Experimental investigation into radiative heat transfer characteristics for mould fluxes containing transition oxides
Infrared transmittance of glassy and crystalline mould fluxes was measured using a Fourier transform infrared spectrometer at room temperature. Radiation heat transfer from the steel shell to the mould was calculated by a model. The results indicate that transition metal oxides MnO, FeO and TiO 2 ha...
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Veröffentlicht in: | Ironmaking & steelmaking 2009-11, Vol.36 (8), p.610-614 |
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creator | Diao, J. Xie, B. Xiao, J. P. |
description | Infrared transmittance of glassy and crystalline mould fluxes was measured using a Fourier transform infrared spectrometer at room temperature. Radiation heat transfer from the steel shell to the mould was calculated by a model. The results indicate that transition metal oxides MnO, FeO and TiO
2
have a marked negative effect on infrared transmittance and radiation heat flux of glassy samples. With MnO, FeO and TiO
2
added, the reductions of radiation heat flux in glassy samples are 19-25%, 34-36%, 6-29% respectively. X-ray diffraction results indicated that the crystalline phase in transition oxides free samples was mainly Ca
4
Si
2
O
7
F
2
. After transition oxides MnO, FeO and TiO
2
added, Mn
2
SiO
4
, Fe
2
SiO
4
, CaTiO
3
, Ca
2
SiO
4
and other minor phases were also precipitated in mould fluxes. On account of strong refraction and scattering, the negative effect on radiation heat flux in crystalline samples was much larger than that in the glassy ones. |
doi_str_mv | 10.1179/030192309X12492910938096 |
format | Article |
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2
have a marked negative effect on infrared transmittance and radiation heat flux of glassy samples. With MnO, FeO and TiO
2
added, the reductions of radiation heat flux in glassy samples are 19-25%, 34-36%, 6-29% respectively. X-ray diffraction results indicated that the crystalline phase in transition oxides free samples was mainly Ca
4
Si
2
O
7
F
2
. After transition oxides MnO, FeO and TiO
2
added, Mn
2
SiO
4
, Fe
2
SiO
4
, CaTiO
3
, Ca
2
SiO
4
and other minor phases were also precipitated in mould fluxes. On account of strong refraction and scattering, the negative effect on radiation heat flux in crystalline samples was much larger than that in the glassy ones.</description><identifier>ISSN: 0301-9233</identifier><identifier>EISSN: 1743-2812</identifier><identifier>DOI: 10.1179/030192309X12492910938096</identifier><identifier>CODEN: IMKSB7</identifier><language>eng</language><publisher>London, England: Taylor & Francis</publisher><subject>CONTINUOUS CASTING ; Crystal structure ; Energy ; Experiments ; Fluxes ; Fourier transforms ; Glassy ; Heat flux ; Heat transfer ; Ligands ; Metal oxides ; Molds ; Molecular structure ; MOULD FLUXES ; Oxidation ; Oxides ; Production capacity ; Radiation ; RADIATION HEAT FLUX ; RADIATIVE HEAT TRANSFER ; Steel ; Studies ; Temperature ; Titanium dioxide ; TRANSITION METAL OXIDES</subject><ispartof>Ironmaking & steelmaking, 2009-11, Vol.36 (8), p.610-614</ispartof><rights>2009 Maney Publishing 2009</rights><rights>2009 Maney Publishing</rights><rights>Copyright Maney Publishing 2009</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c424t-f8e44d1b05fa63f4d5656114e5071068ec9d80125ef5f4c68cfb1234ecb62763</citedby><cites>FETCH-LOGICAL-c424t-f8e44d1b05fa63f4d5656114e5071068ec9d80125ef5f4c68cfb1234ecb62763</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://journals.sagepub.com/doi/pdf/10.1179/030192309X12492910938096$$EPDF$$P50$$Gsage$$H</linktopdf><linktohtml>$$Uhttps://journals.sagepub.com/doi/10.1179/030192309X12492910938096$$EHTML$$P50$$Gsage$$H</linktohtml><link.rule.ids>314,778,782,21802,27907,27908,43604,43605</link.rule.ids></links><search><creatorcontrib>Diao, J.</creatorcontrib><creatorcontrib>Xie, B.</creatorcontrib><creatorcontrib>Xiao, J. P.</creatorcontrib><title>Experimental investigation into radiative heat transfer characteristics for mould fluxes containing transition oxides</title><title>Ironmaking & steelmaking</title><description>Infrared transmittance of glassy and crystalline mould fluxes was measured using a Fourier transform infrared spectrometer at room temperature. Radiation heat transfer from the steel shell to the mould was calculated by a model. The results indicate that transition metal oxides MnO, FeO and TiO
