Synthesis of MCM-41 mesoporous molecular sieves based on recycled glass fibers from waste fan blades

The development of clean energy leads to a significant increase in decommissioned wind turbine blades, which have become a new type of solid waste. Glass fiber, which is the main component of these blades, can be recycled through pyrolysis. However, the deficiencies in size and mechanical properties...

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Veröffentlicht in:Sustainable energy & fuels 2024-11, Vol.8 (23), p.5484-5491
Hauptverfasser: Wang, Nianxuan, Wang, Song, Zhuang, Ke, Xu, Yun, Zeng, Dewang, Zhou, Kai, Zhang, Qian, Xiao, Rui, Xu, Jingxin
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container_end_page 5491
container_issue 23
container_start_page 5484
container_title Sustainable energy & fuels
container_volume 8
creator Wang, Nianxuan
Wang, Song
Zhuang, Ke
Xu, Yun
Zeng, Dewang
Zhou, Kai
Zhang, Qian
Xiao, Rui
Xu, Jingxin
description The development of clean energy leads to a significant increase in decommissioned wind turbine blades, which have become a new type of solid waste. Glass fiber, which is the main component of these blades, can be recycled through pyrolysis. However, the deficiencies in size and mechanical properties of recycled glass fibers preclude their further high-value utilization. This paper presents an innovative approach to the high-value utilization of recycled glass fibers as Si and Al sources for the synthesis of Si-Al MCM-41 mesoporous molecular sieves by the alkali fusion-hydrothermal method. The influences of the templating agent ratio, water ratio, pH, hydrothermal temperature, and hydrothermal time on the synthesis of molecular sieves during the hydrothermal synthesis process were investigated. The results show that the MCM-41 molecular sieve synthesized under optimal conditions exhibited a uniform mesoporous structure, with a specific surface area of 831 m 2 g −1 and a uniform distribution of Si and Al elements. Additionally, it exhibits an adsorption capacity of 223 mg g −1 for alkaline pollutant rhodamine B. This research provides a viable path for the high-value utilization of recycled glass fibers and establishes a novel synthesis approach for MCM-41 with excellent adsorption performance. The development of clean energy leads to a significant increase in decommissioned wind turbine blades, which have become a new type of solid waste.
doi_str_mv 10.1039/d4se01318b
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Glass fiber, which is the main component of these blades, can be recycled through pyrolysis. However, the deficiencies in size and mechanical properties of recycled glass fibers preclude their further high-value utilization. This paper presents an innovative approach to the high-value utilization of recycled glass fibers as Si and Al sources for the synthesis of Si-Al MCM-41 mesoporous molecular sieves by the alkali fusion-hydrothermal method. The influences of the templating agent ratio, water ratio, pH, hydrothermal temperature, and hydrothermal time on the synthesis of molecular sieves during the hydrothermal synthesis process were investigated. The results show that the MCM-41 molecular sieve synthesized under optimal conditions exhibited a uniform mesoporous structure, with a specific surface area of 831 m 2 g −1 and a uniform distribution of Si and Al elements. Additionally, it exhibits an adsorption capacity of 223 mg g −1 for alkaline pollutant rhodamine B. This research provides a viable path for the high-value utilization of recycled glass fibers and establishes a novel synthesis approach for MCM-41 with excellent adsorption performance. 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This research provides a viable path for the high-value utilization of recycled glass fibers and establishes a novel synthesis approach for MCM-41 with excellent adsorption performance. 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Glass fiber, which is the main component of these blades, can be recycled through pyrolysis. However, the deficiencies in size and mechanical properties of recycled glass fibers preclude their further high-value utilization. This paper presents an innovative approach to the high-value utilization of recycled glass fibers as Si and Al sources for the synthesis of Si-Al MCM-41 mesoporous molecular sieves by the alkali fusion-hydrothermal method. The influences of the templating agent ratio, water ratio, pH, hydrothermal temperature, and hydrothermal time on the synthesis of molecular sieves during the hydrothermal synthesis process were investigated. The results show that the MCM-41 molecular sieve synthesized under optimal conditions exhibited a uniform mesoporous structure, with a specific surface area of 831 m 2 g −1 and a uniform distribution of Si and Al elements. Additionally, it exhibits an adsorption capacity of 223 mg g −1 for alkaline pollutant rhodamine B. 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source Royal Society Of Chemistry Journals 2008-
subjects Adsorption
Aluminum
Chemical synthesis
Clean energy
Fan blades
Fibers
Glass fibers
Mechanical properties
Molecular sieves
Molecular structure
Pyrolysis
Recycled materials
Rhodamine
Silicon
Solid wastes
Turbine blades
Utilization
Wind power
Wind turbines
title Synthesis of MCM-41 mesoporous molecular sieves based on recycled glass fibers from waste fan blades
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