Quantum cutting-induced near-infrared luminescence of Yb3+ and Er3+ in a layer structured perovskite film
Quantum cutting is an attractive optical phenomenon where one high-energy photon is converted into two low-energy photons, resulting in photoluminescence quantum yields (PLQYs) above 100%. In this report, we demonstrate a novel approach to enhance the quantum cutting energy transfer from an all-inor...
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Veröffentlicht in: | The Journal of chemical physics 2020-11, Vol.153 (19), p.194704-194704 |
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description | Quantum cutting is an attractive optical phenomenon where one high-energy photon is converted into two low-energy photons, resulting in photoluminescence quantum yields (PLQYs) above 100%. In this report, we demonstrate a novel approach to enhance the quantum cutting energy transfer from an all-inorganic perovskite (CsPbCl3) to ytterbium (Yb3+) and erbium (Er3+) ions as near-infrared (NIR) emitters by using the highly orientated crystalline film. Yb3+ ions are fixed in the neighborhood of the CsPbCl3 lattice by preparing a one-to-one layer arrangement consisting of quasi-2D CsPbCl3 perovskite and Yb3+ layers. The successful preparation of layer arrangements resulted in the highly sensitized luminescence of Yb3+ by CsPbCl3 with NIR PLQYs exceeding 130%, which is attributed to quantum cutting. In addition, Er3+ luminescence at 1540 nm is acquired by the co-existence of Er3+ with Yb3+ in a layer, which is a result of the intralayer metal-to-metal energy transfer from Yb3+ activated by CsPbCl3 via the interlayer quantum cutting process. The PLQY of Er3+ luminescence reaches to 12.6%, which is the highest value ever observed for Er3+ compounds, resulting from the efficient interlayer quantum cutting process over 100% and the following intralayer resonance metal to metal energy transfer with the efficiency over 80%. |
doi_str_mv | 10.1063/5.0030596 |
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In this report, we demonstrate a novel approach to enhance the quantum cutting energy transfer from an all-inorganic perovskite (CsPbCl3) to ytterbium (Yb3+) and erbium (Er3+) ions as near-infrared (NIR) emitters by using the highly orientated crystalline film. Yb3+ ions are fixed in the neighborhood of the CsPbCl3 lattice by preparing a one-to-one layer arrangement consisting of quasi-2D CsPbCl3 perovskite and Yb3+ layers. The successful preparation of layer arrangements resulted in the highly sensitized luminescence of Yb3+ by CsPbCl3 with NIR PLQYs exceeding 130%, which is attributed to quantum cutting. In addition, Er3+ luminescence at 1540 nm is acquired by the co-existence of Er3+ with Yb3+ in a layer, which is a result of the intralayer metal-to-metal energy transfer from Yb3+ activated by CsPbCl3 via the interlayer quantum cutting process. The PLQY of Er3+ luminescence reaches to 12.6%, which is the highest value ever observed for Er3+ compounds, resulting from the efficient interlayer quantum cutting process over 100% and the following intralayer resonance metal to metal energy transfer with the efficiency over 80%.</description><identifier>ISSN: 0021-9606</identifier><identifier>EISSN: 1089-7690</identifier><identifier>DOI: 10.1063/5.0030596</identifier><identifier>CODEN: JCPSA6</identifier><language>eng</language><publisher>Melville: American Institute of Physics</publisher><subject>Cutting energy ; Emitters ; Energy conversion efficiency ; Energy transfer ; Erbium ; Interlayers ; Luminescence ; Near infrared radiation ; Perovskites ; Photoluminescence ; Photons ; Physics ; Ytterbium</subject><ispartof>The Journal of chemical physics, 2020-11, Vol.153 (19), p.194704-194704</ispartof><rights>Author(s)</rights><rights>2020 Author(s). 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In this report, we demonstrate a novel approach to enhance the quantum cutting energy transfer from an all-inorganic perovskite (CsPbCl3) to ytterbium (Yb3+) and erbium (Er3+) ions as near-infrared (NIR) emitters by using the highly orientated crystalline film. Yb3+ ions are fixed in the neighborhood of the CsPbCl3 lattice by preparing a one-to-one layer arrangement consisting of quasi-2D CsPbCl3 perovskite and Yb3+ layers. The successful preparation of layer arrangements resulted in the highly sensitized luminescence of Yb3+ by CsPbCl3 with NIR PLQYs exceeding 130%, which is attributed to quantum cutting. In addition, Er3+ luminescence at 1540 nm is acquired by the co-existence of Er3+ with Yb3+ in a layer, which is a result of the intralayer metal-to-metal energy transfer from Yb3+ activated by CsPbCl3 via the interlayer quantum cutting process. The PLQY of Er3+ luminescence reaches to 12.6%, which is the highest value ever observed for Er3+ compounds, resulting from the efficient interlayer quantum cutting process over 100% and the following intralayer resonance metal to metal energy transfer with the efficiency over 80%.