Performance of Indion ion exchange resin as solid catalyst for the esterification of oleic acid with glycerol
Glycerol Monooleate (GMO) is an emollient and emulsifier that is widely used in cosmetics and food products. GMOs are produced by esterification of oleic acid with glycerol. In this study, Indion Ion Exchange Resins were used to develop low-cost and efficient catalysts for esterification of oleic ac...
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description | Glycerol Monooleate (GMO) is an emollient and emulsifier that is widely used in cosmetics and food products. GMOs are produced by esterification of oleic acid with glycerol. In this study, Indion Ion Exchange Resins were used to develop low-cost and efficient catalysts for esterification of oleic acid with glycerol. The performance of catalyst was studied under various operating conditions (reaction temperature, the molar ratio of oleic acid to glycerol, and catalyst loading). Effect of the catalyst mass ratio on acid (1-5%), the molar ratio of oleic acid/glycerol (1: 1-1: 8), and the reaction temperature (120-170°C) on acid conversion were studied to obtain the optimal reaction conditions. The optimal condition was obtained on 5%wt of catalyst loading, the molar ratio of oleic acid/glycerol 1:3 at 170°C for 180 minutes. Under the optimal conditions, the prepared catalyst provides an acid conversion of 78%. |
doi_str_mv | 10.1063/1.5095045 |
format | Conference Proceeding |
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GMOs are produced by esterification of oleic acid with glycerol. In this study, Indion Ion Exchange Resins were used to develop low-cost and efficient catalysts for esterification of oleic acid with glycerol. The performance of catalyst was studied under various operating conditions (reaction temperature, the molar ratio of oleic acid to glycerol, and catalyst loading). Effect of the catalyst mass ratio on acid (1-5%), the molar ratio of oleic acid/glycerol (1: 1-1: 8), and the reaction temperature (120-170°C) on acid conversion were studied to obtain the optimal reaction conditions. The optimal condition was obtained on 5%wt of catalyst loading, the molar ratio of oleic acid/glycerol 1:3 at 170°C for 180 minutes. Under the optimal conditions, the prepared catalyst provides an acid conversion of 78%.</description><identifier>ISSN: 0094-243X</identifier><identifier>EISSN: 1551-7616</identifier><identifier>DOI: 10.1063/1.5095045</identifier><identifier>CODEN: APCPCS</identifier><language>eng</language><publisher>Melville: American Institute of Physics</publisher><subject>Acids ; Catalysis ; Catalysts ; Conversion ; Cosmetics ; Esterification ; Glycerol ; Ion exchange ; Ion exchange resins ; Oleic acid</subject><ispartof>AIP Conference Proceedings, 2019, Vol.2085 (1)</ispartof><rights>Author(s)</rights><rights>2019 Author(s). 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GMOs are produced by esterification of oleic acid with glycerol. In this study, Indion Ion Exchange Resins were used to develop low-cost and efficient catalysts for esterification of oleic acid with glycerol. The performance of catalyst was studied under various operating conditions (reaction temperature, the molar ratio of oleic acid to glycerol, and catalyst loading). Effect of the catalyst mass ratio on acid (1-5%), the molar ratio of oleic acid/glycerol (1: 1-1: 8), and the reaction temperature (120-170°C) on acid conversion were studied to obtain the optimal reaction conditions. The optimal condition was obtained on 5%wt of catalyst loading, the molar ratio of oleic acid/glycerol 1:3 at 170°C for 180 minutes. Under the optimal conditions, the prepared catalyst provides an acid conversion of 78%.