Femtosecond dynamics of metal-centered and ligand-to-metal charge-transfer (t2g-based) electronic excited states in various solvents: A comprehensive study of IrBr62

The photophysical properties of intraconfigurational metal-centered (MC) and ligand-to-metal charge transfer (LMCT) states were studied in a prototype low spin heavy d5 transition metal complex, IrBr62−. The femtosecond-to-picosecond dynamics of this complex was investigated in solutions of drastica...

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Veröffentlicht in:	The Journal of chemical physics 2019-02, Vol.150 (5)
Hauptverfasser:	Matveev, Sergey M., Budkina, Darya S., Zheldakov, Igor L., Phelan, Michael R., Hicks, Christopher M., Tarnovsky, Alexander N.
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetonitrile Aqueous environments Aqueous solutions Broadband Charge transfer Chloroform Coordination compounds Electron transfer Energy transfer Excitation Internal conversion Jahn-Teller effect Ligands Orbital mechanics Polarity Spin-orbit interactions Transition metal compounds
Online-Zugang:	Volltext
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