High-pressure behavior of heteroepitaxial core–shell particles made of Prussian blue analogs

We report the compressibility of two Prussian blue analogs (PBAs) under hydrostatic pressure, one with small and one with a relatively large cubic unit cell among PBAs, and investigate the modification of their elastic properties when the two lattices are coupled within a heteroepitaxial core–shell...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Journal of applied physics 2021-06, Vol.129 (23)
Hauptverfasser: Maurin, Isabelle, Itoi, Miho, Cain, John M., Talham, Daniel R., Gacoin, Thierry, Boukheddaden, Kamel, Itié, Jean-Paul
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page
container_issue 23
container_start_page
container_title Journal of applied physics
container_volume 129
creator Maurin, Isabelle
Itoi, Miho
Cain, John M.
Talham, Daniel R.
Gacoin, Thierry
Boukheddaden, Kamel
Itié, Jean-Paul
description We report the compressibility of two Prussian blue analogs (PBAs) under hydrostatic pressure, one with small and one with a relatively large cubic unit cell among PBAs, and investigate the modification of their elastic properties when the two lattices are coupled within a heteroepitaxial core–shell structure. Bulk modulus (K0) values are derived from x-ray powder diffraction experiments using a diamond anvil cell with silicone oil as a pressure-transmitting medium. The pressure–volume curves fitted to Murnaghan equations of states show that K0 inversely scales with the crystal packing for the rubidium cobalt hexacyanoferrate and rubidium nickel hexacyanochromate samples (K0 ∼ 29 GPa for Co-Fe PBA, a0 = 9.95 Å and ∼20 GPa for Ni-Cr PBA, a0 = 10.48 Å with a0 being the lattice constant at ambient pressure). The two single-phase samples undergo a cubic-to-rhombohedral phase transition above ∼0.8 GPa, which correlates fairly well with the build-up of nonhydrostatic pressure contributions in the cell. Within the core–shell structure, the volume change observed for the core scales with that of the shell because of the configuration close to the case of a solid pressure-transmitting medium. The Ni-Cr PBA shell layer exhibits an increased rhombohedral distortion with respect to the single-phase reference possibly associated with shearing at the core–shell interface. Its bulk modulus is not significantly modified with respect to that of the single-phase sample despite the presence of defects associated with the growth mode, whereas the P-V curve of the core suggests a stiffening of the Co-Fe PBA lattice.
doi_str_mv 10.1063/5.0049223
format Article
fullrecord <record><control><sourceid>proquest_scita</sourceid><recordid>TN_cdi_scitation_primary_10_1063_5_0049223</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2542109799</sourcerecordid><originalsourceid>FETCH-LOGICAL-c462t-1f052c2e10c2421886f95665e39b484255f6240bea829140979eb7c89faa3acc3</originalsourceid><addsrcrecordid>eNqdkMFKw0AQhhdRsFYPvkHAk0Lq7Cab7h5LUSsU9KBXl8120mxJu3E3KXrzHXxDn8SEFnv3NDB8fP_MT8glhRGFLLnlI4BUMpYckQEFIeMx53BMBgCMxkKO5Sk5C2EFQKlI5IC8zeyyjGuPIbQeoxxLvbXOR66ISmzQO6xtoz-sriLjPP58fYcSqyqqtW-sqTBEa73AHn_2bQhWb6K8ajHSG125ZTgnJ4WuAl7s55C83t-9TGfx_OnhcTqZxybNWBPTAjgzDCkYljIqRFZInmUcE5mnImWcFxlLIUctmKQpdH9gPjZCFlon2phkSK533lJXqvZ2rf2nctqq2WSu-h0kTGTA2JZ27NWOrb17bzE0auVa390bFONdem-XB6PxLgSPxZ-WguqrVlztq-7Ymx0bTFdWY93mf_DW-QOo6kWR_AKS94x4</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2542109799</pqid></control><display><type>article</type><title>High-pressure behavior of heteroepitaxial core–shell particles made of Prussian blue analogs</title><source>AIP Journals Complete</source><source>Alma/SFX Local Collection</source><creator>Maurin, Isabelle ; Itoi, Miho ; Cain, John M. ; Talham, Daniel R. ; Gacoin, Thierry ; Boukheddaden, Kamel ; Itié, Jean-Paul</creator><creatorcontrib>Maurin, Isabelle ; Itoi, Miho ; Cain, John M. ; Talham, Daniel R. ; Gacoin, Thierry ; Boukheddaden, Kamel ; Itié, Jean-Paul</creatorcontrib><description>We report the compressibility of two Prussian blue analogs (PBAs) under hydrostatic pressure, one with small and one with a relatively large cubic unit cell among PBAs, and investigate the modification of their elastic properties when the two lattices are coupled within a heteroepitaxial core–shell structure. Bulk modulus (K0) values are derived from x-ray powder diffraction experiments using a diamond anvil cell with silicone oil as a