</description><subject>Cutting energy</subject><subject>Emitters</subject><subject>Energy conversion efficiency</subject><subject>Energy transfer</subject><subject>Erbium</subject><subject>Interlayers</subject><subject>Luminescence</subject><subject>Near infrared radiation</subject><subject>Perovskites</subject><subject>Photoluminescence</subject><subject>Photons</subject><subject>Physics</subject><subject>Ytterbium</subject><issn>0021-9606</issn><issn>1089-7690</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNqd0EtLxDAQB_AgCq6rB79BwIsPuk6aNGmPsqwPWBBBD55KmqaStU1rHgv77W1ZQfDoaWbgN8PwR-icwIIAp7fZAoBCVvADNCOQF4ngBRyiGUBKkoIDP0Yn3m8AgIiUzZB5idKG2GEVQzD2IzG2jkrX2GrpxqFx0o1TGztjtVfaKo37Br9X9AZLW-OVGxtjscSt3GmHfXBRhTjtDNr1W_9pgsaNabtTdNTI1uuznzpHb_er1-Vjsn5-eFrerRNFMx6SmrA8Z5JkhRBNTYFlqRDAUi4yoCmrask1kzVtqFJMVLpSCgqS6pwxyinndI4u93cH139F7UPZmfHxtpVW99GXKeOUAM3IRC_-0E0fnR2_mxTheQo5HdXVXinXe-90Uw7OdNLtSgLlFHqZlT-hj_Z6b70yQQbT2__hbe9-YTnUDf0GKmqOPQ</recordid><startdate>20201121</startdate><enddate>20201121</enddate><creator>Ishii, Ayumi</creator><creator>Miyasaka, Tsutomu</creator><general>American Institute of Physics</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FD</scope><scope>H8D</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-8034-3710</orcidid><orcidid>https://orcid.org/0000-0001-8535-7911</orcidid></search><sort><creationdate>20201121</creationdate><title>Quantum cutting-induced near-infrared luminescence of Yb3+ and Er3+ in a layer structured perovskite film</title><author>Ishii, Ayumi ; Miyasaka, Tsutomu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c356t-d14884a15977fd30452770426750324bda6e4ad3f3cc47bebcc0912e844363663</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Cutting energy</topic><topic>Emitters</topic><topic>Energy conversion efficiency</topic><topic>Energy transfer</topic><topic>Erbium</topic><topic>Interlayers</topic><topic>Luminescence</topic><topic>Near infrared radiation</topic><topic>Perovskites</topic><topic>Photoluminescence</topic><topic>Photons</topic><topic>Physics</topic><topic>Ytterbium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ishii, Ayumi</creatorcontrib><creatorcontrib>Miyasaka, Tsutomu</creatorcontrib><collection>CrossRef</collection><collection>Technology Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>The Journal of chemical physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ishii, Ayumi</au><au>Miyasaka, Tsutomu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Quantum cutting-induced near-infrared luminescence of Yb3+ and Er3+ in a layer structured perovskite film</atitle><jtitle>The Journal of chemical physics</jtitle><date>2020-11-21</date><risdate>2020</risdate><volume>153</volume><issue>19</issue><spage>194704</spage><epage>194704</epage><pages>194704-194704</pages><issn>0021-9606</issn><eissn>1089-7690</eissn><coden>JCPSA6</coden><abstract>Quantum cutting is an attractive optical phenomenon where one high-energy photon is converted into two low-energy photons, resulting in photoluminescence quantum yields (PLQYs) above 100%. In this report, we demonstrate a novel approach to enhance the quantum cutting energy transfer from an all-inorganic perovskite (CsPbCl3) to ytterbium (Yb3+) and erbium (Er3+) ions as near-infrared (NIR) emitters by using the highly orientated crystalline film. Yb3+ ions are fixed in the neighborhood of the CsPbCl3 lattice by preparing a one-to-one layer arrangement consisting of quasi-2D CsPbCl3 perovskite and Yb3+ layers. The successful preparation of layer arrangements resulted in the highly sensitized luminescence of Yb3+ by CsPbCl3 with NIR PLQYs exceeding 130%, which is attributed to quantum cutting. In addition, Er3+ luminescence at 1540 nm is acquired by the co-existence of Er3+ with Yb3+ in a layer, which is a result of the intralayer metal-to-metal energy transfer from Yb3+ activated by CsPbCl3 via the interlayer quantum cutting process. The PLQY of Er3+ luminescence reaches to 12.6%, which is the highest value ever observed for Er3+ compounds, resulting from the efficient interlayer quantum cutting process over 100% and the following intralayer resonance metal to metal energy transfer with the efficiency over 80%.</abstract><cop>Melville</cop><pub>American Institute of Physics</pub><doi>10.1063/5.0030596</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0002-8034-3710</orcidid><orcidid>https://orcid.org/0000-0001-8535-7911</orcidid></addata></record> |
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subjects | Cutting energy Emitters Energy conversion efficiency Energy transfer Erbium Interlayers Luminescence Near infrared radiation Perovskites Photoluminescence Photons Physics Ytterbium |
title | Quantum cutting-induced near-infrared luminescence of Yb3+ and Er3+ in a layer structured perovskite film |
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