Direct ladderization of cyclooctatetraene-containing, processable conjugated ladder polymers from annulated bis-zirconacyclopentadienes

Conjugated ladder polymers (CLPs) are difficult yet captivating synthetic targets due to their fully unsaturated fused backbones. Inherent challenges associated with their synthesis often lead to low yields, structural defects, and insoluble products. Here a new method to form CLPs is demonstrated,...

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Veröffentlicht in:	Chemical science (Cambridge) 2024-12, Vol.15 (48), p.253-258
Hauptverfasser:	Rothenberger, August J, Bergman, Harrison M, Li, He, Qi, Miao, Wang, Yunfei, Liu, Yi, Tilley, T. Don
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical synthesis Dimerization Microporosity Polymers Prepolymers Thin films
Online-Zugang:	Volltext
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