pressure-transmitting medium. The pressure–volume curves fitted to Murnaghan equations of states show that K0 inversely scales with the crystal packing for the rubidium cobalt hexacyanoferrate and rubidium nickel hexacyanochromate samples (K0 ∼ 29 GPa for Co-Fe PBA, a0 = 9.95 Å and ∼20 GPa for Ni-Cr PBA, a0 = 10.48 Å with a0 being the lattice constant at ambient pressure). The two single-phase samples undergo a cubic-to-rhombohedral phase transition above ∼0.8 GPa, which correlates fairly well with the build-up of nonhydrostatic pressure contributions in the cell. Within the core–shell structure, the volume change observed for the core scales with that of the shell because of the configuration close to the case of a solid pressure-transmitting medium. The Ni-Cr PBA shell layer exhibits an increased rhombohedral distortion with respect to the single-phase reference possibly associated with shearing at the core–shell interface. Its bulk modulus is not significantly modified with respect to that of the single-phase sample despite the presence of defects associated with the growth mode, whereas the P-V curve of the core suggests a stiffening of the Co-Fe PBA lattice.</description><identifier>ISSN: 0021-8979</identifier><identifier>EISSN: 1089-7550</identifier><identifier>DOI: 10.1063/5.0049223</identifier><identifier>CODEN: JAPIAU</identifier><language>eng</language><publisher>Melville: American Institute of Physics</publisher><subject>Analogs ; Applied physics ; Bulk modulus ; Chemical Sciences ; Cobalt ; Compressibility ; Condensed Matter ; Core-shell particles ; Core-shell structure ; Cristallography ; Crystal defects ; Cubic lattice ; Diamond anvil cells ; Elastic properties ; Hydrostatic pressure ; Iron ; Lattice parameters ; Material chemistry ; Nickel ; Phase transitions ; Physics ; Pigments ; Pressure ; Rubidium ; Shearing ; Shells ; Stiffening ; Transmission ; Unit cell ; X ray powder diffraction</subject><ispartof>Journal of applied physics, 2021-06, Vol.129 (23)</ispartof><rights>Author(s)</rights><rights>2021 Author(s). Published under an exclusive license by AIP Publishing.</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c462t-1f052c2e10c2421886f95665e39b484255f6240bea829140979eb7c89faa3acc3</citedby><cites>FETCH-LOGICAL-c462t-1f052c2e10c2421886f95665e39b484255f6240bea829140979eb7c89faa3acc3</cites><orcidid>0000-0003-1783-5285 ; 0000-0002-4296-8568 ; 0000-0001-7345-0983 ; 0000-0003-0464-1609 ; 0000-0001-6774-3181 ; 0000-0002-9992-9973</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://pubs.aip.org/jap/article-lookup/doi/10.1063/5.0049223$$EHTML$$P50$$Gscitation$$H</linktohtml><link.rule.ids>230,314,780,784,794,885,4512,27924,27925,76384</link.rule.ids><backlink>$$Uhttps://hal.science/hal-03286022$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Maurin, Isabelle</creatorcontrib><creatorcontrib>Itoi, Miho</creatorcontrib><creatorcontrib>Cain, John M.</creatorcontrib><creatorcontrib>Talham, Daniel R.</creatorcontrib><creatorcontrib>Gacoin, Thierry</creatorcontrib><creatorcontrib>Boukheddaden, Kamel</creatorcontrib><creatorcontrib>Itié, Jean-Paul</creatorcontrib><title>High-pressure behavior of heteroepitaxial core–shell particles made of Prussian blue analogs</title><title>Journal of applied physics</title><description>We report the compressibility of two Prussian blue analogs (PBAs) under hydrostatic pressure, one with small and one with a relatively large cubic unit cell among PBAs, and investigate the modification of their elastic properties when the two lattices are coupled within a heteroepitaxial core–shell structure. Bulk modulus (K0) values are derived from x-ray powder diffraction experiments using a diamond anvil cell with silicone oil as a pressure-transmitting medium. The pressure–volume curves fitted to Murnaghan equations of states show that K0 inversely scales with the crystal packing for the rubidium cobalt hexacyanoferrate and rubidium nickel hexacyanochromate samples (K0 ∼ 29 GPa for Co-Fe PBA, a0 = 9.95 Å and ∼20 GPa for Ni-Cr PBA, a0 = 10.48 Å with a0 being the lattice constant at ambient pressure). The two single-phase samples undergo a cubic-to-rhombohedral phase transition above ∼0.8 GPa, which correlates fairly well with the build-up of nonhydrostatic pressure contributions in the cell. Within the core–shell structure, the volume change observed for the core scales with that of the shell because of the configuration close to the case of a solid pressure-transmitting medium. The Ni-Cr PBA shell layer exhibits an increased rhombohedral distortion with respect to the single-phase reference possibly associated with shearing at the core–shell interface. Its bulk modulus is not significantly modified with respect to that of the single-phase sample despite the presence of defects associated with the growth mode, whereas the P-V curve of the core suggests a stiffening of the Co-Fe PBA lattice.