A new route to keto and alkyl derivatives of (R)-carvone via diastereoselective conjugate addition of nitronate ions

The reactivity and diastereoselectivity of conjugate addition of different nitronates ions to (R)-carvone was systematically studied. The Michael adducts 2a-e were obtained in good yield and 3,2-cis-3,5-trans selectivity. The nitroadducts 2b,c were transformed via Nef reaction into (R)-carvone keton...

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Veröffentlicht in:	Journal of the Brazilian Chemical Society 2006-12, Vol.17 (7), p.1229-1232
Hauptverfasser:	Costa, Jeronimo S., Freire, Bruno S., Moura, André L. S., Pereira, Vera L. Patrocinio
Format:	Artikel
Sprache:	eng
Schlagworte:	CHEMISTRY, MULTIDISCIPLINARY
Online-Zugang:	Volltext
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