Fast neutral beam ion source coupled to a Fourier transform ion cyclotron resonance mass spectrometer
The coupling of an autoneutralizing SF− 6 fast ion‐beam gun to a Fourier transform ion cyclotron resonance (FT/ICR) mass spectrometer is described. The fast neutral beam provides for secondary‐ion‐type FT/ICR mass analysis [e.g., production of abundant pseudomolecular (M+H)+ ions] of involatile samp...
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| Veröffentlicht in: | Review of scientific instruments 1991-11, Vol.62 (11), p.2612-2617 |
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| container_title | Review of scientific instruments |
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| creator | Hill, Nicholas C. Limbach, Patrick A. Shomo, Ronald E. Marshall, Alan G. Appelhans, Anthony D. Delmore, James E. |
| description | The coupling of an autoneutralizing SF−
6 fast ion‐beam gun to a Fourier transform ion cyclotron resonance (FT/ICR) mass spectrometer is described. The fast neutral beam provides for secondary‐ion‐type FT/ICR mass analysis [e.g., production of abundant pseudomolecular (M+H)+ ions] of involatile samples without the need for external ion injection, since ions are formed at the entrance to the ICR ion trap. The design, construction, and testing of the hybrid instrument are described. The feasibility of the experiment (for both broadband and high‐resolution FT/ICR positive‐ion mass spectra) is demonstrated with tetra‐butylammonium bromide and a Tylenol■ sample. The ability to analyze high molecular weight polymers with high mass resolution is demonstrated for Teflon■. All of the advantages of the fast neutral beam ion source previously demonstrated with quadrupole mass analysis are preserved, and the additional advantages of FT/ICR mass analysis (e.g., high mass resolving power, ion trapping) are retained. |
| doi_str_mv | 10.1063/1.1142239 |
| format | Article |
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6 fast ion‐beam gun to a Fourier transform ion cyclotron resonance (FT/ICR) mass spectrometer is described. The fast neutral beam provides for secondary‐ion‐type FT/ICR mass analysis [e.g., production of abundant pseudomolecular (M+H)+ ions] of involatile samples without the need for external ion injection, since ions are formed at the entrance to the ICR ion trap. The design, construction, and testing of the hybrid instrument are described. The feasibility of the experiment (for both broadband and high‐resolution FT/ICR positive‐ion mass spectra) is demonstrated with tetra‐butylammonium bromide and a Tylenol■ sample. The ability to analyze high molecular weight polymers with high mass resolution is demonstrated for Teflon■. All of the advantages of the fast neutral beam ion source previously demonstrated with quadrupole mass analysis are preserved, and the additional advantages of FT/ICR mass analysis (e.g., high mass resolving power, ion trapping) are retained.</description><identifier>ISSN: 0034-6748</identifier><identifier>EISSN: 1089-7623</identifier><identifier>DOI: 10.1063/1.1142239</identifier><identifier>CODEN: RSINAK</identifier><language>eng</language><publisher>Woodbury, NY: American Institute of Physics</publisher><subject>440800 - Miscellaneous Instrumentation- (1990-) ; DESIGN ; Exact sciences and technology ; FLUORIDES ; FLUORINE COMPOUNDS ; FOURIER TRANSFORM SPECTROMETERS ; HALIDES ; HALOGEN COMPOUNDS ; Instruments, apparatus, components and techniques common to several branches of physics and astronomy ; ION CYCLOTRON RESONANCE SPECTROSCOPY ; ION SOURCES ; ION SPECTROSCOPY ; MASS SPECTROMETERS ; Mass spectrometers and related techniques ; MEASURING INSTRUMENTS ; NEUTRAL BEAM SOURCES ; OTHER INSTRUMENTATION ; Physics ; SPECTROMETERS ; SPECTROSCOPY ; SULFUR COMPOUNDS ; SULFUR FLUORIDES</subject><ispartof>Review of scientific instruments, 1991-11, Vol.62 (11), p.2612-2617</ispartof><rights>American Institute of Physics</rights><rights>1992 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c353t-758842c4051ade116335d156f3a2b63557dd5905d26d52fe230d597fb1bc941e3</citedby><cites>FETCH-LOGICAL-c353t-758842c4051ade116335d156f3a2b63557dd5905d26d52fe230d597fb1bc941e3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://pubs.aip.org/rsi/article-lookup/doi/10.1063/1.1142239$$EHTML$$P50$$Gscitation$$H</linktohtml><link.rule.ids>230,314,776,780,881,1553,27903,27904,76137</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=5503458$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/5043440$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Hill, Nicholas C.