Structural assignment of adenine aggregates in C D Cl 3

Structural assignment of adenine aggregates in C D Cl 3

We reinvestigated the self-association of 9-substituted adenine derivatives in C D Cl 3 solutions and present the infrared spectra of 9-ethyladenine and N -methyl-9-ethyladenine and its aggregates in the spectral regions between 1500 and 1800 cm − 1 and between 2700 and 3600 cm − 1 . Wavelength depe...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:The Journal of chemical physics 2008-05, Vol.128 (19), p.195103-195103-8
Hauptverfasser: Biemann, Lars, Häber, Thomas, Maydt, Daniela, Schaper, Klaus, Kleinermanns, Karl
Format: Artikel
Sprache:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 195103-8
container_issue 19
container_start_page 195103
container_title The Journal of chemical physics
container_volume 128
creator Biemann, Lars
Häber, Thomas
Maydt, Daniela
Schaper, Klaus
Kleinermanns, Karl
description We reinvestigated the self-association of 9-substituted adenine derivatives in C D Cl 3 solutions and present the infrared spectra of 9-ethyladenine and N -methyl-9-ethyladenine and its aggregates in the spectral regions between 1500 and 1800 cm − 1 and between 2700 and 3600 cm − 1 . Wavelength dependent absolute extinction coefficients of the monomer and dimers are presented on the basis of a simple deconvolution method. Comparison of the deconvoluted dimer spectra with quantum chemical calculations allows for a structural assignment of the two dimer structures that coexist in 9-ethyladenine/ C D Cl 3 solutions. In contrast, the dimer spectrum of N -methyl-9-ethyladenine is dominated by a single isomer.
doi_str_mv 10.1063/1.2912064
format Article
fullrecord <record><control><sourceid>scitation</sourceid><recordid>TN_cdi_scitation_primary_10_1063_1_2912064Structural_assignmen</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>scitation_primary_10_1063_1_2912064Structural_assignmen</sourcerecordid><originalsourceid>FETCH-scitation_primary_10_1063_1_2912064Structural_assignmen3</originalsourceid><addsrcrecordid>eNqljksKwjAUAIMoWD8Lb_AuUH0vLanduKmKe92HUNMQaVNJ0oW3F6HoAVzNbmYY2xBuCUW2oy0viaPIJywh3JdpIUqcsgSRU1oKFHO2COGBiFTwPGHFNfqhjoNXLagQrHGddhH6BtRdO-s0KGO8NirqANZBBUeoWshWbNaoNuj1yCU7nE-36pKG2kYVbe_k09tO-ZcklJ81SXJc-yXlN5n9LXgDtbVNow</addsrcrecordid><sourcetype>Publisher</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Structural assignment of adenine aggregates in C D Cl 3</title><source>AIP Journals Complete</source><source>AIP Digital Archive</source><source>Alma/SFX Local Collection</source><creator>Biemann, Lars ; Häber, Thomas ; Maydt, Daniela ; Schaper, Klaus ; Kleinermanns, Karl</creator><creatorcontrib>Biemann, Lars ; Häber, Thomas ; Maydt, Daniela ; Schaper, Klaus ; Kleinermanns, Karl</creatorcontrib><description>We reinvestigated the self-association of 9-substituted adenine derivatives in C D Cl 3 solutions and present the infrared spectra of 9-ethyladenine and N -methyl-9-ethyladenine and its aggregates in the spectral regions between 1500 and 1800 cm − 1 and between 2700 and 3600 cm − 1 . Wavelength dependent absolute extinction coefficients of the monomer and dimers are presented on the basis of a simple deconvolution method. Comparison of the deconvoluted dimer spectra with quantum chemical calculations allows for a structural assignment of the two dimer structures that coexist in 9-ethyladenine/ C D Cl 3 solutions. In contrast, the dimer spectrum of N -methyl-9-ethyladenine is dominated by a single isomer.</description><identifier>ISSN: 0021-9606</identifier><identifier>EISSN: 1089-7690</identifier><identifier>DOI: 10.1063/1.2912064</identifier><identifier>CODEN: JCPSA6</identifier><publisher>American Institute of Physics</publisher><ispartof>The Journal of chemical physics, 2008-05, Vol.128 (19), p.195103-195103-8</ispartof><rights>2008 American Institute of Physics</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-scitation_primary_10_1063_1_2912064Structural_assignmen3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,794,1559,4512,27924,27925</link.rule.ids></links><search><creatorcontrib>Biemann, Lars</creatorcontrib><creatorcontrib>Häber, Thomas</creatorcontrib><creatorcontrib>Maydt, Daniela</creatorcontrib><creatorcontrib>Schaper, Klaus</creatorcontrib><creatorcontrib>Kleinermanns, Karl</creatorcontrib><title>Structural assignment of adenine aggregates in C D Cl 3</title><title>The Journal of chemical physics</title><description>We