Engineering the nature of polarization dynamics in lead-free relaxors based on (Bi1/2Na1/2)TiO3
(Bi1/2Na1/2)TiO3 (BNT) is a lead-free ferroelectric material, which has shown promising electromechanical properties and energy storage capacities. These attractive functionalities and property performances are attributed to the relaxor behavior of BNT. However, the nature of the dielectric relaxati...
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Veröffentlicht in: | Applied physics letters 2021-09, Vol.119 (11) |
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description | (Bi1/2Na1/2)TiO3 (BNT) is a lead-free ferroelectric material, which has shown promising electromechanical properties and energy storage capacities. These attractive functionalities and property performances are attributed to the relaxor behavior of BNT. However, the nature of the dielectric relaxation is not well understood in these materials, and the physical meaning of some important parameters associated with the permittivity is still under debate. In this Letter, we focus on the dielectric “shoulder,” Ts, that is readily seen in the ε′–T curve of every BNT-based relaxor. It is found that the Ts is controlled by not only the typical compositional engineering but also by the thermal, electrical, or mechanical history. From a moderate temperature (≤250 °C), a sample can be rapidly cooled to room temperature or slowly cooled under an electrical bias or a mechanical bias in the form of a compressive stress. All three treatments lead to a nearly identical effect, which is to alter the Ts with respect to rest of the ε′–T curve that remains unperturbed. Therefore, the internal stress is identified to be a general perturbance to the polarization dynamics. Finally, the “breathing” model is revisited to interpret the physical meaning of Ts for these BNT materials under these metastable conditions. |
doi_str_mv | 10.1063/5.0064160 |
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These attractive functionalities and property performances are attributed to the relaxor behavior of BNT. However, the nature of the dielectric relaxation is not well understood in these materials, and the physical meaning of some important parameters associated with the permittivity is still under debate. In this Letter, we focus on the dielectric “shoulder,” Ts, that is readily seen in the ε′–T curve of every BNT-based relaxor. It is found that the Ts is controlled by not only the typical compositional engineering but also by the thermal, electrical, or mechanical history. From a moderate temperature (≤250 °C), a sample can be rapidly cooled to room temperature or slowly cooled under an electrical bias or a mechanical bias in the form of a compressive stress. All three treatments lead to a nearly identical effect, which is to alter the Ts with respect to rest of the ε′–T curve that remains unperturbed. Therefore, the internal stress is identified to be a general perturbance to the polarization dynamics. Finally, the “breathing” model is revisited to interpret the physical meaning of Ts for these BNT materials under these metastable conditions.</description><identifier>ISSN: 0003-6951</identifier><identifier>EISSN: 1077-3118</identifier><identifier>DOI: 10.1063/5.0064160</identifier><identifier>CODEN: APPLAB</identifier><language>eng</language><publisher>Melville: American Institute of Physics</publisher><subject>Applied physics ; Bias ; Compressive properties ; Dielectric relaxation ; Energy storage ; Ferroelectric materials ; Ferroelectricity ; Lead free ; Polarization ; Relaxors ; Residual stress ; Room temperature</subject><ispartof>Applied physics letters, 2021-09, Vol.119 (11)</ispartof><rights>Author(s)</rights><rights>2021 Author(s). Published under an exclusive license by AIP Publishing.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c362t-7eb6584cc6defc96b889a9c5786fc820fa1bac2da19249c182ffe86d30f331203</citedby><cites>FETCH-LOGICAL-c362t-7eb6584cc6defc96b889a9c5786fc820fa1bac2da19249c182ffe86d30f331203</cites><orcidid>0000-0002-5478-2699 ; 0000-0001-6251-1787</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://pubs.aip.org/apl/article-lookup/doi/10.1063/5.0064160$$EHTML$$P50$$Gscitation$$H</linktohtml><link.rule.ids>314,780,784,794,4509,27922,27923,76154</link.rule.ids></links><search><creatorcontrib>Fan, Zhongming</creatorcontrib><creatorcontrib>Randall, Clive A.</creatorcontrib><title>Engineering the nature of polarization dynamics in lead-free relaxors based on (Bi1/2Na1/2)TiO3</title><title>Applied physics letters</title><description>(Bi1/2Na1/2)TiO3 (BNT) is a lead-free ferroelectric material, which has shown promising electromechanical properties and energy storage capacities. These attractive functionalities and property performances are attributed to the relaxor behavior of BNT. However, the nature of the dielectric relaxation is not well understood in these materials, and the physical meaning of some important parameters associated with the permittivity is still under debate. In this Letter, we focus on the dielectric “shoulder,” Ts, that is readily seen in the ε′–T curve of every BNT-based relaxor. It is found that the Ts is controlled by not only the typical compositional engineering but also by the thermal, electrical, or mechanical history. From a moderate temperature (≤250 °C), a sample can be rapidly cooled to room temperature or slowly cooled under an electrical bias or a mechanical bias in the form of a compressive stress. All three treatments lead to a nearly identical effect, which is to alter the Ts with respect to rest of the ε′–T curve that remains unperturbed. Therefore, the internal stress is identified to be a general perturbance to the polarization dynamics. Finally, the “breathing” model is revisited to interpret the physical meaning of Ts for these BNT materials under these metastable conditions.