Physical and structural properties of polyaniline/microcrystalline cellulose nanocomposite
A composite of Polyaniline/Microcrystalline Cellulose (PAni/MCC) was prepared via a chemical polymerization method in the presence of ammonium persulfate (NH4)2S2O8 as oxidant and cetyltrimethylammonium bromide (CTAB) as a cationic surfactant. The results of FESEM showed that the morphology of nanoc...
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| creator | Abdi, Mahnaz M. Liyana, Rawaida Tahir, Paridah Md Heng, Lee Yook Sulaiman, Yusran Waheeda, Nur Farhana Hassan, Nabihah Abu |
| description | A composite of Polyaniline/Microcrystalline Cellulose (PAni/MCC) was prepared via a chemical polymerization method in the presence of ammonium persulfate (NH4)2S2O8 as oxidant and cetyltrimethylammonium bromide (CTAB) as a cationic surfactant. The results of FESEM showed that the morphology of nanocomposite depends on the monomer concentration. Wire-like and porous nanostructure was observed for PAni/MCC/CTAB composite that could be suitable for enzyme immobilization and sensor applications. The electrochemical properties of the composites were studied using Cyclic Voltammetry (CV) and it was shown that PAni/MCC/CTAB composite generated a higher current response compared to the pure PAni. The synergy effect of MCC and CTAB on the physical and electrochemical properties of composite resulted in higher electron transferring in PAni/MCC/CTAB. The presence of significant peaks of PAni and MCC in FT-IR spectrum of nanocomposite indicating polymerization of aniline on the surface of MCC. Characteristic peaks of crystalline cellulose were observed at 22.8 and 14.7 2theta in XRD pattern. |
| doi_str_mv | 10.1063/1.5010540 |
| format | Conference Proceeding |
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The results of FESEM showed that the morphology of nanocomposite depends on the monomer concentration. Wire-like and porous nanostructure was observed for PAni/MCC/CTAB composite that could be suitable for enzyme immobilization and sensor applications. The electrochemical properties of the composites were studied using Cyclic Voltammetry (CV) and it was shown that PAni/MCC/CTAB composite generated a higher current response compared to the pure PAni. The synergy effect of MCC and CTAB on the physical and electrochemical properties of composite resulted in higher electron transferring in PAni/MCC/CTAB. The presence of significant peaks of PAni and MCC in FT-IR spectrum of nanocomposite indicating polymerization of aniline on the surface of MCC. Characteristic peaks of crystalline cellulose were observed at 22.8 and 14.7 2theta in XRD pattern.</description><identifier>ISSN: 0094-243X</identifier><identifier>EISSN: 1551-7616</identifier><identifier>DOI: 10.1063/1.5010540</identifier><identifier>CODEN: APCPCS</identifier><language>eng</language><publisher>Melville: American Institute of Physics</publisher><subject>Ammonium peroxodisulfate ; Aniline ; Cellulose ; Cetyltrimethylammonium bromide ; Crystalline cellulose ; Electrochemical analysis ; Morphology ; Nanocomposites ; Organic chemistry ; Oxidation ; Polyanilines ; Polymerization ; Properties (attributes)</subject><ispartof>AIP conference proceedings, 2017, Vol.1901 (1)</ispartof><rights>Author(s)</rights><rights>2017 Author(s). 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The results of FESEM showed that the morphology of nanocomposite depends on the monomer concentration. Wire-like and porous nanostructure was observed for PAni/MCC/CTAB composite that could be suitable for enzyme immobilization and sensor applications. The electrochemical properties of the composites were studied using Cyclic Voltammetry (CV) and it was shown that PAni/MCC/CTAB composite generated a higher current response compared to the pure PAni. The synergy effect of MCC and CTAB on the physical and electrochemical properties of composite resulted in higher electron transferring in PAni/MCC/CTAB. The presence of significant peaks of PAni and MCC in FT-IR spectrum of nanocomposite indicating polymerization of aniline on the surface of MCC. Characteristic peaks of crystalline cellulose were observed at 22.8 and 14.7 2theta in XRD pattern.