alkali resulted in higher lignin purity by both acid precipitation, AIL of 19.11 and 15.69 % for each 17 and 19% active alkali (AA) by HCl precipitation and 40.74 and 30.62 % by H3PO4. Less AA also obtained less residue by TGA analysis and a lower s/g ratio by Py-GCMS. Nevertheless, the difference of acids (HCl or H3PO4) does not show any difference in terms of s/g ratio, but they impact the purity and thermal properties of produced lignin. FTIR spectrum showed that all isolated lignin has a similar functional group to commercial lignin. Therefore, the lignin produced can be influenced by the use of various active alkalis in the pulping process and various acids in the lignin isolation process.</description><subject>Black liquor</subject><subject>Catechu</subject><subject>Fourier transforms</subject><subject>Functional groups</subject><subject>G ratio</subject><subject>Hydrochloric acid</subject><subject>Hydrogen chloride</subject><subject>Infrared analysis</subject><subject>Infrared spectroscopy</subject><subject>Inorganic acids</subject><subject>Kraft process (woodpulp)</subject><subject>Lignin</subject><subject>Moisture content</subject><subject>Phosphoric acid</subject><subject>Pulping</subject><subject>Purity</subject><subject>Sheaths</subject><subject>Thermodynamic properties</subject><subject>Thermogravimetry</subject><issn>0094-243X</issn><issn>1551-7616</issn><fulltext>true</fulltext><rsrctype>conference_proceeding</rsrctype><creationdate>2024</creationdate><recordtype>conference_proceeding</recordtype><recordid>eNo1kMtKxDAUhoMoOI4ufIOAGxVac22T5TB4GRhwo-CupGliM3aaTtIi41P4yHYuLg4HvvNzfvgAuMYoxSijDzxFWDDG-AmYYM5xkmc4OwUThCRLCKMf5-AixhVCROa5mIDfRfSN6p1voWorqGsVlO5NcD8H6C1s3GfrWmiDX8OyUfprJJvBh91NBaNVO_SwMcrCWBvV1_B2tqNQq97oeoDL9A5-u5HX2yp4XTc-OA2VdtW-sqt9HOefXYIzq5poro57Ct6fHt_mL8ny9Xkxny2TDmeCJ9SWlBKiDaeGK6stlhxnnGItBMlJxUthkRQ5lZKZslRZZUtbVsjQCnMmOJ2Cm8PfLvjNYGJfrPwQ2rGyIJJnjEjEyZi6P6Sidv3eSNEFt1ZhW2BU7IwXvDgap39Tf3RX</recordid><startdate>20240313</startdate><enddate>20240313</enddate><creator>Ridho, Muhammad Rasyidur</creator><creator>Madyaratri, Elvara Windra</creator><creator>Agustiany, Erika Ayu</creator><creator>Solihat, Nissa Nurfajrin</creator><creator>Nawawi, Deded Sarip</creator><creator>Juliana, Ika</creator><creator>Fatriasari, Widya</creator><general>American Institute of Physics</general><scope>8FD</scope><scope>H8D</scope><scope>L7M</scope></search><sort><creationdate>20240313</creationdate><title>Isolation and characterization of lignin from black liquor of arecanut leaf sheath (Areca catechu L.) with hydrochloric acid and phosphoric acid</title><author>Ridho, Muhammad Rasyidur ; Madyaratri, Elvara Windra ; Agustiany, Erika Ayu ; Solihat, Nissa Nurfajrin ; Nawawi, Deded Sarip ; Juliana, Ika ; Fatriasari, Widya</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p1685-3fb3322ce53e5afcf19516531c88272d5b8f09873994ebba6dfbfbd0e3d154853</frbrgroupid><rsrctype>conference_proceedings</rsrctype><prefilter>conference_proceedings</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Black liquor</topic><topic>Catechu</topic><topic>Fourier transforms</topic><topic>Functional groups</topic><topic>G ratio</topic><topic>Hydrochloric acid</topic><topic>Hydrogen chloride</topic><topic>Infrared analysis</topic><topic>Infrared spectroscopy</topic><topic>Inorganic acids</topic><topic>Kraft process (woodpulp)</topic><topic>Lignin</topic><topic>Moisture content</topic><topic>Phosphoric acid</topic><topic>Pulping</topic><topic>Purity</topic><topic>Sheaths</topic><topic>Thermodynamic properties</topic><topic>Thermogravimetry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ridho, Muhammad Rasyidur</creatorcontrib><creatorcontrib>Madyaratri, Elvara Windra</creatorcontrib><creatorcontrib>Agustiany, Erika Ayu</creatorcontrib><creatorcontrib>Solihat, Nissa Nurfajrin</creatorcontrib><creatorcontrib>Nawawi, Deded Sarip</creatorcontrib><creatorcontrib>Juliana, Ika</creatorcontrib><creatorcontrib>Fatriasari, Widya</creatorcontrib><collection>Technology Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ridho, Muhammad