Palladium-catalyzed electrochemical C(sp)-H acetoxylation of alcohol derivatives with an -directing group
Palladium-catalyzed electrochemical C(sp 3 )-H acetoxylation to prepare 1,2-diol derivatives was achieved using oxime ethers as exo -directing groups. Various substrates containing alkoxy groups with a methyl branch at the α-position as well as norbornan-2-ol derivative were acetoxylated only using...
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| Veröffentlicht in: | Organic & biomolecular chemistry 2024-09, Vol.22 (37), p.7696-771 |
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| container_end_page | 771 |
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| container_issue | 37 |
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| container_title | Organic & biomolecular chemistry |
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| creator | Ogawa, Daisuke Sasaki, Ayumu Kochi, Takuya Kakiuchi, Fumitoshi |
| description | Palladium-catalyzed electrochemical C(sp
3
)-H acetoxylation to prepare 1,2-diol derivatives was achieved using oxime ethers as
exo
-directing groups. Various substrates containing alkoxy groups with a methyl branch at the α-position as well as norbornan-2-ol derivative were acetoxylated only using a catalytic amount of Pd(OAc)
2
along with NaOAc/Ac
2
O/AcOH under anodic oxidation conditions.
Palladium-catalyzed electrochemical C(sp
3
)-H acetoxylation to prepare 1,2-diol derivatives was achieved using oxime ethers as
exo
-directing groups. |
| doi_str_mv | 10.1039/d4ob01241k |
| format | Article |
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3
)-H acetoxylation to prepare 1,2-diol derivatives was achieved using oxime ethers as
exo
-directing groups. Various substrates containing alkoxy groups with a methyl branch at the α-position as well as norbornan-2-ol derivative were acetoxylated only using a catalytic amount of Pd(OAc)
2
along with NaOAc/Ac
2
O/AcOH under anodic oxidation conditions.
Palladium-catalyzed electrochemical C(sp
3
)-H acetoxylation to prepare 1,2-diol derivatives was achieved using oxime ethers as
exo
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3
)-H acetoxylation to prepare 1,2-diol derivatives was achieved using oxime ethers as
exo
-directing groups. Various substrates containing alkoxy groups with a methyl branch at the α-position as well as norbornan-2-ol derivative were acetoxylated only using a catalytic amount of Pd(OAc)
2
along with NaOAc/Ac
2
O/AcOH under anodic oxidation conditions.
Palladium-catalyzed electrochemical C(sp
3
)-H acetoxylation to prepare 1,2-diol derivatives was achieved using oxime ethers as
exo
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3
)-H acetoxylation to prepare 1,2-diol derivatives was achieved using oxime ethers as
exo
-directing groups. Various substrates containing alkoxy groups with a methyl branch at the α-position as well as norbornan-2-ol derivative were acetoxylated only using a catalytic amount of Pd(OAc)
2
along with NaOAc/Ac
2
O/AcOH under anodic oxidation conditions.
Palladium-catalyzed electrochemical C(sp
3
)-H acetoxylation to prepare 1,2-diol derivatives was achieved using oxime ethers as
exo
-directing groups.</abstract><doi>10.1039/d4ob01241k</doi><tpages>6</tpages></addata></record> |
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| ispartof | Organic & biomolecular chemistry, 2024-09, Vol.22 (37), p.7696-771 |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | Palladium-catalyzed electrochemical C(sp)-H acetoxylation of alcohol derivatives with an -directing group |
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