Multi-phosphine-chelated iron-carbide clusters redox-promoted ligand exchange on an inert hexa-iron-carbide carbonyl cluster, [Fe(μ-C)(μ-CO)(CO)]

We report the reactivity, structures and spectroscopic characterization of reactions of phosphine-based ligands (mono-, di- and tri-dentate) with iron-carbide carbonyl clusters. Historically, the archetype of this cluster class, namely [Fe 6 (μ 6 -C)(μ 2 -CO) 4 (CO) 12 ] 2− , can be prepared on a gr...

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Veröffentlicht in:	Chemical science (Cambridge) 2024-07, Vol.15 (29), p.11455-11471
Hauptverfasser:	Cobb, Caitlyn R, Ngo, Ren K, Dick, Emily J, Lynch, Vincent M, Rose, Michael J
Format:	Artikel
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