</creatorcontrib><creatorcontrib>Limbach, Patrick A.</creatorcontrib><creatorcontrib>Shomo, Ronald E.</creatorcontrib><creatorcontrib>Marshall, Alan G.</creatorcontrib><creatorcontrib>Appelhans, Anthony D.</creatorcontrib><creatorcontrib>Delmore, James E.</creatorcontrib><title>Fast neutral beam ion source coupled to a Fourier transform ion cyclotron resonance mass spectrometer</title><title>Review of scientific instruments</title><description>The coupling of an autoneutralizing SF−
6 fast ion‐beam gun to a Fourier transform ion cyclotron resonance (FT/ICR) mass spectrometer is described. The fast neutral beam provides for secondary‐ion‐type FT/ICR mass analysis [e.g., production of abundant pseudomolecular (M+H)+ ions] of involatile samples without the need for external ion injection, since ions are formed at the entrance to the ICR ion trap. The design, construction, and testing of the hybrid instrument are described. The feasibility of the experiment (for both broadband and high‐resolution FT/ICR positive‐ion mass spectra) is demonstrated with tetra‐butylammonium bromide and a Tylenol■ sample. The ability to analyze high molecular weight polymers with high mass resolution is demonstrated for Teflon■. All of the advantages of the fast neutral beam ion source previously demonstrated with quadrupole mass analysis are preserved, and the additional advantages of FT/ICR mass analysis (e.g., high mass resolving power, ion trapping) are retained.</description><subject>440800 - Miscellaneous Instrumentation- (1990-)</subject><subject>DESIGN</subject><subject>Exact sciences and technology</subject><subject>FLUORIDES</subject><subject>FLUORINE COMPOUNDS</subject><subject>FOURIER TRANSFORM SPECTROMETERS</subject><subject>HALIDES</subject><subject>HALOGEN COMPOUNDS</subject><subject>Instruments, apparatus, components and techniques common to several branches of physics and astronomy</subject><subject>ION CYCLOTRON RESONANCE SPECTROSCOPY</subject><subject>ION SOURCES</subject><subject>ION SPECTROSCOPY</subject><subject>MASS SPECTROMETERS</subject><subject>Mass spectrometers and related techniques</subject><subject>MEASURING INSTRUMENTS</subject><subject>NEUTRAL BEAM SOURCES</subject><subject>OTHER INSTRUMENTATION</subject><subject>Physics</subject><subject>SPECTROMETERS</subject><subject>SPECTROSCOPY</subject><subject>SULFUR COMPOUNDS</subject><subject>SULFUR FLUORIDES</subject><issn>0034-6748</issn><issn>1089-7623</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1991</creationdate><recordtype>article</recordtype><recordid>eNp9kEtLAzEUhYMoWKsL_0EQNwpT85zHUopVoeBG1yGTB45MJ0NuKvTfmzKlLgSzSe7lu-eeHISuKVlQUvIHuqBUMMabEzSjpG6KqmT8FM0I4aIoK1GfowuAL5KPpHSG3EpDwoPbpqh73Dq9wV0YMIRtNA6bsB17Z3EKWONV7nUu4kwO4EOcSLMzfUgxv6KDMOghj200AIbRmdzfuOTiJTrzugd3dbjn6GP19L58KdZvz6_Lx3VhuOSpqGRdC2ZEtqato7TkXFoqS881a0suZWWtbIi0rLSSecc4yXXlW9qaRlDH5-hm0g2QOgWmS858mjAM2YqSRHAhSIbuJsjEABCdV2PsNjruFCVqH6Ki6hBiZm8ndtRgdO_z100HxwEpc6yyztj9hO1X6pRzOSLfIf7qqdH6_-C_Bn4AsreM5Q</recordid><startdate>19911101</startdate><enddate>19911101</enddate><creator>Hill, Nicholas C.</creator><creator>Limbach, Patrick A.</creator><creator>Shomo, Ronald E.</creator><creator>Marshall, Alan G.</creator><creator>Appelhans, Anthony D.</creator><creator>Delmore, James E.</creator><general>American Institute of Physics</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>19911101</creationdate><title>Fast neutral beam ion source coupled to a Fourier transform ion cyclotron resonance mass spectrometer</title><author>Hill, Nicholas C. ; Limbach, Patrick A. ; Shomo, Ronald E. ; Marshall, Alan G. ; Appelhans, Anthony D. ; Delmore, James E.