Shell biorefineries: mixed biofuel production from chitin
Bioenergy is a key strategy for sustainability, yet the potential for biofuel production from chitin is under-exploited. Here, we report the cleavage of the inherently inert σ-type C-C bonds in chitin under the condition of initially breaking the unstable C-O bonds. Mechanistic studies indicate that...
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| Veröffentlicht in: | Green chemistry : an international journal and green chemistry resource : GC 2024-11, Vol.26 (22), p.1128-11289 |
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| container_title | Green chemistry : an international journal and green chemistry resource : GC |
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| creator | Huang, Hao Zhou, Guangping Cai, Xiaolan Zhuang, Min Xie, Shaoqu |
| description | Bioenergy is a key strategy for sustainability, yet the potential for biofuel production from chitin is under-exploited. Here, we report the cleavage of the inherently inert σ-type C-C bonds in chitin under the condition of initially breaking the unstable C-O bonds. Mechanistic studies indicate that by regulating the valence state of Ru and the interaction between RuO
x
and AC-HNO
3
-melamine, the ability of Ru nanoparticles to cleave C-C and C-O bonds can be controlled. One-pot sequential hydrogenolysis of chitin with RuO
x
/AC-HNO
3
-melamine resulted in a mixed alcohol yield 1.66 times that of commercial Ru/C. A mixed alcohol yield of 16.8% was achieved using raw chitin and green process conditions. We expanded the substrate range to include chitosan,
N
-acetyl-
d
-glucosamine, and glucosamine. This work demonstrates the potential of shell biorefinery to produce affordable clean energy.
Bioenergy is a key strategy for sustainability, yet the potential for biofuel production from chitin is under-exploited. |
| doi_str_mv | 10.1039/d4gc03761h |
| format | Article |
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x
and AC-HNO
3
-melamine, the ability of Ru nanoparticles to cleave C-C and C-O bonds can be controlled. One-pot sequential hydrogenolysis of chitin with RuO
x
/AC-HNO
3
-melamine resulted in a mixed alcohol yield 1.66 times that of commercial Ru/C. A mixed alcohol yield of 16.8% was achieved using raw chitin and green process conditions. We expanded the substrate range to include chitosan,
N
-acetyl-
d
-glucosamine, and glucosamine. This work demonstrates the potential of shell biorefinery to produce affordable clean energy.
Bioenergy is a key strategy for sustainability, yet the potential for biofuel production from chitin is under-exploited.</description><identifier>ISSN: 1463-9262</identifier><identifier>EISSN: 1463-9270</identifier><identifier>DOI: 10.1039/d4gc03761h</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Biofuels ; Biorefineries ; Bonding ; Chitin ; Chitosan ; Clean energy ; Covalent bonds ; Glucosamine ; Hydrogenolysis ; Melamine ; N-Acetylglucosamine ; Nanoparticles ; Refining ; Renewable energy ; Ruthenium ; Valence</subject><ispartof>Green chemistry : an international journal and green chemistry resource : GC, 2024-11, Vol.26 (22), p.1128-11289</ispartof><rights>Copyright Royal Society of Chemistry 2024</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c170t-92f56539061053a0f14e364532618ecca1172dcc36764e2fd8a677ed1958ad7f3</cites><orcidid>0009-0006-5310-1536 ; 0000-0001-5829-0045</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27903,27904</link.rule.ids></links><search><creatorcontrib>Huang, Hao</creatorcontrib><creatorcontrib>Zhou, Guangping</creatorcontrib><creatorcontrib>Cai, Xiaolan</creatorcontrib><creatorcontrib>Zhuang, Min</creatorcontrib><creatorcontrib>Xie, Shaoqu</creatorcontrib><title>Shell biorefineries: mixed biofuel production from chitin</title><title>Green chemistry : an international journal and green chemistry resource : GC</title><description>Bioenergy is a key strategy for sustainability, yet the potential for biofuel production from chitin is under-exploited. Here, we report the cleavage of the inherently inert σ-type C-C bonds in chitin under the condition of initially breaking the unstable C-O bonds. Mechanistic studies indicate that by regulating the valence state of Ru and the interaction between RuO
x
and AC-HNO
3
-melamine, the ability of Ru nanoparticles to cleave C-C and C-O bonds can be controlled. One-pot sequential hydrogenolysis of chitin with RuO
x
/AC-HNO
3
-melamine resulted in a mixed alcohol yield 1.66 times that of commercial Ru/C. A mixed alcohol yield of 16.8% was achieved using raw chitin and green process conditions. We expanded the substrate range to include chitosan,
N
-acetyl-
d
-glucosamine, and glucosamine. This work demonstrates the potential of shell biorefinery to produce affordable clean energy.
