Metal-organic frameworks with a sulfur-rich heterocycle: synthesis, gas adsorption properties, and metal exchange
Three new three-dimensional (3D) metal-organic frameworks [M 2 (ttdc) 2 (dabco)] (M = Zn( ii ), 1-Zn ; Cu( ii ), 1-Cu ; and Zn/Cu, 1-ZnCu ) based on thieno[3,2- b ]thiophene-2,5-dicarboxylate (ttdc 2− ) were synthesized and characterized by a combination of physicochemical methods (single crystal X-...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2024-10, Vol.53 (4), p.16654-1666 |
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| creator | Dubskikh, Vadim A Lysova, Anna A Kovalenko, Konstantin A Samsonenko, Denis G Dybtsev, Danil N Fedin, Vladimir P |
| description | Three new three-dimensional (3D) metal-organic frameworks [M
2
(ttdc)
2
(dabco)] (M = Zn(
ii
),
1-Zn
; Cu(
ii
),
1-Cu
; and Zn/Cu,
1-ZnCu
) based on thieno[3,2-
b
]thiophene-2,5-dicarboxylate (ttdc
2−
) were synthesized and characterized by a combination of physicochemical methods (single crystal X-ray diffraction, powder X-ray diffraction, chemical and thermogravimetric analyses and IR spectroscopy).
1-Cu
demonstrated permanent porosity (
V
pore
= 0.790 cm
3
g
−1
and
S
BET
= 1725 m
2
g
−1
) and significant CO
2
, CH
4
, C
2
H
2
, C
2
H
4
and C
2
H
6
gas uptakes under ambient conditions. The adsorption selectivities for gas mixtures, calculated by IAST, were 10.8 (10.7), 14.6 (9.4), 1.7 (1.6) and 1.5 (1.6) for the equimolar gas mixture compositions CO
2
/N
2
, C
2
H
6
/CH
4
, C
2
H
6
/C
2
H
4
and C
2
H
6
/C
2
H
2
at 1 bar and 273 K (298 K), respectively. The mixed-metal compound
1-ZnCu
was prepared by a crystal-to-crystal ion exchange metathesis reaction from
1-Zn
with a 52% degree of ion substitution, confirmed by energy-dispersive X-ray spectroscopy, optical microscopy and single crystal X-ray diffraction analysis.
Three new 3D metal-organic frameworks [M
2
(ttdc)
2
(dabco)] (M = Zn(
ii
),
1-Zn
; Cu(
ii
),
1-Cu
; and Zn/Cu,
1-ZnCu
) based on thieno[3,2-
b
]thiophene-2,5-dicarboxylate (ttdc
2−
) were synthesized and characterized by a combination of physicochemical methods. |
| doi_str_mv | 10.1039/d4dt02209b |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_rsc_p</sourceid><recordid>TN_cdi_rsc_primary_d4dt02209b</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3110405675</sourcerecordid><originalsourceid>FETCH-LOGICAL-c226t-6ecaa3333447c141197f520c5f348119e581150b6870b515c6c5e317d9da2e3</originalsourceid><addsrcrecordid>eNpdkc1PxCAQxYnR-H3xriHxYoxVKFAWb35rssaD3huWTrfVtuwCzbr_vayrayKHgcn88uaFh9ABJeeUMHVR8CKQNCVqtIa2KZcyUSnj66t3mm2hHe_fyQIS6SbaYoqlikm2jabPEHSTWDfWXW1w6XQLM-s-PJ7VocIa-74pe5e42lS4ggDOmrlp4BL7eRcq8LU_w2PtsS68dZNQ2w5PnJ2ACzXEke4K3C5WYPg0le7GsIc2St142P-5d9Hr_d3bzWMyfHl4urkaJiYaDkkGRmsWD-fSUE6pkqVIiREl44PYgYhVkFE2kGQkqDCZEcCoLFShU2C76GSpGs1Me_Ahb2tvoGl0B7b3OaOUcCIyKSJ6_A99t73rorcFlQkqB0pF6nRJGWe9d1DmE1e32s1zSvJFDPktv337juE6wkc_kv2ohWKF_v57BA6XgPNmNf3LkX0B7NCMXQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>3116517899</pqid></control><display><type>article</type><title>Metal-organic frameworks with a sulfur-rich heterocycle: synthesis, gas adsorption properties, and metal exchange</title><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Dubskikh, Vadim A ; Lysova, Anna A ; Kovalenko, Konstantin A ; Samsonenko, Denis G ; Dybtsev, Danil N ; Fedin, Vladimir P</creator><creatorcontrib>Dubskikh, Vadim A ; Lysova, Anna A ; Kovalenko, Konstantin A ; Samsonenko, Denis G ; Dybtsev, Danil N ; Fedin, Vladimir P</creatorcontrib><description>Three new three-dimensional (3D) metal-organic frameworks [M
2
(ttdc)
2
(dabco)] (M = Zn(
ii
),
1-Zn
; Cu(
ii
),
1-Cu
; and Zn/Cu,
1-ZnCu
) based on thieno[3,2-
b
]thiophene-2,5-dicarboxylate (ttdc
2−
) were synthesized and characterized by a combination of physicochemical methods (single crystal X-ray diffraction, powder X-ray diffraction, chemical and thermogravimetric analyses and IR spectroscopy).
