Selective C-H functionalizations of arenes catalyzed by poly NHC-Pd in flow

A series of heterogenized NHC-Pd catalysts were developed to address the high economic cost of C - H functionalizations resulting from the poor recyclability of transition metal catalysts. The catalytic activities of the obtained solid hypercrosslinked catalysts were studied in C - H acetoxylation,...

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Veröffentlicht in:	Reaction chemistry & engineering 2024-06, Vol.9 (7), p.1641-1645
Hauptverfasser:	Huang, Shiqi, Hao, Runqi, Li, Qiao, Wan, Li, Chen, Fener
Format:	Artikel
Sprache:	eng
Schlagworte:	Aromatic compounds Catalysts Economic impact Iodination Palladium Recyclability Transition metals
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creator	Huang, Shiqi Hao, Runqi Li, Qiao Wan, Li Chen, Fener
description	A series of heterogenized NHC-Pd catalysts were developed to address the high economic cost of C - H functionalizations resulting from the poor recyclability of transition metal catalysts. The catalytic activities of the obtained solid hypercrosslinked catalysts were studied in C - H acetoxylation, iodination, and nitrosation. A series of heterogenized NHC-Pd catalysts were prepared and exploited in flow C-H acetoxylation, iodination and nitrosation.
doi_str_mv	10.1039/d4re00140k
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subjects	Aromatic compounds Catalysts Economic impact Iodination Palladium Recyclability Transition metals
title	Selective C-H functionalizations of arenes catalyzed by poly NHC-Pd in flow
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