The method of synthesis of 2-(1,3-diphenyl-1H-1,2,4-triazol-5-yl)-2,2-dinitroacetonitrile and its reaction with substituted aromatic nitrile N-oxides
A method for the synthesis of 2-(1,3-diphenyl-1H-1,2,4-triazol-5-yl)-2,2-dinitroacetonitrile has been developed herein and its subsequent reaction with substituted aromatic nitrile N-oxides was explored. The latter proceeds by 1.3-dipolar cycloaddition mechanism and results in the formation of 5-[(1...
Gespeichert in:
| Hauptverfasser: | , , , |
|---|---|
| Format: | Tagungsbericht |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | |
|---|---|
| container_issue | 1 |
| container_start_page | |
| container_title | |
| container_volume | 2390 |
| creator | Tyrkov, A. Yurtaeva, E. Pitelina, M. Luzhnova, S. |
| description | A method for the synthesis of 2-(1,3-diphenyl-1H-1,2,4-triazol-5-yl)-2,2-dinitroacetonitrile has been developed herein and its subsequent reaction with substituted aromatic nitrile N-oxides was explored. The latter proceeds by 1.3-dipolar cycloaddition mechanism and results in the formation of 5-[(1,3-diphenyl-1H-1,2,4-triazol-5-yl)dinitromethyl]-3-aryl-1,2,4-oxadiazoles. This oxadiazole derivative further interacts with KOH in ethanol to afford the potassium salt of aci-5-dinitromethyl-1,3-diphenyl-1H-1,2,4-triazole and substituted 5-hydroxy-1,2,4-oxadiazoles. |
| doi_str_mv | 10.1063/5.0069528 |
| format | Conference Proceeding |
| fullrecord | <record><control><sourceid>proquest_scita</sourceid><recordid>TN_cdi_scitation_primary_10_1063_5_0069528</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2625383561</sourcerecordid><originalsourceid>FETCH-LOGICAL-p168t-b3fa698358720b99e73dd69364174341709ef0a9fd29346254872640a13ec8b3</originalsourceid><addsrcrecordid>eNp9kctKxDAUhoMoOI4ufIOAG5VmzKVNm6UM6giim1m4K2mT0gydpiapWt_D97VlRty5ORf4_v9wzgHgnOAFwZzdJAuMuUhodgBmJEkISjnhh2CGsYgRjdnrMTjxfoMxFWmazcD3utZwq0NtFbQV9EMbau2NnxqKLknEkDJdrduhQWSFSESjGAVn5JdtUIKG5grRiI5Ma4KzstTBTpVpNJStgiZ46LQsg7Et_DChhr4vfDChD1pB6exWBlPCX8kzsp9GaX8KjirZeH22z3Owvr9bL1fo6eXhcXn7hDrCs4AKVkkuMpZkKcWFEDplSnHBeEzSmI0BC11hKSpFBYs5TeIR5DGWhOkyK9gcXOxsO2ffeu1DvrG9a8eJOR1pNjpzMlLXO8qXJshpk7xzZivdkL9blyf5_uJ5p6r_YILz6UV_AvYD3_CBaw</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>conference_proceeding</recordtype><pqid>2625383561</pqid></control><display><type>conference_proceeding</type><title>The method of synthesis of 2-(1,3-diphenyl-1H-1,2,4-triazol-5-yl)-2,2-dinitroacetonitrile and its reaction with substituted aromatic nitrile N-oxides</title><source>AIP Journals Complete</source><creator>Tyrkov, A. ; Yurtaeva, E. ; Pitelina, M. ; Luzhnova, S.</creator><contributor>Glukhareva, Tatiana ; Bakulev, Vasiliy ; Schafran, Yuri ; Beryozkina, Tatiana ; Koptyaeva, Olga ; Lyubyakina, Polina ; Kovaleva, Elena</contributor><creatorcontrib>Tyrkov, A. ; Yurtaeva, E. ; Pitelina, M. ; Luzhnova, S. ; Glukhareva, Tatiana ; Bakulev, Vasiliy ; Schafran, Yuri ; Beryozkina, Tatiana ; Koptyaeva, Olga ; Lyubyakina, Polina ; Kovaleva, Elena</creatorcontrib><description>A method for the synthesis of 2-(1,3-diphenyl-1H-1,2,4-triazol-5-yl)-2,2-dinitroacetonitrile has been developed herein and its subsequent reaction with substituted aromatic nitrile N-oxides was explored. The latter proceeds by 1.3-dipolar cycloaddition mechanism and results in the formation of 5-[(1,3-diphenyl-1H-1,2,4-triazol-5-yl)dinitromethyl]-3-aryl-1,2,4-oxadiazoles. This oxadiazole derivative further interacts with KOH in ethanol to afford the potassium salt of aci-5-dinitromethyl-1,3-diphenyl-1H-1,2,4-triazole and substituted 5-hydroxy-1,2,4-oxadiazoles.