1-Cu
demonstrated permanent porosity (
V
pore
= 0.790 cm
3
g
−1
and
S
BET
= 1725 m
2
g
−1
) and significant CO
2
, CH
4
, C
2
H
2
, C
2
H
4
and C
2
H
6
gas uptakes under ambient conditions. The adsorption selectivities for gas mixtures, calculated by IAST, were 10.8 (10.7), 14.6 (9.4), 1.7 (1.6) and 1.5 (1.6) for the equimolar gas mixture compositions CO
2
/N
2
, C
2
H
6
/CH
4
, C
2
H
6
/C
2
H
4
and C
2
H
6
/C
2
H
2
at 1 bar and 273 K (298 K), respectively. The mixed-metal compound
1-ZnCu
was prepared by a crystal-to-crystal ion exchange metathesis reaction from
1-Zn
with a 52% degree of ion substitution, confirmed by energy-dispersive X-ray spectroscopy, optical microscopy and single crystal X-ray diffraction analysis.
Three new 3D metal-organic frameworks [M
2
(ttdc)
2
(dabco)] (M = Zn(
ii
),
1-Zn
; Cu(
ii
),
1-Cu
; and Zn/Cu,
1-ZnCu
) based on thieno[3,2-
b
]thiophene-2,5-dicarboxylate (ttdc
2−
) were synthesized and characterized by a combination of physicochemical methods.</description><identifier>ISSN: 1477-9226</identifier><identifier>ISSN: 1477-9234</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/d4dt02209b</identifier><identifier>PMID: 39329373</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Adsorption ; Carbon dioxide ; Chemical synthesis ; Gas mixtures ; Infrared spectroscopy ; Ion exchange ; Metal compounds ; Metal-organic frameworks ; Metathesis ; Optical microscopy ; Single crystals ; Spectroscopic analysis ; Substitution reactions ; Thermogravimetric analysis ; X ray powder diffraction ; X-ray diffraction</subject><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2024-10, Vol.53 (4), p.16654-1666</ispartof><rights>Copyright Royal Society of Chemistry 2024</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c226t-6ecaa3333447c141197f520c5f348119e581150b6870b515c6c5e317d9da2e3</cites><orcidid>0000-0002-1337-5106 ; 0000-0001-8922-0066 ; 0000-0003-2688-4521 ; 0000-0001-8779-0612 ; 0009-0000-5821-3218 ; 0000-0001-7817-6370</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/39329373$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Dubskikh, Vadim A</creatorcontrib><creatorcontrib>Lysova, Anna A</creatorcontrib><creatorcontrib>Kovalenko, Konstantin A</creatorcontrib><creatorcontrib>Samsonenko, Denis G</creatorcontrib><creatorcontrib>Dybtsev, Danil N</creatorcontrib><creatorcontrib>Fedin, Vladimir P</creatorcontrib><title>Metal-organic frameworks with a sulfur-rich heterocycle: synthesis, gas adsorption properties, and metal exchange</title><title>Dalton transactions : an international journal of inorganic chemistry</title><addtitle>Dalton Trans</addtitle><description>Three new three-dimensional (3D) metal-organic frameworks [M
2
(ttdc)
2
(dabco)] (M = Zn(
ii
),
1-Zn
; Cu(
ii
),
1-Cu
; and Zn/Cu,
1-ZnCu
) based on thieno[3,2-
b
]thiophene-2,5-dicarboxylate (ttdc
2−
) were synthesized and characterized by a combination of physicochemical methods (single crystal X-ray diffraction, powder X-ray diffraction, chemical and thermogravimetric analyses and IR spectroscopy).