</description><subject>Analogs</subject><subject>Applied physics</subject><subject>Bulk modulus</subject><subject>Chemical Sciences</subject><subject>Cobalt</subject><subject>Compressibility</subject><subject>Condensed Matter</subject><subject>Core-shell particles</subject><subject>Core-shell structure</subject><subject>Cristallography</subject><subject>Crystal defects</subject><subject>Cubic lattice</subject><subject>Diamond anvil cells</subject><subject>Elastic properties</subject><subject>Hydrostatic pressure</subject><subject>Iron</subject><subject>Lattice parameters</subject><subject>Material chemistry</subject><subject>Nickel</subject><subject>Phase transitions</subject><subject>Physics</subject><subject>Pigments</subject><subject>Pressure</subject><subject>Rubidium</subject><subject>Shearing</subject><subject>Shells</subject><subject>Stiffening</subject><subject>Transmission</subject><subject>Unit cell</subject><subject>X ray powder diffraction</subject><issn>0021-8979</issn><issn>1089-7550</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNqdkMFKw0AQhhdRsFYPvkHAk0Lq7Cab7h5LUSsU9KBXl8120mxJu3E3KXrzHXxDn8SEFnv3NDB8fP_MT8glhRGFLLnlI4BUMpYckQEFIeMx53BMBgCMxkKO5Sk5C2EFQKlI5IC8zeyyjGuPIbQeoxxLvbXOR66ISmzQO6xtoz-sriLjPP58fYcSqyqqtW-sqTBEa73AHn_2bQhWb6K8ajHSG125ZTgnJ4WuAl7s55C83t-9TGfx_OnhcTqZxybNWBPTAjgzDCkYljIqRFZInmUcE5mnImWcFxlLIUctmKQpdH9gPjZCFlon2phkSK533lJXqvZ2rf2nctqq2WSu-h0kTGTA2JZ27NWOrb17bzE0auVa390bFONdem-XB6PxLgSPxZ-WguqrVlztq-7Ymx0bTFdWY93mf_DW-QOo6kWR_AKS94x4</recordid><startdate>20210621</startdate><enddate>20210621</enddate><creator>Maurin, Isabelle</creator><creator>Itoi, Miho</creator><creator>Cain, John M.</creator><creator>Talham, Daniel R.</creator><creator>Gacoin, Thierry</creator><creator>Boukheddaden, Kamel</creator><creator>Itié, Jean-Paul</creator><general>American Institute of Physics</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FD</scope><scope>H8D</scope><scope>L7M</scope><scope>1XC</scope><scope>VOOES</scope><orcidid>https://orcid.org/0000-0003-1783-5285</orcidid><orcidid>https://orcid.org/0000-0002-4296-8568</orcidid><orcidid>https://orcid.org/0000-0001-7345-0983</orcidid><orcidid>https://orcid.org/0000-0003-0464-1609</orcidid><orcidid>https://orcid.org/0000-0001-6774-3181</orcidid><orcidid>https://orcid.org/0000-0002-9992-9973</orcidid></search><sort><creationdate>20210621</creationdate><title>High-pressure behavior of heteroepitaxial core–shell particles made of Prussian blue analogs</title><author>Maurin, Isabelle ; Itoi, Miho ; Cain, John M. ; Talham, Daniel R. ; Gacoin, Thierry ; Boukheddaden, Kamel ; Itié, Jean-Paul</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c462t-1f052c2e10c2421886f95665e39b484255f6240bea829140979eb7c89faa3acc3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Analogs</topic><topic>Applied physics</topic><topic>Bulk modulus</topic><topic>Chemical Sciences</topic><topic>Cobalt</topic><topic>Compressibility</topic><topic>Condensed Matter</topic><topic>Core-shell particles</topic><topic>Core-shell structure</topic><topic>Cristallography</topic><topic>Crystal defects</topic><topic>Cubic lattice</topic><topic>Diamond anvil cells</topic><topic>Elastic properties</topic><topic>Hydrostatic pressure</topic><topic>Iron</topic><topic>Lattice parameters</topic><topic>Material chemistry</topic><topic>Nickel</topic><topic>Phase transitions</topic><topic>Physics</topic><topic>Pigments</topic><topic>Pressure</topic><topic>Rubidium</topic><topic>Shearing</topic><topic>Shells</topic><topic>Stiffening</topic><topic>Transmission</topic><topic>Unit cell</topic><topic>X ray powder diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Maurin, Isabelle</creatorcontrib><creatorcontrib>Itoi, Miho</creatorcontrib><creatorcontrib>Cain, John M.</creatorcontrib><creatorcontrib>Talham, Daniel R.