Bioenergy is a key strategy for sustainability, yet the potential for biofuel production from chitin is under-exploited.</description><subject>Biofuels</subject><subject>Biorefineries</subject><subject>Bonding</subject><subject>Chitin</subject><subject>Chitosan</subject><subject>Clean energy</subject><subject>Covalent bonds</subject><subject>Glucosamine</subject><subject>Hydrogenolysis</subject><subject>Melamine</subject><subject>N-Acetylglucosamine</subject><subject>Nanoparticles</subject><subject>Refining</subject><subject>Renewable energy</subject><subject>Ruthenium</subject><subject>Valence</subject><issn>1463-9262</issn><issn>1463-9270</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNpFkEtLxDAQx4MouK5evAsFb0I1k6RJ601W3RUWPKjnEPOwWfpYkxb025u1sp5mGH7M_4HQOeBrwLS6MexDYyo41AdoBozTvCICH-53To7RSYwbjAEEZzNUvdS2abJ33wfrfGeDt_E2a_2XNbujG22TbUNvRj34vstc6NtM137w3Sk6cqqJ9uxvztHb48PrYpWvn5dPi7t1rkHgIWm6ghe0whxwQRV2wCzlrKCEQ2m1VskIMVpTnvxY4kypuBDWQFWUyghH5-hy-ptsfI42DnLTj6FLkpIC4VxQQspEXU2UDn2MKYvcBt-q8C0By1018p4tF7_VrBJ8McEh6j33Xx39AeD1Xrw</recordid><startdate>20241111</startdate><enddate>20241111</enddate><creator>Huang, Hao</creator><creator>Zhou, Guangping</creator><creator>Cai, Xiaolan</creator><creator>Zhuang, Min</creator><creator>Xie, Shaoqu</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7ST</scope><scope>7U6</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>JG9</scope><orcidid>https://orcid.org/0009-0006-5310-1536</orcidid><orcidid>https://orcid.org/0000-0001-5829-0045</orcidid></search><sort><creationdate>20241111</creationdate><title>Shell biorefineries: mixed biofuel production from chitin</title><author>Huang, Hao ; Zhou, Guangping ; Cai, Xiaolan ; Zhuang, Min ; Xie, Shaoqu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c170t-92f56539061053a0f14e364532618ecca1172dcc36764e2fd8a677ed1958ad7f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Biofuels</topic><topic>Biorefineries</topic><topic>Bonding</topic><topic>Chitin</topic><topic>Chitosan</topic><topic>Clean energy</topic><topic>Covalent bonds</topic><topic>Glucosamine</topic><topic>Hydrogenolysis</topic><topic>Melamine</topic><topic>N-Acetylglucosamine</topic><topic>Nanoparticles</topic><topic>Refining</topic><topic>Renewable energy</topic><topic>Ruthenium</topic><topic>Valence</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Huang, Hao</creatorcontrib><creatorcontrib>Zhou, Guangping</creatorcontrib><creatorcontrib>Cai, Xiaolan</creatorcontrib><creatorcontrib>Zhuang, Min</creatorcontrib><creatorcontrib>Xie, Shaoqu</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Environment Abstracts</collection><collection>Sustainability Science Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Materials Research Database</collection><jtitle>Green chemistry : an international journal and green chemistry resource : GC</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Huang, Hao</au><au>Zhou, Guangping</au><au>Cai, Xiaolan</au><au>Zhuang, Min</au><au>Xie, Shaoqu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Shell biorefineries: mixed biofuel production from chitin</atitle><jtitle>Green chemistry : an international journal and green chemistry resource : GC</jtitle><date>2024-11-11</date><risdate>2024</risdate><volume>26</volume><issue>22</issue><spage>1128</spage><epage>11289</epage><pages>1128-11289</pages><issn>1463-9262</issn><eissn>1463-9270</eissn><abstract>Bioenergy is a key strategy for sustainability, yet the potential for biofuel production from chitin is under-exploited. Here, we report the cleavage of the inherently inert σ-type C-C bonds in chitin under the condition of initially breaking the unstable C-O bonds. Mechanistic studies indicate that by regulating the valence state of Ru and the interaction between RuO
x
and AC-HNO
3
-melamine, the ability of Ru nanoparticles to cleave C-C and C-O bonds can be controlled. One-pot sequential hydrogenolysis of chitin with RuO
x
/AC-HNO
3
-melamine resulted in a mixed alcohol yield 1.66 times that of commercial Ru/C. A mixed alcohol yield of 16.8% was achieved using raw chitin and green process conditions. We expanded the substrate range to include chitosan,
N
-acetyl-
d
-glucosamine, and glucosamine. This work demonstrates the potential of shell biorefinery to produce affordable clean energy.
Bioenergy is a key strategy for sustainability, yet the potential for biofuel production from chitin is under-exploited.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d4gc03761h</doi><tpages>1</tpages><orcidid>https://orcid.org/0009-0006-5310-1536</orcidid><orcidid>https://orcid.org/0000-0001-5829-0045</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1463-9262 |
| ispartof | Green chemistry : an international journal and green chemistry resource : GC, 2024-11, Vol.26 (22), p.1128-11289 |
| issn | 1463-9262 1463-9270 |
| language | eng |
| recordid | cdi_rsc_primary_d4gc03761h |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Biofuels Biorefineries Bonding Chitin Chitosan Clean energy Covalent bonds Glucosamine Hydrogenolysis Melamine N-Acetylglucosamine Nanoparticles Refining Renewable energy Ruthenium Valence |
| title | Shell biorefineries: mixed biofuel production from chitin |
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