</description><identifier>ISSN: 0094-243X</identifier><identifier>EISSN: 1551-7616</identifier><identifier>DOI: 10.1063/5.0069528</identifier><identifier>CODEN: APCPCS</identifier><language>eng</language><publisher>Melville: American Institute of Physics</publisher><subject>Cycloaddition ; Ethanol ; Oxadiazoles ; Potassium salts ; Substitutes</subject><ispartof>AIP conference proceedings, 2022, Vol.2390 (1)</ispartof><rights>Author(s)</rights><rights>2022 Author(s). Published by AIP Publishing.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://pubs.aip.org/acp/article-lookup/doi/10.1063/5.0069528$$EHTML$$P50$$Gscitation$$H</linktohtml><link.rule.ids>309,310,314,776,780,785,786,790,4498,23911,23912,25120,27903,27904,76130</link.rule.ids></links><search><contributor>Glukhareva, Tatiana</contributor><contributor>Bakulev, Vasiliy</contributor><contributor>Schafran, Yuri</contributor><contributor>Beryozkina, Tatiana</contributor><contributor>Koptyaeva, Olga</contributor><contributor>Lyubyakina, Polina</contributor><contributor>Kovaleva, Elena</contributor><creatorcontrib>Tyrkov, A.</creatorcontrib><creatorcontrib>Yurtaeva, E.</creatorcontrib><creatorcontrib>Pitelina, M.</creatorcontrib><creatorcontrib>Luzhnova, S.</creatorcontrib><title>The method of synthesis of 2-(1,3-diphenyl-1H-1,2,4-triazol-5-yl)-2,2-dinitroacetonitrile and its reaction with substituted aromatic nitrile N-oxides</title><title>AIP conference proceedings</title><description>A method for the synthesis of 2-(1,3-diphenyl-1H-1,2,4-triazol-5-yl)-2,2-dinitroacetonitrile has been developed herein and its subsequent reaction with substituted aromatic nitrile N-oxides was explored. The latter proceeds by 1.3-dipolar cycloaddition mechanism and results in the formation of 5-[(1,3-diphenyl-1H-1,2,4-triazol-5-yl)dinitromethyl]-3-aryl-1,2,4-oxadiazoles. This oxadiazole derivative further interacts with KOH in ethanol to afford the potassium salt of aci-5-dinitromethyl-1,3-diphenyl-1H-1,2,4-triazole and substituted 5-hydroxy-1,2,4-oxadiazoles.</description><subject>Cycloaddition</subject><subject>Ethanol</subject><subject>Oxadiazoles</subject><subject>Potassium salts</subject><subject>Substitutes</subject><issn>0094-243X</issn><issn>1551-7616</issn><fulltext>true</fulltext><rsrctype>conference_proceeding</rsrctype><creationdate>2022</creationdate><recordtype>conference_proceeding</recordtype><recordid>eNp9kctKxDAUhoMoOI4ufIOAG5VmzKVNm6UM6giim1m4K2mT0gydpiapWt_D97VlRty5ORf4_v9wzgHgnOAFwZzdJAuMuUhodgBmJEkISjnhh2CGsYgRjdnrMTjxfoMxFWmazcD3utZwq0NtFbQV9EMbau2NnxqKLknEkDJdrduhQWSFSESjGAVn5JdtUIKG5grRiI5Ma4KzstTBTpVpNJStgiZ46LQsg7Et_DChhr4vfDChD1pB6exWBlPCX8kzsp9GaX8KjirZeH22z3Owvr9bL1fo6eXhcXn7hDrCs4AKVkkuMpZkKcWFEDplSnHBeEzSmI0BC11hKSpFBYs5TeIR5DGWhOkyK9gcXOxsO2ffeu1DvrG9a8eJOR1pNjpzMlLXO8qXJshpk7xzZivdkL9blyf5_uJ5p6r_YILz6UV_AvYD3_CBaw</recordid><startdate>20220204</startdate><enddate>20220204</enddate><creator>Tyrkov, A.</creator><creator>Yurtaeva, E.</creator><creator>Pitelina, M.</creator><creator>Luzhnova, S.</creator><general>American Institute of Physics</general><scope>8FD</scope><scope>H8D</scope><scope>L7M</scope></search><sort><creationdate>20220204</creationdate><title>The method of synthesis of 2-(1,3-diphenyl-1H-1,2,4-triazol-5-yl)-2,2-dinitroacetonitrile and its reaction with substituted aromatic nitrile N-oxides</title><author>Tyrkov, A. ; Yurtaeva, E. ; Pitelina, M. ; Luzhnova, S.