Experimental investigation into radiative heat transfer characteristics for mould fluxes containing transition oxides

Infrared transmittance of glassy and crystalline mould fluxes was measured using a Fourier transform infrared spectrometer at room temperature. Radiation heat transfer from the steel shell to the mould was calculated by a model. The results indicate that transition metal oxides MnO, FeO and TiO 2 ha...

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Veröffentlicht in:Ironmaking & steelmaking 2009-11, Vol.36 (8), p.610-614
Hauptverfasser: Diao, J., Xie, B., Xiao, J. P.
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Xiao, J. P.
description Infrared transmittance of glassy and crystalline mould fluxes was measured using a Fourier transform infrared spectrometer at room temperature. Radiation heat transfer from the steel shell to the mould was calculated by a model. The results indicate that transition metal oxides MnO, FeO and TiO 2 have a marked negative effect on infrared transmittance and radiation heat flux of glassy samples. With MnO, FeO and TiO 2 added, the reductions of radiation heat flux in glassy samples are 19-25%, 34-36%, 6-29% respectively. X-ray diffraction results indicated that the crystalline phase in transition oxides free samples was mainly Ca 4 Si 2 O 7 F 2 . After transition oxides MnO, FeO and TiO 2 added, Mn 2 SiO 4 , Fe 2 SiO 4 , CaTiO 3 , Ca 2 SiO 4 and other minor phases were also precipitated in mould fluxes. On account of strong refraction and scattering, the negative effect on radiation heat flux in crystalline samples was much larger than that in the glassy ones.
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P.</creatorcontrib><title>Experimental investigation into radiative heat transfer characteristics for mould fluxes containing transition oxides</title><title>Ironmaking &amp; steelmaking</title><description>Infrared transmittance of glassy and crystalline mould fluxes was measured using a Fourier transform infrared spectrometer at room temperature. Radiation heat transfer from the steel shell to the mould was calculated by a model. The results indicate that transition metal oxides MnO, FeO and TiO 2 have a marked negative effect on infrared transmittance and radiation heat flux of glassy samples. With MnO, FeO and TiO 2 added, the reductions of radiation heat flux in glassy samples are 19-25%, 34-36%, 6-29% respectively. X-ray diffraction results indicated that the crystalline phase in transition oxides free samples was mainly Ca 4 Si 2 O 7 F 2 . After transition oxides MnO, FeO and TiO 2 added, Mn 2 SiO 4 , Fe 2 SiO 4 , CaTiO 3 , Ca 2 SiO 4 and other minor phases were also precipitated in mould fluxes. 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P.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Experimental investigation into radiative heat transfer characteristics for mould fluxes containing transition oxides</atitle><jtitle>Ironmaking &amp; steelmaking</jtitle><date>2009-11-01</date><risdate>2009</risdate><volume>36</volume><issue>8</issue><spage>610</spage><epage>614</epage><pages>610-614</pages><issn>0301-9233</issn><eissn>1743-2812</eissn><coden>IMKSB7</coden><abstract>Infrared transmittance of glassy and crystalline mould fluxes was measured using a Fourier transform infrared spectrometer at room temperature. Radiation heat transfer from the steel shell to the mould was calculated by a model. The results indicate that transition metal oxides MnO, FeO and TiO 2 have a marked negative effect on infrared transmittance and radiation heat flux of glassy samples. With MnO, FeO and TiO 2 added, the reductions of radiation heat flux in glassy samples are 19-25%, 34-36%, 6-29% respectively. X-ray diffraction results indicated that the crystalline phase in transition oxides free samples was mainly Ca 4 Si 2 O 7 F 2 . After transition oxides MnO, FeO and TiO 2 added, Mn 2 SiO 4 , Fe 2 SiO 4 , CaTiO 3 , Ca 2 SiO 4 and other minor phases were also precipitated in mould fluxes. On account of strong refraction and scattering, the negative effect on radiation heat flux in crystalline samples was much larger than that in the glassy ones.</abstract><cop>London, England</cop><pub>Taylor &amp; Francis</pub><doi>10.1179/030192309X12492910938096</doi><tpages>5</tpages></addata></record>
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subjects CONTINUOUS CASTING
Crystal structure
Energy
Experiments
Fluxes
Fourier transforms
Glassy
Heat flux
Heat transfer
Ligands
Metal oxides
Molds
Molecular structure
MOULD FLUXES
Oxidation
Oxides
Production capacity
Radiation
RADIATION HEAT FLUX
RADIATIVE HEAT TRANSFER
Steel
Studies
Temperature
Titanium dioxide
TRANSITION METAL OXIDES
title Experimental investigation into radiative heat transfer characteristics for mould fluxes containing transition oxides
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