</description><subject>Acids</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Conversion</subject><subject>Cosmetics</subject><subject>Esterification</subject><subject>Glycerol</subject><subject>Ion exchange</subject><subject>Ion exchange resins</subject><subject>Oleic acid</subject><issn>0094-243X</issn><issn>1551-7616</issn><fulltext>true</fulltext><rsrctype>conference_proceeding</rsrctype><creationdate>2019</creationdate><recordtype>conference_proceeding</recordtype><recordid>eNp9kE1LAzEQhoMoWKsH_0HAm7A12ST7cZTiFxT0oOAtTLOTNmW7WZOt2n9vagvePMzMYZ535p0h5JKzCWeFuOETxWrFpDoiI64Uz8qCF8dkxFgts1yK91NyFuOKsbwuy2pE1i8YrA9r6AxSb-lT1zjf0V3gt1lCt0AaMLqOQqTRt66hBgZot3GgSUeHJVKMAwZnXWrsdGmKb9EZCibRX25Y0kW7NRh8e05OLLQRLw51TN7u716nj9ns-eFpejvL-lyJIRN2booq5QoRQEHyWswt1JxLU5VsLmWNNp1ZCtVY0zCGCgqASkpkpUIlxuRqP7cP_mOT_OmV34QurdQ5r2VV51yJRF3vqWjc8Otd98GtIWw1Z3r3Ts314Z3_wZ8-_IG6b6z4AW3Qd2g</recordid><startdate>20190321</startdate><enddate>20190321</enddate><creator>Diana</creator><creator>Mukti, Nur Indah Fajar</creator><creator>Hidayat, Arif</creator><general>American Institute of Physics</general><scope>8FD</scope><scope>H8D</scope><scope>L7M</scope></search><sort><creationdate>20190321</creationdate><title>Performance of Indion ion exchange resin as solid catalyst for the esterification of oleic acid with glycerol</title><author>Diana ; Mukti, Nur Indah Fajar ; Hidayat, Arif</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p253t-3fbc683fb8eeaa5a2976bfa9114c870b449ef095735dfcd00e5a6aa844e075e53</frbrgroupid><rsrctype>conference_proceedings</rsrctype><prefilter>conference_proceedings</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Acids</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Conversion</topic><topic>Cosmetics</topic><topic>Esterification</topic><topic>Glycerol</topic><topic>Ion exchange</topic><topic>Ion exchange resins</topic><topic>Oleic acid</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Diana</creatorcontrib><creatorcontrib>Mukti, Nur Indah Fajar</creatorcontrib><creatorcontrib>Hidayat, Arif</creatorcontrib><collection>Technology Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Diana</au><au>Mukti, Nur Indah Fajar</au><au>Hidayat, Arif</au><au>Ariyanto, Teguh</au><au>Rochmadi</au><au>Prasetyo, Imam</au><au>Putri, Nur Rofiqoh Eviana</au><format>book</format><genre>proceeding</genre><ristype>CONF</ristype><atitle>Performance of Indion ion exchange resin as solid catalyst for the esterification of oleic acid with glycerol</atitle><btitle>AIP Conference Proceedings</btitle><date>2019-03-21</date><risdate>2019</risdate><volume>2085</volume><issue>1</issue><issn>0094-243X</issn><eissn>1551-7616</eissn><coden>APCPCS</coden><abstract>Glycerol Monooleate (GMO) is an emollient and emulsifier that is widely used in cosmetics and food products. GMOs are produced by esterification of oleic acid with glycerol. In this study, Indion Ion Exchange Resins were used to develop low-cost and efficient catalysts for esterification of oleic acid with glycerol. The performance of catalyst was studied under various operating conditions (reaction temperature, the molar ratio of oleic acid to glycerol, and catalyst loading). Effect of the catalyst mass ratio on acid (1-5%), the molar ratio of oleic acid/glycerol (1: 1-1: 8), and the reaction temperature (120-170°C) on acid conversion were studied to obtain the optimal reaction conditions. The optimal condition was obtained on 5%wt of catalyst loading, the molar ratio of oleic acid/glycerol 1:3 at 170°C for 180 minutes. Under the optimal conditions, the prepared catalyst provides an acid conversion of 78%.</abstract><cop>Melville</cop><pub>American Institute of Physics</pub><doi>10.1063/1.5095045</doi><tpages>5</tpages></addata></record> |
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issn | 0094-243X 1551-7616 |
language | eng |
recordid | cdi_scitation_primary_10_1063_1_5095045 |
source | AIP Journals Complete |
subjects | Acids Catalysis Catalysts Conversion Cosmetics Esterification Glycerol Ion exchange Ion exchange resins Oleic acid |
title | Performance of Indion ion exchange resin as solid catalyst for the esterification of oleic acid with glycerol |
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