1-Cu
demonstrated permanent porosity (
V
pore
= 0.790 cm
3
g
−1
and
S
BET
= 1725 m
2
g
−1
) and significant CO
2
, CH
4
, C
2
H
2
, C
2
H
4
and C
2
H
6
gas uptakes under ambient conditions. The adsorption selectivities for gas mixtures, calculated by IAST, were 10.8 (10.7), 14.6 (9.4), 1.7 (1.6) and 1.5 (1.6) for the equimolar gas mixture compositions CO
2
/N
2
, C
2
H
6
/CH
4
, C
2
H
6
/C
2
H
4
and C
2
H
6
/C
2
H
2
at 1 bar and 273 K (298 K), respectively. The mixed-metal compound
1-ZnCu
was prepared by a crystal-to-crystal ion exchange metathesis reaction from
1-Zn
with a 52% degree of ion substitution, confirmed by energy-dispersive X-ray spectroscopy, optical microscopy and single crystal X-ray diffraction analysis.
Three new 3D metal-organic frameworks [M
2
(ttdc)
2
(dabco)] (M = Zn(
ii
),
1-Zn
; Cu(
ii
),
1-Cu
; and Zn/Cu,
1-ZnCu
) based on thieno[3,2-
b
]thiophene-2,5-dicarboxylate (ttdc
2−
) were synthesized and characterized by a combination of physicochemical methods.</description><subject>Adsorption</subject><subject>Carbon dioxide</subject><subject>Chemical synthesis</subject><subject>Gas mixtures</subject><subject>Infrared spectroscopy</subject><subject>Ion exchange</subject><subject>Metal compounds</subject><subject>Metal-organic frameworks</subject><subject>Metathesis</subject><subject>Optical microscopy</subject><subject>Single crystals</subject><subject>Spectroscopic analysis</subject><subject>Substitution reactions</subject><subject>Thermogravimetric analysis</subject><subject>X ray powder diffraction</subject><subject>X-ray diffraction</subject><issn>1477-9226</issn><issn>1477-9234</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNpdkc1PxCAQxYnR-H3xriHxYoxVKFAWb35rssaD3huWTrfVtuwCzbr_vayrayKHgcn88uaFh9ABJeeUMHVR8CKQNCVqtIa2KZcyUSnj66t3mm2hHe_fyQIS6SbaYoqlikm2jabPEHSTWDfWXW1w6XQLM-s-PJ7VocIa-74pe5e42lS4ggDOmrlp4BL7eRcq8LU_w2PtsS68dZNQ2w5PnJ2ACzXEke4K3C5WYPg0le7GsIc2St142P-5d9Hr_d3bzWMyfHl4urkaJiYaDkkGRmsWD-fSUE6pkqVIiREl44PYgYhVkFE2kGQkqDCZEcCoLFShU2C76GSpGs1Me_Ahb2tvoGl0B7b3OaOUcCIyKSJ6_A99t73rorcFlQkqB0pF6nRJGWe9d1DmE1e32s1zSvJFDPktv337juE6wkc_kv2ohWKF_v57BA6XgPNmNf3LkX0B7NCMXQ</recordid><startdate>20241015</startdate><enddate>20241015</enddate><creator>Dubskikh, Vadim A</creator><creator>Lysova, Anna A</creator><creator>Kovalenko, Konstantin A</creator><creator>Samsonenko, Denis G</creator><creator>Dybtsev, Danil N</creator><creator>Fedin, Vladimir P</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-1337-5106</orcidid><orcidid>https://orcid.org/0000-0001-8922-0066</orcidid><orcidid>https://orcid.org/0000-0003-2688-4521</orcidid><orcidid>https://orcid.org/0000-0001-8779-0612</orcidid><orcidid>https://orcid.org/0009-0000-5821-3218</orcidid><orcidid>https://orcid.org/0000-0001-7817-6370</orcidid></search><sort><creationdate>20241015</creationdate><title>Metal-organic frameworks with a sulfur-rich heterocycle: synthesis, gas adsorption properties, and metal exchange</title><author>Dubskikh, Vadim A ; Lysova, Anna A ; Kovalenko, Konstantin A ; Samsonenko, Denis G ; Dybtsev, Danil N ; Fedin, Vladimir P</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c226t-6ecaa3333447c141197f520c5f348119e581150b6870b515c6c5e317d9da2e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Adsorption</topic><topic>Carbon dioxide</topic><topic>Chemical synthesis</topic><topic>Gas mixtures</topic><topic>Infrared spectroscopy</topic><topic>Ion exchange</topic><topic>Metal compounds</topic><topic>Metal-organic frameworks</topic><topic>Metathesis</topic><topic>Optical microscopy</topic><topic>Single crystals</topic><topic>Spectroscopic analysis</topic><topic>Substitution