2
have a marked negative effect on infrared transmittance and radiation heat flux of glassy samples. With MnO, FeO and TiO
2
added, the reductions of radiation heat flux in glassy samples are 19-25%, 34-36%, 6-29% respectively. X-ray diffraction results indicated that the crystalline phase in transition oxides free samples was mainly Ca
4
Si
2
O
7
F
2
. After transition oxides MnO, FeO and TiO
2
added, Mn
2
SiO
4
, Fe
2
SiO
4
, CaTiO
3
, Ca
2
SiO
4
and other minor phases were also precipitated in mould fluxes. On account of strong refraction and scattering, the negative effect on radiation heat flux in crystalline samples was much larger than that in the glassy ones.</description><subject>CONTINUOUS CASTING</subject><subject>Crystal structure</subject><subject>Energy</subject><subject>Experiments</subject><subject>Fluxes</subject><subject>Fourier transforms</subject><subject>Glassy</subject><subject>Heat flux</subject><subject>Heat transfer</subject><subject>Ligands</subject><subject>Metal oxides</subject><subject>Molds</subject><subject>Molecular structure</subject><subject>MOULD FLUXES</subject><subject>Oxidation</subject><subject>Oxides</subject><subject>Production capacity</subject><subject>Radiation</subject><subject>RADIATION HEAT FLUX</subject><subject>RADIATIVE HEAT TRANSFER</subject><subject>Steel</subject><subject>Studies</subject><subject>Temperature</subject><subject>Titanium dioxide</subject><subject>TRANSITION METAL OXIDES</subject><issn>0301-9233</issn><issn>1743-2812</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNqNkc1qGzEURkVpoG6adxDddDWN_kajWRaTpoVANl50J2TNlS0zlhxJk9pvH7kTCARCsxIXvnO4-i5CmJLvlHb9NeGE9oyT_g9lomc9JT1XpJcf0IJ2gjdMUfYRLc6xpub4J_Q55x0hpOtYt0DTzfEAye8hFDNiHx4hF78xxcdQpxJxMoOv4yPgLZiCSzIhO0jYbk0ytlS2AjZjFxPex2kcsBunI2RsY1X64MNmhvw_Zzz6AfIXdOHMmOHq-b1Eq583q-Wv5u7-9vfyx11jBROlcQqEGOiatM5I7sTQylZSKqAlHSVSge0HRShrwbVOWKmsW1PGBdi1ZJ3kl-jbrD2k-DDVn-m9zxbG0QSIU9ZKESk5b2lNfn2V3MUphbqbZlwKzqU669QcsinmnMDpQ23OpJOmRJ-Pod86RkXbGc1mAy_ud3DLmfOhFrw3f2MaB13MaYzJ1Vatz5r_1_IEFsei7Q</recordid><startdate>20091101</startdate><enddate>20091101</enddate><creator>Diao, J.</creator><creator>Xie, B.</creator><creator>Xiao, J. P.</creator><general>Taylor & Francis</general><general>SAGE Publications</general><general>Taylor & Francis Ltd</general><scope>AAYXX</scope><scope>CITATION</scope><scope>0U~</scope><scope>1-H</scope><scope>3V.</scope><scope>7RQ</scope><scope>7WY</scope><scope>7XB</scope><scope>883</scope><scope>8FE</scope><scope>8FG</scope><scope>8FK</scope><scope>8FL</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BEZIV</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>FRNLG</scope><scope>HCIFZ</scope><scope>K60</scope><scope>K6~</scope><scope>KB.</scope><scope>L.-</scope><scope>L.0</scope><scope>M0F</scope><scope>PDBOC</scope><scope>PQBIZ</scope><scope>PQBZA</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PYYUZ</scope><scope>Q9U</scope><scope>U9A</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20091101</creationdate><title>Experimental investigation into radiative heat transfer characteristics for mould fluxes containing transition oxides</title><author>Diao, J. ; Xie, B. ; Xiao, J. P.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c424t-f8e44d1b05fa63f4d5656114e5071068ec9d80125ef5f4c68cfb1234ecb62763</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>CONTINUOUS CASTING</topic><topic>Crystal structure</topic><topic>Energy</topic><topic>Experiments</topic><topic>Fluxes</topic><topic>Fourier transforms</topic><topic>Glassy</topic><topic>Heat flux</topic><topic>Heat transfer</topic><topic>Ligands</topic><topic>Metal oxides</topic><topic>Molds</topic><topic>Molecular structure</topic><topic>MOULD FLUXES</topic><topic>Oxidation</topic><topic>Oxides</topic><topic>Production capacity</topic><topic>Radiation</topic><topic>RADIATION HEAT FLUX</topic><topic>RADIATIVE HEAT TRANSFER</topic><topic>Steel</topic><topic>Studies</topic><topic>Temperature</topic><topic>Titanium dioxide</topic><topic>TRANSITION METAL OXIDES</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Diao, J.