Photoinduced [4 + 2]-cycloaddition reactions of vinyldiazo compounds for the construction of heterocyclic and bicyclic rings

Highly selective formal [4 + 2]-cycloaddition of vinyldiazoacetates with azoalkenes from α-halohydrazones, as well as with cyclopentadiene and furan, occurs with light irradiation at room temperature, producing highly functionalized heterocyclic and bicyclic compounds in good yields and excellent di...

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Veröffentlicht in:	Chemical science (Cambridge) 2024-07, Vol.15 (3), p.1242-1246
Hauptverfasser:	Bao, Ming, Bohórquez, Arnold R. Romero, Arman, Hadi, Doyle, Michael P
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Cycloaddition Cyclopentadiene Dimerization Functional groups Light irradiation Organic compounds Reagents Room temperature
Online-Zugang:	Volltext
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