reactions</topic><topic>Thermogravimetric analysis</topic><topic>X ray powder diffraction</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Dubskikh, Vadim A</creatorcontrib><creatorcontrib>Lysova, Anna A</creatorcontrib><creatorcontrib>Kovalenko, Konstantin A</creatorcontrib><creatorcontrib>Samsonenko, Denis G</creatorcontrib><creatorcontrib>Dybtsev, Danil N</creatorcontrib><creatorcontrib>Fedin, Vladimir P</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Dubskikh, Vadim A</au><au>Lysova, Anna A</au><au>Kovalenko, Konstantin A</au><au>Samsonenko, Denis G</au><au>Dybtsev, Danil N</au><au>Fedin, Vladimir P</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Metal-organic frameworks with a sulfur-rich heterocycle: synthesis, gas adsorption properties, and metal exchange</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><addtitle>Dalton Trans</addtitle><date>2024-10-15</date><risdate>2024</risdate><volume>53</volume><issue>4</issue><spage>16654</spage><epage>1666</epage><pages>16654-1666</pages><issn>1477-9226</issn><issn>1477-9234</issn><eissn>1477-9234</eissn><abstract>Three new three-dimensional (3D) metal-organic frameworks [M
2
(ttdc)
2
(dabco)] (M = Zn(
ii
),
1-Zn
; Cu(
ii
),
1-Cu
; and Zn/Cu,
1-ZnCu
) based on thieno[3,2-
b
]thiophene-2,5-dicarboxylate (ttdc
2−
) were synthesized and characterized by a combination of physicochemical methods (single crystal X-ray diffraction, powder X-ray diffraction, chemical and thermogravimetric analyses and IR spectroscopy).
1-Cu
demonstrated permanent porosity (
V
pore
= 0.790 cm
3
g
−1
and
S
BET
= 1725 m
2
g
−1
) and significant CO
2
, CH
4
, C
2
H
2
, C
2
H
4
and C
2
H
6
gas uptakes under ambient conditions. The adsorption selectivities for gas mixtures, calculated by IAST, were 10.8 (10.7), 14.6 (9.4), 1.7 (1.6) and 1.5 (1.6) for the equimolar gas mixture compositions CO
2
/N
2
, C
2
H
6
/CH
4
, C
2
H
6
/C
2
H
4
and C
2
H
6
/C
2
H
2
at 1 bar and 273 K (298 K), respectively. The mixed-metal compound
1-ZnCu
was prepared by a crystal-to-crystal ion exchange metathesis reaction from
1-Zn
with a 52% degree of ion substitution, confirmed by energy-dispersive X-ray spectroscopy, optical microscopy and single crystal X-ray diffraction analysis.
Three new 3D metal-organic frameworks [M
2
(ttdc)
2
(dabco)] (M = Zn(
ii
),
1-Zn
; Cu(
ii
),
1-Cu
; and Zn/Cu,
1-ZnCu
) based on thieno[3,2-
b
]thiophene-2,5-dicarboxylate (ttdc
2−
) were synthesized and characterized by a combination of physicochemical methods.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>39329373</pmid><doi>10.1039/d4dt02209b</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0002-1337-5106</orcidid><orcidid>https://orcid.org/0000-0001-8922-0066</orcidid><orcidid>https://orcid.org/0000-0003-2688-4521</orcidid><orcidid>https://orcid.org/0000-0001-8779-0612</orcidid><orcidid>https://orcid.org/0009-0000-5821-3218</orcidid><orcidid>https://orcid.org/0000-0001-7817-6370</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2024-10, Vol.53 (4), p.16654-1666 |
| issn | 1477-9226 1477-9234 1477-9234 |
| language | eng |
| recordid | cdi_rsc_primary_d4dt02209b |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Adsorption Carbon dioxide Chemical synthesis Gas mixtures Infrared spectroscopy Ion exchange Metal compounds Metal-organic frameworks Metathesis Optical microscopy Single crystals Spectroscopic analysis Substitution reactions Thermogravimetric analysis X ray powder diffraction X-ray diffraction |
| title | Metal-organic frameworks with a sulfur-rich heterocycle: synthesis, gas adsorption properties, and metal exchange |
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