Au()/TPPMS-catalyzed Friedel-Crafts benzylation of deactivated -alkylanilines in water

The Friedel-Crafts reaction of electronically deactivated anilines including those with strong electron-withdrawing NO 2 , CN or CO 2 H groups is challenging due to the reduced electron density of the aromatic ring. Here, we demonstrate the Au( iii )/TPPMS-catalyzed Friedel-Crafts benzylation of dea...

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Veröffentlicht in:	Organic & biomolecular chemistry 2024-10, Vol.22 (38), p.7874-7879
Hauptverfasser:	Hikawa, Hidemasa, Fukuda, Akane, Kondo, Kazuma, Nakayama, Taku, Enda, Tomokatsu, Kikkawa, Shoko, Azumaya, Isao
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