The hydrate of a neutral iron() complex based on the pyruvic acid thiosemicarbazone ligand with abrupt spin-crossover with = 340 K and a wide hysteresis loop of 45 K

The hydrate of a neutral iron( iii ) complex based on the pyruvic acid thiosemicarbazone ligand [Fe III (Hthpy)(thpy)]·H 2 O ( 1 ) was synthesized and characterized using FT-IR spectroscopy, powder and single-crystal X-ray diffraction, dc magnetic measurements, EPR and 57 Fe Mössbauer spectroscopy....

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2024-12, Vol.54 (1), p.346-356
Hauptverfasser:	Blagov, Maxim A, Akimov, Alexander V, Lobach, Anatoly S, Zorina, Leokadiya V, Simonov, Sergey V, Zakharov, Konstantin V, Vasiliev, Alexander N, Spitsyna, Nataliya G
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