</creatorcontrib><creatorcontrib>Gacoin, Thierry</creatorcontrib><creatorcontrib>Boukheddaden, Kamel</creatorcontrib><creatorcontrib>Itié, Jean-Paul</creatorcontrib><collection>CrossRef</collection><collection>Technology Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Hyper Article en Ligne (HAL)</collection><collection>Hyper Article en Ligne (HAL) (Open Access)</collection><jtitle>Journal of applied physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Maurin, Isabelle</au><au>Itoi, Miho</au><au>Cain, John M.</au><au>Talham, Daniel R.</au><au>Gacoin, Thierry</au><au>Boukheddaden, Kamel</au><au>Itié, Jean-Paul</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>High-pressure behavior of heteroepitaxial core–shell particles made of Prussian blue analogs</atitle><jtitle>Journal of applied physics</jtitle><date>2021-06-21</date><risdate>2021</risdate><volume>129</volume><issue>23</issue><issn>0021-8979</issn><eissn>1089-7550</eissn><coden>JAPIAU</coden><abstract>We report the compressibility of two Prussian blue analogs (PBAs) under hydrostatic pressure, one with small and one with a relatively large cubic unit cell among PBAs, and investigate the modification of their elastic properties when the two lattices are coupled within a heteroepitaxial core–shell structure. Bulk modulus (K0) values are derived from x-ray powder diffraction experiments using a diamond anvil cell with silicone oil as a pressure-transmitting medium. The pressure–volume curves fitted to Murnaghan equations of states show that K0 inversely scales with the crystal packing for the rubidium cobalt hexacyanoferrate and rubidium nickel hexacyanochromate samples (K0 ∼ 29 GPa for Co-Fe PBA, a0 = 9.95 Å and ∼20 GPa for Ni-Cr PBA, a0 = 10.48 Å with a0 being the lattice constant at ambient pressure). The two single-phase samples undergo a cubic-to-rhombohedral phase transition above ∼0.8 GPa, which correlates fairly well with the build-up of nonhydrostatic pressure contributions in the cell. Within the core–shell structure, the volume change observed for the core scales with that of the shell because of the configuration close to the case of a solid pressure-transmitting medium. The Ni-Cr PBA shell layer exhibits an increased rhombohedral distortion with respect to the single-phase reference possibly associated with shearing at the core–shell interface. Its bulk modulus is not significantly modified with respect to that of the single-phase sample despite the presence of defects associated with the growth mode, whereas the P-V curve of the core suggests a stiffening of the Co-Fe PBA lattice.</abstract><cop>Melville</cop><pub>American Institute of Physics</pub><doi>10.1063/5.0049223</doi><tpages>10</tpages><orcidid>https://orcid.org/0000-0003-1783-5285</orcidid><orcidid>https://orcid.org/0000-0002-4296-8568</orcidid><orcidid>https://orcid.org/0000-0001-7345-0983</orcidid><orcidid>https://orcid.org/0000-0003-0464-1609</orcidid><orcidid>https://orcid.org/0000-0001-6774-3181</orcidid><orcidid>https://orcid.org/0000-0002-9992-9973</orcidid><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 0021-8979
ispartof Journal of applied physics, 2021-06, Vol.129 (23)
issn 0021-8979
1089-7550
language eng
recordid cdi_scitation_primary_10_1063_5_0049223
source AIP Journals Complete; Alma/SFX Local Collection
subjects Analogs
Applied physics
Bulk modulus
Chemical Sciences
Cobalt
Compressibility
Condensed Matter
Core-shell particles
Core-shell structure
Cristallography
Crystal defects
Cubic lattice
Diamond anvil cells
Elastic properties
Hydrostatic pressure
Iron
Lattice parameters
Material chemistry
Nickel
Phase transitions
Physics
Pigments
Pressure
Rubidium
Shearing
Shells
Stiffening
Transmission
Unit cell
X ray powder diffraction
title High-pressure behavior of heteroepitaxial core–shell particles made of Prussian blue analogs
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-03T22%3A43%3A02IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_scita&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=High-pressure%20behavior%20of%20heteroepitaxial%20core%E2%80%93shell%20particles%20made%20of%20Prussian%20blue%20analogs&rft.jtitle=Journal%20of%20applied%20physics&rft.au=Maurin,%20Isabelle&rft.date=2021-06-21&rft.volume=129&rft.issue=23&rft.issn=0021-8979&rft.eissn=1089-7550&rft.coden=JAPIAU&rft_id=info:doi/10.1063/5.0049223&rft_dat=%3Cproquest_scita%3E2542109799%3C/proquest_scita%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2542109799&rft_id=info:pmid/&rfr_iscdi=true