Vibrational structure, spin-orbit splitting, and bond dissociation energyof Cl 2 + ( X ̃ Π g 2 ) studied by zero kinetic energy photoelectron spectroscopyand ion-pair formation imaging method

The isotopomer-resolved vibrational and spin-orbit energy structures of Cl 2 + ( X ̃ Π g 2 ) have been studied by one-photon zero kinetic energy photoelectron spectroscopy. The spin-orbit energy splitting for the ground vibrational state is determined as 717.7 ± 1.5 cm − 1 , which greatly improves o...

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Veröffentlicht in:The Journal of chemical physics 2007-09, Vol.127 (10), p.104307-104307-8
Hauptverfasser: Li, Juan, Hao, Yusong, Yang, Jie, Zhou, Chang, Mo, Yuxiang
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