A polarization double-enhancement strategy to achieve super low energy consumption with ultra-high energy storage capacity in BCZT-based relaxor ferroelectrics
Due to dielectric capacitors' already-obtained fast charge-discharge speed, research has been focused on improving their W rec . Increasing the polarization and enhancing the voltage endurance are efficient ways to reach higher W rec , however simultaneous modification still seems a paradox. Fo...
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| Veröffentlicht in: | Materials horizons 2024-07, Vol.11 (14), p.333-3344 |
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| creator | Sun, Zixiong Bai, Yuhan Jing, Hongmei Hu, Tianyi Du, Kang Guo, Qing Gao, Pan Tian, Ye Ma, Chunrui Liu, Ming Pu, Yongping |
| description | Due to dielectric capacitors' already-obtained fast charge-discharge speed, research has been focused on improving their
W
rec
. Increasing the polarization and enhancing the voltage endurance are efficient ways to reach higher
W
rec
, however simultaneous modification still seems a paradox. For example, in the ferroelectric-to-relaxor ferroelectric (FE-to-RFE) phase transition strategy, which has been widely used in the latest decade, electric breakdown strength (
E
b
) and energy storage efficiency (
η
) always increase, while at the same time, the maximum polarization (
P
max
) inevitably decreases. The solution to this problem can be obtained from another degree of freedom, like defect engineering. By incorporating Bi(Zn
2/3
Ta
1/3
)O
3
(BZT) into the Ba
0.15
Ca
0.85
Zr
0.1
Ti
0.9
O
3
(BCZT) lattice to form (1 −
x
)Ba
0.15
Ca
0.85
Zr
0.1
Ti
0.9
O
3
-
x
Bi(Zn
2/3
Ta
1/3
)O
3
(BCZT-
x
BZT) solid-solution ceramics, in this work, ultrahigh ferroelectric polarization was achieved in BCZT-0.15BZT, which is caused by the polarization double-enhancement, comprising the contribution of interfacial and dipole polarization. In addition, due to the electron compensation, a Schottky contact formed at the interface between the electrode and the ceramic, which in the meantime, enhanced its
E
b
. A
W
rec
of 8.03 J cm
−3
, which is the highest among the BCZT-based ceramics reported so far, with an extremely low energy consumption, was finally achieved. BCZT-0.15BZT also has relatively good polarization fatigue after long-term use, good energy storage frequency stability and thermal stability, as well as excellent discharge properties.
Due to the combination of interfacial polarization and depolarization, the energy density of BCZT-based lead-free ferroelectric reached 8.03 J cm
−3
at only 425 kV cm
−1
. High energy density with extremely low energy consumption was achieved. |
| doi_str_mv | 10.1039/d4mh00322e |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_rsc_p</sourceid><recordid>TN_cdi_rsc_primary_d4mh00322e</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3080368418</sourcerecordid><originalsourceid>FETCH-LOGICAL-c296t-c833bc326095c3dcb448ee6c484ab880c2a9b59ec6a70612c8735147675977753</originalsourceid><addsrcrecordid>eNpd0U1v1DAQBuAIUdGq9MIdZIkLQgo48WeO7VLaSkVcyoVL5ExmN64SO9gOZfkz_FVMt91KnMbSPH410lsUryr6oaKs-djzaaCU1TU-K45qKqpSMiGe799cHRYnMd5SSivGBdX0RXHItNS1FOqo-HNKZj-aYH-bZL0jvV-6EUt0g3GAE7pEYgom4WZLkicGBos_kcRlxkBGf0fQYcg78C4u03yfcWfTQJYxfysHuxkeSUw-mA0SMLMBm7bEOnK2-n5TdiZiTwKO5pcPZI0heBwRUrAQXxYHazNGPHmYx8W3z-c3q8vy-uvF1er0uoS6kakEzVgHrJa0EcB66DjXiBK45qbTmkJtmk40CNIoKqsatGKi4koq0SilBDsu3u1y5-B_LBhTO9kIOI7GoV9iyyjXWWtJM337H731S3D5uqw0ZVLzSmf1fqcg-BgDrts52MmEbVvR9l9z7Sf-5fK-ufOM3zxELt2E_Z4-9pTB6x0IEfbbp-rZX7PYn2w</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>3080368418</pqid></control><display><type>article</type><title>A polarization double-enhancement strategy to achieve super low energy consumption with ultra-high energy storage capacity in BCZT-based relaxor ferroelectrics</title><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Sun, Zixiong ; Bai, Yuhan ; Jing, Hongmei ; Hu, Tianyi ; Du, Kang ; Guo, Qing ; Gao, Pan ; Tian, Ye ; Ma, Chunrui ; Liu, Ming ; Pu, Yongping</creator><creatorcontrib>Sun, Zixiong ; Bai, Yuhan ; Jing, Hongmei ; Hu, Tianyi ; Du, Kang ; Guo, Qing ; Gao, Pan ; Tian, Ye ; Ma, Chunrui ; Liu, Ming ; Pu, Yongping</creatorcontrib><description>Due to dielectric capacitors' already-obtained fast charge-discharge speed, research has been focused on improving their
W
rec
. Increasing the polarization and enhancing the voltage endurance are efficient ways to reach higher
W
rec
, however simultaneous modification still seems a paradox. For example, in the ferroelectric-to-relaxor ferroelectric (FE-to-RFE) phase transition strategy, which has been widely used in the latest decade, electric breakdown strength (
E
b
) and energy storage efficiency (
η