reinvestigated the self-association of 9-substituted adenine derivatives in C D Cl 3 solutions and present the infrared spectra of 9-ethyladenine and N -methyl-9-ethyladenine and its aggregates in the spectral regions between 1500 and 1800 cm − 1 and between 2700 and 3600 cm − 1 . Wavelength dependent absolute extinction coefficients of the monomer and dimers are presented on the basis of a simple deconvolution method. Comparison of the deconvoluted dimer spectra with quantum chemical calculations allows for a structural assignment of the two dimer structures that coexist in 9-ethyladenine/ C D Cl 3 solutions. In contrast, the dimer spectrum of N -methyl-9-ethyladenine is dominated by a single isomer.</description><issn>0021-9606</issn><issn>1089-7690</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqljksKwjAUAIMoWD8Lb_AuUH0vLanduKmKe92HUNMQaVNJ0oW3F6HoAVzNbmYY2xBuCUW2oy0viaPIJywh3JdpIUqcsgSRU1oKFHO2COGBiFTwPGHFNfqhjoNXLagQrHGddhH6BtRdO-s0KGO8NirqANZBBUeoWshWbNaoNuj1yCU7nE-36pKG2kYVbe_k09tO-ZcklJ81SXJc-yXlN5n9LXgDtbVNow</recordid><startdate>20080520</startdate><enddate>20080520</enddate><creator>Biemann, Lars</creator><creator>Häber, Thomas</creator><creator>Maydt, Daniela</creator><creator>Schaper, Klaus</creator><creator>Kleinermanns, Karl</creator><general>American Institute of Physics</general><scope/></search><sort><creationdate>20080520</creationdate><title>Structural assignment of adenine aggregates in C D Cl 3</title><author>Biemann, Lars ; Häber, Thomas ; Maydt, Daniela ; Schaper, Klaus ; Kleinermanns, Karl</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-scitation_primary_10_1063_1_2912064Structural_assignmen3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><creationdate>2008</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Biemann, Lars</creatorcontrib><creatorcontrib>Häber, Thomas</creatorcontrib><creatorcontrib>Maydt, Daniela</creatorcontrib><creatorcontrib>Schaper, Klaus</creatorcontrib><creatorcontrib>Kleinermanns, Karl</creatorcontrib><jtitle>The Journal of chemical physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Biemann, Lars</au><au>Häber, Thomas</au><au>Maydt, Daniela</au><au>Schaper, Klaus</au><au>Kleinermanns, Karl</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Structural assignment of adenine aggregates in C D Cl 3</atitle><jtitle>The Journal of chemical physics</jtitle><date>2008-05-20</date><risdate>2008</risdate><volume>128</volume><issue>19</issue><spage>195103</spage><epage>195103-8</epage><pages>195103-195103-8</pages><issn>0021-9606</issn><eissn>1089-7690</eissn><coden>JCPSA6</coden><abstract>We reinvestigated the self-association of 9-substituted adenine derivatives in C D Cl 3 solutions and present the infrared spectra of 9-ethyladenine and N -methyl-9-ethyladenine and its aggregates in the spectral regions between 1500 and 1800 cm − 1 and between 2700 and 3600 cm − 1 . Wavelength dependent absolute extinction coefficients of the monomer and dimers are presented on the basis of a simple deconvolution method. Comparison of the deconvoluted dimer spectra with quantum chemical calculations allows for a structural assignment of the two dimer structures that coexist in 9-ethyladenine/ C D Cl 3 solutions. In contrast, the dimer spectrum of N -methyl-9-ethyladenine is dominated by a single isomer.</abstract><pub>American Institute of Physics</pub><doi>10.1063/1.2912064</doi></addata></record>
fulltext fulltext
identifier ISSN: 0021-9606
ispartof The Journal of chemical physics, 2008-05, Vol.128 (19), p.195103-195103-8
issn 0021-9606
1089-7690
language
recordid cdi_scitation_primary_10_1063_1_2912064Structural_assignmen
source AIP Journals Complete; AIP Digital Archive; Alma/SFX Local Collection
title Structural assignment of adenine aggregates in C D Cl 3
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-06T10%3A25%3A59IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-scitation&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Structural%20assignment%20of%20adenine%20aggregates%20in%20C%20D%20Cl%203&rft.jtitle=The%20Journal%20of%20chemical%20physics&rft.au=Biemann,%20Lars&rft.date=2008-05-20&rft.volume=128&rft.issue=19&rft.spage=195103&rft.epage=195103-8&rft.pages=195103-195103-8&rft.issn=0021-9606&rft.eissn=1089-7690&rft.coden=JCPSA6&rft_id=info:doi/10.1063/1.2912064&rft_dat=%3Cscitation%3Escitation_primary_10_1063_1_2912064Structural_assignmen%3C/scitation%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true