</description><subject>Ammonium peroxodisulfate</subject><subject>Aniline</subject><subject>Cellulose</subject><subject>Cetyltrimethylammonium bromide</subject><subject>Crystalline cellulose</subject><subject>Electrochemical analysis</subject><subject>Morphology</subject><subject>Nanocomposites</subject><subject>Organic chemistry</subject><subject>Oxidation</subject><subject>Polyanilines</subject><subject>Polymerization</subject><subject>Properties (attributes)</subject><issn>0094-243X</issn><issn>1551-7616</issn><fulltext>true</fulltext><rsrctype>conference_proceeding</rsrctype><creationdate>2017</creationdate><recordtype>conference_proceeding</recordtype><recordid>eNp9kE9LxDAQxYMouK4e_AYFb0J3J02Tbo-y-A8W9KAgXkI6STFLtqlJKvTb22UXvHka3vBj3ptHyDWFBQXBlnTBgQIv4YTMKOc0rwQVp2QGUJd5UbKPc3IR4xagqKtqNSOfr19jtKhcpjqdxRQGTEOYZB98b0KyJma-zXrvRtVZZzuz3FkMHsMYk3L7RYbGucH5aLJOdR79rvfRJnNJzlrlork6zjl5f7h_Wz_lm5fH5_XdJseiZikXtNEMUDWqapiZRK1bgQprxLpUVJfAeFs1NfCKao6oVyAaBA1G64qvOJuTm8PdKfL3YGKSWz-EbrKUBaVi-pwWbKJuD1REm1SyvpN9sDsVRklB7ruTVB67-w_-8eEPlL1u2S_wmnLK</recordid><startdate>20171204</startdate><enddate>20171204</enddate><creator>Abdi, Mahnaz M.</creator><creator>Liyana, Rawaida</creator><creator>Tahir, Paridah Md</creator><creator>Heng, Lee Yook</creator><creator>Sulaiman, Yusran</creator><creator>Waheeda, Nur Farhana</creator><creator>Hassan, Nabihah Abu</creator><general>American Institute of Physics</general><scope>8FD</scope><scope>H8D</scope><scope>L7M</scope></search><sort><creationdate>20171204</creationdate><title>Physical and structural properties of polyaniline/microcrystalline cellulose nanocomposite</title><author>Abdi, Mahnaz M. ; Liyana, Rawaida ; Tahir, Paridah Md ; Heng, Lee Yook ; Sulaiman, Yusran ; Waheeda, Nur Farhana ; Hassan, Nabihah Abu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c293t-61bd30caba7b3e1bd9df6cac9cc94a1d4035f7b90571d5ccd806bc0d0edd75853</frbrgroupid><rsrctype>conference_proceedings</rsrctype><prefilter>conference_proceedings</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Ammonium peroxodisulfate</topic><topic>Aniline</topic><topic>Cellulose</topic><topic>Cetyltrimethylammonium bromide</topic><topic>Crystalline cellulose</topic><topic>Electrochemical analysis</topic><topic>Morphology</topic><topic>Nanocomposites</topic><topic>Organic chemistry</topic><topic>Oxidation</topic><topic>Polyanilines</topic><topic>Polymerization</topic><topic>Properties (attributes)</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Abdi, Mahnaz M.</creatorcontrib><creatorcontrib>Liyana, Rawaida</creatorcontrib><creatorcontrib>Tahir, Paridah Md</creatorcontrib><creatorcontrib>Heng, Lee Yook</creatorcontrib><creatorcontrib>Sulaiman, Yusran</creatorcontrib><creatorcontrib>Waheeda, Nur Farhana</creatorcontrib><creatorcontrib>Hassan, Nabihah Abu</creatorcontrib><collection>Technology Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Abdi, Mahnaz M.</au><au>Liyana, Rawaida</au><au>Tahir, Paridah Md</au><au>Heng, Lee Yook</au><au>Sulaiman, Yusran</au><au>Waheeda, Nur Farhana</au><au>Hassan, Nabihah Abu</au><au>Noorsal, Kartini</au><au>Ibrahim, Suhaina Mohd</au><format>book</format><genre>proceeding</genre><ristype>CONF</ristype><atitle>Physical and structural properties of polyaniline/microcrystalline cellulose nanocomposite</atitle><btitle>AIP conference proceedings</btitle><date>2017-12-04</date><risdate>2017</risdate><volume>1901</volume><issue>1</issue><issn>0094-243X</issn><eissn>1551-7616</eissn><coden>APCPCS</coden><abstract>A composite of Polyaniline/Microcrystalline Cellulose (PAni/MCC) was prepared via a chemical polymerization method in the presence of ammonium persulfate (NH4)2S2O8 as oxidant and cetyltrimethylammonium bromide (CTAB) as a cationic surfactant. The results of FESEM showed that the morphology of nanocomposite depends on the monomer concentration. Wire-like and porous nanostructure was observed for PAni/MCC/CTAB composite that could be suitable for enzyme immobilization and sensor applications. The electrochemical properties of the composites were studied using Cyclic Voltammetry (CV) and it was shown that PAni/MCC/CTAB composite generated a higher current response compared to the pure PAni. The synergy effect of MCC and CTAB on the physical and electrochemical properties of composite resulted in higher electron transferring in PAni/MCC/CTAB. The presence of significant peaks of PAni and MCC in FT-IR spectrum of nanocomposite indicating polymerization of aniline on the surface of MCC. Characteristic peaks of crystalline cellulose were observed at 22.8 and 14.7 2theta in XRD pattern.</abstract><cop>Melville</cop><pub>American Institute of Physics</pub><doi>10.1063/1.5010540</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0094-243X |
| ispartof | AIP conference proceedings, 2017, Vol.1901 (1) |
| issn | 0094-243X 1551-7616 |
| language | eng |
| recordid | cdi_scitation_primary_10_1063_1_5010540 |
| source | AIP Journals Complete |
| subjects | Ammonium peroxodisulfate Aniline Cellulose Cetyltrimethylammonium bromide Crystalline cellulose Electrochemical analysis Morphology Nanocomposites Organic chemistry Oxidation Polyanilines Polymerization Properties (attributes) |
| title | Physical and structural properties of polyaniline/microcrystalline cellulose nanocomposite |
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