) always increase, while at the same time, the maximum polarization (
P
max
) inevitably decreases. The solution to this problem can be obtained from another degree of freedom, like defect engineering. By incorporating Bi(Zn
2/3
Ta
1/3
)O
3
(BZT) into the Ba
0.15
Ca
0.85
Zr
0.1
Ti
0.9
O
3
(BCZT) lattice to form (1 −
x
)Ba
0.15
Ca
0.85
Zr
0.1
Ti
0.9
O
3
-
x
Bi(Zn
2/3
Ta
1/3
)O
3
(BCZT-
x
BZT) solid-solution ceramics, in this work, ultrahigh ferroelectric polarization was achieved in BCZT-0.15BZT, which is caused by the polarization double-enhancement, comprising the contribution of interfacial and dipole polarization. In addition, due to the electron compensation, a Schottky contact formed at the interface between the electrode and the ceramic, which in the meantime, enhanced its
E
b
. A
W
rec
of 8.03 J cm
−3
, which is the highest among the BCZT-based ceramics reported so far, with an extremely low energy consumption, was finally achieved. BCZT-0.15BZT also has relatively good polarization fatigue after long-term use, good energy storage frequency stability and thermal stability, as well as excellent discharge properties.
Due to the combination of interfacial polarization and depolarization, the energy density of BCZT-based lead-free ferroelectric reached 8.03 J cm
−3
at only 425 kV cm
−1
. High energy density with extremely low energy consumption was achieved.</description><identifier>ISSN: 2051-6347</identifier><identifier>ISSN: 2051-6355</identifier><identifier>EISSN: 2051-6355</identifier><identifier>DOI: 10.1039/d4mh00322e</identifier><identifier>PMID: 38682657</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Ceramics ; Dielectric relaxation ; Dipoles ; Discharge ; Electric contacts ; Energy consumption ; Energy storage ; Ferroelectric materials ; Ferroelectricity ; Frequency stability ; Phase transitions ; Polarization ; Relaxors ; Solid solutions ; Storage capacity ; Thermal stability</subject><ispartof>Materials horizons, 2024-07, Vol.11 (14), p.333-3344</ispartof><rights>Copyright Royal Society of Chemistry 2024</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c296t-c833bc326095c3dcb448ee6c484ab880c2a9b59ec6a70612c8735147675977753</cites><orcidid>0000-0001-9127-8224 ; 0000-0002-8268-0593 ; 0000-0002-7824-7930 ; 0000-0001-5012-5328</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/38682657$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Sun, Zixiong</creatorcontrib><creatorcontrib>Bai, Yuhan</creatorcontrib><creatorcontrib>Jing, Hongmei</creatorcontrib><creatorcontrib>Hu, Tianyi</creatorcontrib><creatorcontrib>Du, Kang</creatorcontrib><creatorcontrib>Guo, Qing</creatorcontrib><creatorcontrib>Gao, Pan</creatorcontrib><creatorcontrib>Tian, Ye</creatorcontrib><creatorcontrib>Ma, Chunrui</creatorcontrib><creatorcontrib>Liu, Ming</creatorcontrib><creatorcontrib>Pu, Yongping</creatorcontrib><title>A polarization double-enhancement strategy to achieve super low energy consumption with ultra-high energy storage capacity in BCZT-based relaxor ferroelectrics</title><title>Materials horizons</title><addtitle>Mater Horiz</addtitle><description>Due to dielectric capacitors' already-obtained fast charge-discharge speed, research has been focused on improving their
W
rec
. Increasing the polarization and enhancing the voltage endurance are efficient ways to reach higher
W
rec
, however simultaneous modification still seems a paradox. For example, in the ferroelectric-to-relaxor ferroelectric (FE-to-RFE) phase transition strategy, which has been widely used in the latest decade, electric breakdown strength (
E
b
) and energy storage efficiency (
η
) always increase, while at the same time, the maximum polarization (
P
max
) inevitably decreases. The solution to this problem can be obtained from another degree of freedom, like defect engineering. By incorporating Bi(Zn
2/3
Ta
1/3
)O
3
(BZT) into the Ba
0.15
Ca
0.85
Zr
0.1
Ti
0.9
O
3
(BCZT) lattice to form (1 −
x
)Ba
0.15
Ca
0.85
Zr
0.1
Ti
0.9
O
3
-
x
Bi(Zn
2/3
Ta
1/3
)O
3
(BCZT-
x
BZT) solid-solution ceramics, in this work, ultrahigh ferroelectric polarization was achieved in BCZT-0.15BZT, which is caused by the polarization double-enhancement, comprising the contribution of interfacial and dipole polarization. In addition, due to the electron compensation, a Schottky contact formed at the interface between the electrode and the ceramic, which in the meantime, enhanced its
E
b
. A
W
rec
of 8.03 J cm
−3
, which is the highest among the BCZT-based ceramics reported so far, with an extremely low energy consumption, was finally achieved. BCZT-0.15BZT also has relatively good polarization fatigue after long-term use, good energy storage frequency stability and thermal stability, as well as excellent discharge properties.