</description><subject>Applied physics</subject><subject>Bias</subject><subject>Compressive properties</subject><subject>Dielectric relaxation</subject><subject>Energy storage</subject><subject>Ferroelectric materials</subject><subject>Ferroelectricity</subject><subject>Lead free</subject><subject>Polarization</subject><subject>Relaxors</subject><subject>Residual stress</subject><subject>Room temperature</subject><issn>0003-6951</issn><issn>1077-3118</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp90E1LAzEQBuAgCtbqwX8Q8GKFbfOxm80etdQPKPZSzyGbTWrKNlmTrVh_vdGKHgQvMww8zDAvAOcYjTFidFKMEWI5ZugADDAqy4xizA_BACFEM1YV-BicxLhOY0EoHQAxcyvrtA7WrWD_rKGT_TZo6A3sfCuDfZe99Q42Oyc3VkVoHWy1bDITtIZBt_LNhwhrGXUDk7u8sXhCHmUqo6Vd0FNwZGQb9dl3H4Kn29lyep_NF3cP0-t5pigjfVbqmhU8V4o12qiK1ZxXslJFyZlRnCAjcS0VaSSuSF4pzIkxmrOGIkMpJogOwcV-bxf8y1bHXqz9Nrh0UpCiJOnzHJdJjfZKBR9j0EZ0wW5k2AmMxGd-ohDf-SV7tbdR2f4rhB_86sMvFF1j_sN_N38AL4p8ww</recordid><startdate>20210913</startdate><enddate>20210913</enddate><creator>Fan, Zhongming</creator><creator>Randall, Clive A.</creator><general>American Institute of Physics</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FD</scope><scope>H8D</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0002-5478-2699</orcidid><orcidid>https://orcid.org/0000-0001-6251-1787</orcidid></search><sort><creationdate>20210913</creationdate><title>Engineering the nature of polarization dynamics in lead-free relaxors based on (Bi1/2Na1/2)TiO3</title><author>Fan, Zhongming ; Randall, Clive A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c362t-7eb6584cc6defc96b889a9c5786fc820fa1bac2da19249c182ffe86d30f331203</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Applied physics</topic><topic>Bias</topic><topic>Compressive properties</topic><topic>Dielectric relaxation</topic><topic>Energy storage</topic><topic>Ferroelectric materials</topic><topic>Ferroelectricity</topic><topic>Lead free</topic><topic>Polarization</topic><topic>Relaxors</topic><topic>Residual stress</topic><topic>Room temperature</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Fan, Zhongming</creatorcontrib><creatorcontrib>Randall, Clive A.</creatorcontrib><collection>CrossRef</collection><collection>Technology Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Applied physics letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Fan, Zhongming</au><au>Randall, Clive A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Engineering the nature of polarization dynamics in lead-free relaxors based on (Bi1/2Na1/2)TiO3</atitle><jtitle>Applied physics letters</jtitle><date>2021-09-13</date><risdate>2021</risdate><volume>119</volume><issue>11</issue><issn>0003-6951</issn><eissn>1077-3118</eissn><coden>APPLAB</coden><abstract>(Bi1/2Na1/2)TiO3 (BNT) is a lead-free ferroelectric material, which has shown promising electromechanical properties and energy storage capacities. These attractive functionalities and property performances are attributed to the relaxor behavior of BNT. However, the nature of the dielectric relaxation is not well understood in these materials, and the physical meaning of some important parameters associated with the permittivity is still under debate. In this Letter, we focus on the dielectric “shoulder,” Ts, that is readily seen in the ε′–T curve of every BNT-based relaxor. It is found that the Ts is controlled by not only the typical compositional engineering but also by the thermal, electrical, or mechanical history. From a moderate temperature (≤250 °C), a sample can be rapidly cooled to room temperature or slowly cooled under an electrical bias or a mechanical bias in the form of a compressive stress. All three treatments lead to a nearly identical effect, which is to alter the Ts with respect to rest of the ε′–T curve that remains unperturbed. Therefore, the internal stress is identified to be a general perturbance to the polarization dynamics. Finally, the “breathing” model is revisited to interpret the physical meaning of Ts for these BNT materials under these metastable conditions.</abstract><cop>Melville</cop><pub>American Institute of Physics</pub><doi>10.1063/5.0064160</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0002-5478-2699</orcidid><orcidid>https://orcid.org/0000-0001-6251-1787</orcidid><oa>free_for_read</oa></addata></record> |
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source | 美国小型学会期刊集(AIP Scitation平台); Alma/SFX Local Collection |
subjects | Applied physics Bias Compressive properties Dielectric relaxation Energy storage Ferroelectric materials Ferroelectricity Lead free Polarization Relaxors Residual stress Room temperature |
title | Engineering the nature of polarization dynamics in lead-free relaxors based on (Bi1/2Na1/2)TiO3 |
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