A cell for combined UV-visible and x-ray absorption spectroscopy studies under low-temperature and air exclusion conditions

A cell for combined UV-visible and x-ray absorption spectroscopy studies under low-temperature and air exclusion conditions

A measuring system that integrates a low-temperature optical cell UV-visible (UV-Vis) for air exclusion experiments with a liquid x-ray absorption spectroscopy (XAS) cell (x-ray absorption near-edge spectroscopy and extended x-ray absorption fine structure) is reported here together with its applica...

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Veröffentlicht in:Review of scientific instruments 2002-08, Vol.73 (8), p.2994-2998
Hauptverfasser: Sprakel, V. S. I., Feiters, M. C., Nolte, R. J. M., Hombergen, P. M. F. M., Groenen, A., De Haas, H. J. R.
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container_end_page 2998
container_issue 8
container_start_page 2994
container_title Review of scientific instruments
container_volume 73
creator Sprakel, V. S. I.
Feiters, M. C.
Nolte, R. J. M.
Hombergen, P. M. F. M.
Groenen, A.
De Haas, H. J. R.
description A measuring system that integrates a low-temperature optical cell UV-visible (UV-Vis) for air exclusion experiments with a liquid x-ray absorption spectroscopy (XAS) cell (x-ray absorption near-edge spectroscopy and extended x-ray absorption fine structure) is reported here together with its application in studies of organometallic complexes. UV-Vis measurements are performed in a three-compartment glass vessel, fitted with an external fiber optics probe. This UV-Vis cell is suitable for the measurement of oxygen- and air-sensitive compounds at variable temperatures (RT to −78 °C). The liquid XAS cell is filled with the UV-Vis solution at low temperature and can be used in both fluorescence- or transmission-mode measurements with (frozen) solutions. The complete measuring system is reusable and easy to clean and handle. To test the performance of these cells the oxygenation behavior of a dinuclear organometallic copper(I) complex was studied in acetone by UV-Vis and XAS. It is shown that direct correlation of low-temperature UV-Vis and XAS data is possible in organic solvents.
doi_str_mv 10.1063/1.1494869
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title A cell for combined UV-visible and x-ray absorption spectroscopy studies under low-temperature and air exclusion conditions
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