Due to the combination of interfacial polarization and depolarization, the energy density of BCZT-based lead-free ferroelectric reached 8.03 J cm
−3
at only 425 kV cm
−1
. High energy density with extremely low energy consumption was achieved.</description><subject>Ceramics</subject><subject>Dielectric relaxation</subject><subject>Dipoles</subject><subject>Discharge</subject><subject>Electric contacts</subject><subject>Energy consumption</subject><subject>Energy storage</subject><subject>Ferroelectric materials</subject><subject>Ferroelectricity</subject><subject>Frequency stability</subject><subject>Phase transitions</subject><subject>Polarization</subject><subject>Relaxors</subject><subject>Solid solutions</subject><subject>Storage capacity</subject><subject>Thermal stability</subject><issn>2051-6347</issn><issn>2051-6355</issn><issn>2051-6355</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNpd0U1v1DAQBuAIUdGq9MIdZIkLQgo48WeO7VLaSkVcyoVL5ExmN64SO9gOZfkz_FVMt91KnMbSPH410lsUryr6oaKs-djzaaCU1TU-K45qKqpSMiGe799cHRYnMd5SSivGBdX0RXHItNS1FOqo-HNKZj-aYH-bZL0jvV-6EUt0g3GAE7pEYgom4WZLkicGBos_kcRlxkBGf0fQYcg78C4u03yfcWfTQJYxfysHuxkeSUw-mA0SMLMBm7bEOnK2-n5TdiZiTwKO5pcPZI0heBwRUrAQXxYHazNGPHmYx8W3z-c3q8vy-uvF1er0uoS6kakEzVgHrJa0EcB66DjXiBK45qbTmkJtmk40CNIoKqsatGKi4koq0SilBDsu3u1y5-B_LBhTO9kIOI7GoV9iyyjXWWtJM337H731S3D5uqw0ZVLzSmf1fqcg-BgDrts52MmEbVvR9l9z7Sf-5fK-ufOM3zxELt2E_Z4-9pTB6x0IEfbbp-rZX7PYn2w</recordid><startdate>20240715</startdate><enddate>20240715</enddate><creator>Sun, Zixiong</creator><creator>Bai, Yuhan</creator><creator>Jing, Hongmei</creator><creator>Hu, Tianyi</creator><creator>Du, Kang</creator><creator>Guo, Qing</creator><creator>Gao, Pan</creator><creator>Tian, Ye</creator><creator>Ma, Chunrui</creator><creator>Liu, Ming</creator><creator>Pu, Yongping</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7TB</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0001-9127-8224</orcidid><orcidid>https://orcid.org/0000-0002-8268-0593</orcidid><orcidid>https://orcid.org/0000-0002-7824-7930</orcidid><orcidid>https://orcid.org/0000-0001-5012-5328</orcidid></search><sort><creationdate>20240715</creationdate><title>A polarization double-enhancement strategy to achieve super low energy consumption with ultra-high energy storage capacity in BCZT-based relaxor ferroelectrics</title><author>Sun, Zixiong ; Bai, Yuhan ; Jing, Hongmei ; Hu, Tianyi ; Du, Kang ; Guo, Qing ; Gao, Pan ; Tian, Ye ; Ma, Chunrui ; Liu, Ming ; Pu, Yongping</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c296t-c833bc326095c3dcb448ee6c484ab880c2a9b59ec6a70612c8735147675977753</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Ceramics</topic><topic>Dielectric relaxation</topic><topic>Dipoles</topic><topic>Discharge</topic><topic>Electric contacts</topic><topic>Energy consumption</topic><topic>Energy storage</topic><topic>Ferroelectric materials</topic><topic>Ferroelectricity</topic><topic>Frequency stability</topic><topic>Phase transitions</topic><topic>Polarization</topic><topic>Relaxors</topic><topic>Solid solutions</topic><topic>Storage capacity</topic><topic>Thermal stability</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sun, Zixiong</creatorcontrib><creatorcontrib>Bai, Yuhan</creatorcontrib><creatorcontrib>Jing, Hongmei</creatorcontrib><creatorcontrib>Hu, Tianyi</creatorcontrib><creatorcontrib>Du, Kang</creatorcontrib><creatorcontrib>Guo, Qing</creatorcontrib><creatorcontrib>Gao, Pan</creatorcontrib><creatorcontrib>Tian, Ye</creatorcontrib><creatorcontrib>Ma, Chunrui</creatorcontrib><creatorcontrib>Liu, Ming</creatorcontrib><creatorcontrib>Pu, Yongping</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Materials