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p168t-b3fa698358720b99e73dd69364174341709ef0a9fd29346254872640a13ec8b3</frbrgroupid><rsrctype>conference_proceedings</rsrctype><prefilter>conference_proceedings</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Cycloaddition</topic><topic>Ethanol</topic><topic>Oxadiazoles</topic><topic>Potassium salts</topic><topic>Substitutes</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Tyrkov, A.</creatorcontrib><creatorcontrib>Yurtaeva, E.</creatorcontrib><creatorcontrib>Pitelina, M.</creatorcontrib><creatorcontrib>Luzhnova, S.</creatorcontrib><collection>Technology Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Tyrkov, A.</au><au>Yurtaeva, E.</au><au>Pitelina, M.</au><au>Luzhnova, S.</au><au>Glukhareva, Tatiana</au><au>Bakulev, Vasiliy</au><au>Schafran, Yuri</au><au>Beryozkina, Tatiana</au><au>Koptyaeva, Olga</au><au>Lyubyakina, Polina</au><au>Kovaleva, Elena</au><format>book</format><genre>proceeding</genre><ristype>CONF</ristype><atitle>The method of synthesis of 2-(1,3-diphenyl-1H-1,2,4-triazol-5-yl)-2,2-dinitroacetonitrile and its reaction with substituted aromatic nitrile N-oxides</atitle><btitle>AIP conference proceedings</btitle><date>2022-02-04</date><risdate>2022</risdate><volume>2390</volume><issue>1</issue><issn>0094-243X</issn><eissn>1551-7616</eissn><coden>APCPCS</coden><abstract>A method for the synthesis of 2-(1,3-diphenyl-1H-1,2,4-triazol-5-yl)-2,2-dinitroacetonitrile has been developed herein and its subsequent reaction with substituted aromatic nitrile N-oxides was explored. The latter proceeds by 1.3-dipolar cycloaddition mechanism and results in the formation of 5-[(1,3-diphenyl-1H-1,2,4-triazol-5-yl)dinitromethyl]-3-aryl-1,2,4-oxadiazoles. This oxadiazole derivative further interacts with KOH in ethanol to afford the potassium salt of aci-5-dinitromethyl-1,3-diphenyl-1H-1,2,4-triazole and substituted 5-hydroxy-1,2,4-oxadiazoles.</abstract><cop>Melville</cop><pub>American Institute of Physics</pub><doi>10.1063/5.0069528</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0094-243X |
| ispartof | AIP conference proceedings, 2022, Vol.2390 (1) |
| issn | 0094-243X 1551-7616 |
| language | eng |
| recordid | cdi_scitation_primary_10_1063_5_0069528 |
| source | AIP Journals Complete |
| subjects | Cycloaddition Ethanol Oxadiazoles Potassium salts Substitutes |
| title | The method of synthesis of 2-(1,3-diphenyl-1H-1,2,4-triazol-5-yl)-2,2-dinitroacetonitrile and its reaction with substituted aromatic nitrile N-oxides |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-27T15%3A24%3A56IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_scita&rft_val_fmt=info:ofi/fmt:kev:mtx:book&rft.genre=proceeding&rft.atitle=The%20method%20of%20synthesis%20of%202-(1,3-diphenyl-1H-1,2,4-triazol-5-yl)-2,2-dinitroacetonitrile%20and%20its%20reaction%20with%20substituted%20aromatic%20nitrile%20N-oxides&rft.btitle=AIP%20conference%20proceedings&rft.au=Tyrkov,%20A.&rft.date=2022-02-04&rft.volume=2390&rft.issue=1&rft.issn=0094-243X&rft.eissn=1551-7616&rft.coden=APCPCS&rft_id=info:doi/10.1063/5.0069528&rft_dat=%3Cproquest_scita%3E2625383561%3C/proquest_scita%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2625383561&rft_id=info:pmid/&rfr_iscdi=true |