Rasyidur</au><au>Madyaratri, Elvara Windra</au><au>Agustiany, Erika Ayu</au><au>Solihat, Nissa Nurfajrin</au><au>Nawawi, Deded Sarip</au><au>Juliana, Ika</au><au>Fatriasari, Widya</au><au>Kristak, Lubos</au><au>Lubis, Muhammad Adly Rahandi</au><au>Lee, Seng Hua</au><au>Antov, Petar</au><format>book</format><genre>proceeding</genre><ristype>CONF</ristype><atitle>Isolation and characterization of lignin from black liquor of arecanut leaf sheath (Areca catechu L.) with hydrochloric acid and phosphoric acid</atitle><btitle>AIP Conference Proceedings</btitle><date>2024-03-13</date><risdate>2024</risdate><volume>2973</volume><issue>1</issue><issn>0094-243X</issn><eissn>1551-7616</eissn><coden>APCPCS</coden><abstract>Most of the Arecanut Leaf Sheath (ALS) was burned and disposed of as waste, in which lignin, including a major cell wall component of ALS, has potency as a green chemical. Up to now, there is a limited report on lignin extraction and isolation from ALS. Hence, this research used kraft pulping with different percentages of active alkaline (17 and 19%) and sulfidity (20%) as a delignification method for lignin extraction from ALS. And this study aimed to describe the effect of the variation of inorganic acids (HCl and H3PO4) in the lignin isolation process on lignin characterization. Furthermore, the characterization of isolated lignin entails moisture content, yield, purity, ash content, thermogravimetry analysis (TGA), Fourier transform infrared spectroscopy (FTIR), and PyGCMS. Interestingly, acid precipitation had a critical effect on lignin yield, where HCl obtained a higher yield (38-40%) than H3PO4 (14-15%). The result showed that less active alkali resulted in higher lignin purity by both acid precipitation, AIL of 19.11 and 15.69 % for each 17 and 19% active alkali (AA) by HCl precipitation and 40.74 and 30.62 % by H3PO4. Less AA also obtained less residue by TGA analysis and a lower s/g ratio by Py-GCMS. Nevertheless, the difference of acids (HCl or H3PO4) does not show any difference in terms of s/g ratio, but they impact the purity and thermal properties of produced lignin. FTIR spectrum showed that all isolated lignin has a similar functional group to commercial lignin. Therefore, the lignin produced can be influenced by the use of various active alkalis in the pulping process and various acids in the lignin isolation process.</abstract><cop>Melville</cop><pub>American Institute of Physics</pub><doi>10.1063/5.0184445</doi><tpages>9</tpages><oa>free_for_read</oa></addata></record> |
fulltext | fulltext |
identifier | ISSN: 0094-243X |
ispartof | AIP Conference Proceedings, 2024, Vol.2973 (1) |
issn | 0094-243X 1551-7616 |
language | eng |
recordid | cdi_scitation_primary_10_1063_5_0184445 |
source | AIP Journals Complete |
subjects | Black liquor Catechu Fourier transforms Functional groups G ratio Hydrochloric acid Hydrogen chloride Infrared analysis Infrared spectroscopy Inorganic acids Kraft process (woodpulp) Lignin Moisture content Phosphoric acid Pulping Purity Sheaths Thermodynamic properties Thermogravimetry |
title | Isolation and characterization of lignin from black liquor of arecanut leaf sheath (Areca catechu L.) with hydrochloric acid and phosphoric acid |
url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-25T18%3A22%3A00IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_scita&rft_val_fmt=info:ofi/fmt:kev:mtx:book&rft.genre=proceeding&rft.atitle=Isolation%20and%20characterization%20of%20lignin%20from%20black%20liquor%20of%20arecanut%20leaf%20sheath%20(Areca%20catechu%20L.)%20with%20hydrochloric%20acid%20and%20phosphoric%20acid&rft.btitle=AIP%20Conference%20Proceedings&rft.au=Ridho,%20Muhammad%20Rasyidur&rft.date=2024-03-13&rft.volume=2973&rft.issue=1&rft.issn=0094-243X&rft.eissn=1551-7616&rft.coden=APCPCS&rft_id=info:doi/10.1063/5.0184445&rft_dat=%3Cproquest_scita%3E2956429052%3C/proquest_scita%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2956429052&rft_id=info:pmid/&rfr_iscdi=true |