horizons</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sun, Zixiong</au><au>Bai, Yuhan</au><au>Jing, Hongmei</au><au>Hu, Tianyi</au><au>Du, Kang</au><au>Guo, Qing</au><au>Gao, Pan</au><au>Tian, Ye</au><au>Ma, Chunrui</au><au>Liu, Ming</au><au>Pu, Yongping</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A polarization double-enhancement strategy to achieve super low energy consumption with ultra-high energy storage capacity in BCZT-based relaxor ferroelectrics</atitle><jtitle>Materials horizons</jtitle><addtitle>Mater Horiz</addtitle><date>2024-07-15</date><risdate>2024</risdate><volume>11</volume><issue>14</issue><spage>333</spage><epage>3344</epage><pages>333-3344</pages><issn>2051-6347</issn><issn>2051-6355</issn><eissn>2051-6355</eissn><abstract>Due to dielectric capacitors' already-obtained fast charge-discharge speed, research has been focused on improving their
W
rec
. Increasing the polarization and enhancing the voltage endurance are efficient ways to reach higher
W
rec
, however simultaneous modification still seems a paradox. For example, in the ferroelectric-to-relaxor ferroelectric (FE-to-RFE) phase transition strategy, which has been widely used in the latest decade, electric breakdown strength (
E
b
) and energy storage efficiency (
η
) always increase, while at the same time, the maximum polarization (
P
max
) inevitably decreases. The solution to this problem can be obtained from another degree of freedom, like defect engineering. By incorporating Bi(Zn
2/3
Ta
1/3
)O
3
(BZT) into the Ba
0.15
Ca
0.85
Zr
0.1
Ti
0.9
O
3
(BCZT) lattice to form (1 −
x
)Ba
0.15
Ca
0.85
Zr
0.1
Ti
0.9
O
3
-
x
Bi(Zn
2/3
Ta
1/3
)O
3
(BCZT-
x
BZT) solid-solution ceramics, in this work, ultrahigh ferroelectric polarization was achieved in BCZT-0.15BZT, which is caused by the polarization double-enhancement, comprising the contribution of interfacial and dipole polarization. In addition, due to the electron compensation, a Schottky contact formed at the interface between the electrode and the ceramic, which in the meantime, enhanced its
E
b
. A
W
rec
of 8.03 J cm
−3
, which is the highest among the BCZT-based ceramics reported so far, with an extremely low energy consumption, was finally achieved. BCZT-0.15BZT also has relatively good polarization fatigue after long-term use, good energy storage frequency stability and thermal stability, as well as excellent discharge properties.
Due to the combination of interfacial polarization and depolarization, the energy density of BCZT-based lead-free ferroelectric reached 8.03 J cm
−3
at only 425 kV cm
−1
. High energy density with extremely low energy consumption was achieved.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>38682657</pmid><doi>10.1039/d4mh00322e</doi><tpages>15</tpages><orcidid>https://orcid.org/0000-0001-9127-8224</orcidid><orcidid>https://orcid.org/0000-0002-8268-0593</orcidid><orcidid>https://orcid.org/0000-0002-7824-7930</orcidid><orcidid>https://orcid.org/0000-0001-5012-5328</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2051-6347 |
| ispartof | Materials horizons, 2024-07, Vol.11 (14), p.333-3344 |
| issn | 2051-6347 2051-6355 2051-6355 |
| language | eng |
| recordid | cdi_rsc_primary_d4mh00322e |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Ceramics Dielectric relaxation Dipoles Discharge Electric contacts Energy consumption Energy storage Ferroelectric materials Ferroelectricity Frequency stability Phase transitions Polarization Relaxors Solid solutions Storage capacity Thermal stability |
| title | A polarization double-enhancement strategy to achieve super low energy consumption with ultra-high energy storage capacity in BCZT-based relaxor ferroelectrics |
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