Temperature-insensitive high piezoelectricity in a (BiK)TiO-PbTiO-PbZrO ternary system

Piezoelectric actuators operating in harsh environments require piezoelectric ceramics with high and temperature-insensitive piezoelectric responses, which poses a significant challenge due to the inverse correlation between the piezoelectric d 33 and the Curie temperature ( T C ). In this study, a novel ternary system of Bi 0.5 K 0.5 TiO 3 -PbTiO 3 -PbZrO 3 (BKT-PT-PZ) is explored for high-temperature piezoelectric materials by considering the local structural heterogeneity and tolerance factor. The ferroelectric, piezoelectric, and dielectric properties, phase structure and temperature stability of x BKT-0.32PT-(0.68 − x )PZ (0.13 ≤ x ≤ 0.17) are systematically studied. The optimal piezoelectric d 33 value exceeding 350 pC N −1 , maintained up to 320 °C, is achieved at x = 0.15. Significantly, a large strain of 0.24% is obtained at 4 kV mm −1 , corresponding to a piezoelectric strain response of 682 pm V −1 . The strain variation within 20% observed in the range of 25-275 °C demonstrates excellent temperature stability. In situ high-energy synchrotron X-ray diffraction (SXRD) and piezoresponse force microscopy (PFM) indicate that the lattice strain and stable nanosized domains (up to 200 °C) is contributed to the high piezoelectricity and excellent temperature-insensitive properties, respectively. This outstanding feature positions it as a strong candidate for the next generation of piezoelectric actuators. A d 33 value exceeding 350 pC N −1 , maintained up to 320 °C, and a large strain of 0.29% within 20% variation are achieved in a novel system of BKT-PT-PZ. The stable nanosized domains contribute to the temperature-insensitive high piezoelectricity.