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c353t-758842c4051ade116335d156f3a2b63557dd5905d26d52fe230d597fb1bc941e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1991</creationdate><topic>440800 - Miscellaneous Instrumentation- (1990-)</topic><topic>DESIGN</topic><topic>Exact sciences and technology</topic><topic>FLUORIDES</topic><topic>FLUORINE COMPOUNDS</topic><topic>FOURIER TRANSFORM SPECTROMETERS</topic><topic>HALIDES</topic><topic>HALOGEN COMPOUNDS</topic><topic>Instruments, apparatus, components and techniques common to several branches of physics and astronomy</topic><topic>ION CYCLOTRON RESONANCE SPECTROSCOPY</topic><topic>ION SOURCES</topic><topic>ION SPECTROSCOPY</topic><topic>MASS SPECTROMETERS</topic><topic>Mass spectrometers and related techniques</topic><topic>MEASURING INSTRUMENTS</topic><topic>NEUTRAL BEAM SOURCES</topic><topic>OTHER INSTRUMENTATION</topic><topic>Physics</topic><topic>SPECTROMETERS</topic><topic>SPECTROSCOPY</topic><topic>SULFUR COMPOUNDS</topic><topic>SULFUR FLUORIDES</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hill, Nicholas C.</creatorcontrib><creatorcontrib>Limbach, Patrick A.</creatorcontrib><creatorcontrib>Shomo, Ronald E.</creatorcontrib><creatorcontrib>Marshall, Alan G.</creatorcontrib><creatorcontrib>Appelhans, Anthony D.</creatorcontrib><creatorcontrib>Delmore, James E.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>Review of scientific instruments</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hill, Nicholas C.</au><au>Limbach, Patrick A.</au><au>Shomo, Ronald E.</au><au>Marshall, Alan G.</au><au>Appelhans, Anthony D.</au><au>Delmore, James E.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Fast neutral beam ion source coupled to a Fourier transform ion cyclotron resonance mass spectrometer</atitle><jtitle>Review of scientific instruments</jtitle><date>1991-11-01</date><risdate>1991</risdate><volume>62</volume><issue>11</issue><spage>2612</spage><epage>2617</epage><pages>2612-2617</pages><issn>0034-6748</issn><eissn>1089-7623</eissn><coden>RSINAK</coden><abstract>The coupling of an autoneutralizing SF−
6 fast ion‐beam gun to a Fourier transform ion cyclotron resonance (FT/ICR) mass spectrometer is described. The fast neutral beam provides for secondary‐ion‐type FT/ICR mass analysis [e.g., production of abundant pseudomolecular (M+H)+ ions] of involatile samples without the need for external ion injection, since ions are formed at the entrance to the ICR ion trap. The design, construction, and testing of the hybrid instrument are described. The feasibility of the experiment (for both broadband and high‐resolution FT/ICR positive‐ion mass spectra) is demonstrated with tetra‐butylammonium bromide and a Tylenol■ sample. The ability to analyze high molecular weight polymers with high mass resolution is demonstrated for Teflon■. All of the advantages of the fast neutral beam ion source previously demonstrated with quadrupole mass analysis are preserved, and the additional advantages of FT/ICR mass analysis (e.g., high mass resolving power, ion trapping) are retained.</abstract><cop>Woodbury, NY</cop><pub>American Institute of Physics</pub><doi>10.1063/1.1142239</doi><tpages>6</tpages></addata></record> |
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| ispartof | Review of scientific instruments, 1991-11, Vol.62 (11), p.2612-2617 |
| issn | 0034-6748 1089-7623 |
| language | eng |
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| source | AIP Digital Archive |
| subjects | 440800 - Miscellaneous Instrumentation- (1990-) DESIGN Exact sciences and technology FLUORIDES FLUORINE COMPOUNDS FOURIER TRANSFORM SPECTROMETERS HALIDES HALOGEN COMPOUNDS Instruments, apparatus, components and techniques common to several branches of physics and astronomy ION CYCLOTRON RESONANCE SPECTROSCOPY ION SOURCES ION SPECTROSCOPY MASS SPECTROMETERS Mass spectrometers and related techniques MEASURING INSTRUMENTS NEUTRAL BEAM SOURCES OTHER INSTRUMENTATION Physics SPECTROMETERS SPECTROSCOPY SULFUR COMPOUNDS SULFUR FLUORIDES |
| title | Fast neutral beam ion source coupled to a Fourier transform ion cyclotron resonance mass spectrometer |
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