</creatorcontrib><creatorcontrib>Xie, B.</creatorcontrib><creatorcontrib>Xiao, J. P.</creatorcontrib><collection>CrossRef</collection><collection>Global News & ABI/Inform Professional</collection><collection>Trade PRO</collection><collection>ProQuest Central (Corporate)</collection><collection>Career & Technical Education Database</collection><collection>ABI/INFORM Collection</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>ABI/INFORM Trade & Industry (Alumni Edition)</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>ABI/INFORM Collection (Alumni Edition)</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Business Premium Collection</collection><collection>Technology Collection (ProQuest)</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>Business Premium Collection (Alumni)</collection><collection>SciTech Premium Collection</collection><collection>ProQuest Business Collection (Alumni Edition)</collection><collection>ProQuest Business Collection</collection><collection>Materials Science Database</collection><collection>ABI/INFORM Professional Advanced</collection><collection>ABI/INFORM Professional Standard</collection><collection>ABI/INFORM Trade & Industry</collection><collection>Materials Science Collection</collection><collection>ProQuest One Business</collection><collection>ProQuest One Business (Alumni)</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>ABI/INFORM Collection China</collection><collection>ProQuest Central Basic</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Ironmaking & steelmaking</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Diao, J.</au><au>Xie, B.</au><au>Xiao, J. P.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Experimental investigation into radiative heat transfer characteristics for mould fluxes containing transition oxides</atitle><jtitle>Ironmaking & steelmaking</jtitle><date>2009-11-01</date><risdate>2009</risdate><volume>36</volume><issue>8</issue><spage>610</spage><epage>614</epage><pages>610-614</pages><issn>0301-9233</issn><eissn>1743-2812</eissn><coden>IMKSB7</coden><abstract>Infrared transmittance of glassy and crystalline mould fluxes was measured using a Fourier transform infrared spectrometer at room temperature. Radiation heat transfer from the steel shell to the mould was calculated by a model. The results indicate that transition metal oxides MnO, FeO and TiO
2
have a marked negative effect on infrared transmittance and radiation heat flux of glassy samples. With MnO, FeO and TiO
2
added, the reductions of radiation heat flux in glassy samples are 19-25%, 34-36%, 6-29% respectively. X-ray diffraction results indicated that the crystalline phase in transition oxides free samples was mainly Ca
4
Si
2
O
7
F
2
. After transition oxides MnO, FeO and TiO
2
added, Mn
2
SiO
4
, Fe
2
SiO
4
, CaTiO
3
, Ca
2
SiO
4
and other minor phases were also precipitated in mould fluxes. On account of strong refraction and scattering, the negative effect on radiation heat flux in crystalline samples was much larger than that in the glassy ones.</abstract><cop>London, England</cop><pub>Taylor & Francis</pub><doi>10.1179/030192309X12492910938096</doi><tpages>5</tpages></addata></record> |
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language | eng |
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source | SAGE Complete A-Z List |
subjects | CONTINUOUS CASTING Crystal structure Energy Experiments Fluxes Fourier transforms Glassy Heat flux Heat transfer Ligands Metal oxides Molds Molecular structure MOULD FLUXES Oxidation Oxides Production capacity Radiation RADIATION HEAT FLUX RADIATIVE HEAT TRANSFER Steel Studies Temperature Titanium dioxide TRANSITION METAL OXIDES |
title | Experimental investigation into radiative heat transfer characteristics for mould fluxes containing transition oxides |
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