Thermal decomposition of DMSO or DMF solvates: an advanced method for obtaining new hybrid bismuth() halides
Eight new solvates of 1,1′-(1,4-phenylenebis(methylene))bis(1-pyridinium) hybrid halobismuthates were obtained from dimethyl sulfoxide (DMSO) and dimethylformamide (DMF) solutions and structurally characterized. The thermal stability of the solvates was studied using TGA/DSC methods, and the appropr...
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| Veröffentlicht in: | CrystEngComm 2024-07, Vol.26 (26), p.349-35 |
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| creator | Dudko, Ekaterina M Buikin, Petr A Ilyukhin, Andey B Korlyukov, Alexander A Dorovatovskii, Pavel V Simonenko, Nikolai P Kotov, Vitalii Yu |
| description | Eight new solvates of 1,1′-(1,4-phenylenebis(methylene))bis(1-pyridinium) hybrid halobismuthates were obtained from dimethyl sulfoxide (DMSO) and dimethylformamide (DMF) solutions and structurally characterized. The thermal stability of the solvates was studied using TGA/DSC methods, and the appropriate conditions for the solvent molecule loss were defined. As a result, five new hybrid halobismuthates were prepared by the thermal decomposition of the obtained solvates. Based on the synchrotron powder X-ray diffraction data, the structure of the anionic part of the crystal products produced by the thermal decomposition of solvates was determined. The optical band gap values were defined for all the prepared products. The proposed method for obtaining new hybrid halobismuthates is prospective for the synthesis of compounds, which cannot be prepared from solutions.
Producing new hybrid halobismuthates by the thermal decomposition of corresponding solvates. |
| doi_str_mv | 10.1039/d4ce00279b |
| format | Article |
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Producing new hybrid halobismuthates by the thermal decomposition of corresponding solvates.</description><subject>Bismuth</subject><subject>Dimethyl sulfoxide</subject><subject>Dimethylformamide</subject><subject>Halides</subject><subject>Thermal decomposition</subject><subject>Thermal stability</subject><subject>X ray powder diffraction</subject><issn>1466-8033</issn><issn>1466-8033</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNpN0M1LwzAYBvAgCs7pxbsQ8KJCNWnStPGm-1BhsoPzXPLx1na0zUy6yf57qxP19LyHH88LD0KnlFxTwuSN5QYIiVOp99CAciGijDC2_-8-REchLAmhnFIyQPWiBN-oGlswrlm5UHWVa7Er8Pj5ZY6d73OKg6s3qoNwi1WLld2o1oDFDXSls7jokdOdqtqqfcMtfOByq31lsa5Cs-7Ki0tcqrqyEI7RQaHqACc_OUSv08li9BjN5g9Po7tZZGhKuohxCUow0NpkwMCoRNtYq5QIJRIrWGx1ZqS0AFLGCY9jYjhYRUUitASesSE63_WuvHtfQ-jypVv7tn-ZM5KyTGSUyV5d7ZTxLgQPRb7yVaP8Nqck_1ozH_PR5HvN-x6f7bAP5tf9rc0-AeOVcZM</recordid><startdate>20240701</startdate><enddate>20240701</enddate><creator>Dudko, Ekaterina M</creator><creator>Buikin, Petr A</creator><creator>Ilyukhin, Andey B</creator><creator>Korlyukov, Alexander A</creator><creator>Dorovatovskii, Pavel V</creator><creator>Simonenko, Nikolai P</creator><creator>Kotov, Vitalii Yu</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0002-5600-9886</orcidid><orcidid>https://orcid.org/0000-0003-3681-1799</orcidid><orcidid>https://orcid.org/0000-0002-4209-6034</orcidid><orcidid>https://orcid.org/0000-0001-7776-9342</orcidid><orcidid>https://orcid.org/0000-0001-9243-9915</orcidid><orcidid>https://orcid.org/0000-0002-2978-3614</orcidid></search><sort><creationdate>20240701</creationdate><title>Thermal decomposition of DMSO or DMF solvates: an advanced method for obtaining new hybrid bismuth() halides</title><author>Dudko, Ekaterina M ; Buikin, Petr A ; Ilyukhin, Andey B ; Korlyukov, Alexander A ; Dorovatovskii, Pavel V ; Simonenko, Nikolai P ; Kotov, Vitalii Yu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c170t-349ea63ebbc8e3eca5bd2ba706a65d632db8c99dee99254220c4eda1656b9e483</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Bismuth</topic><topic>Dimethyl sulfoxide</topic><topic>Dimethylformamide</topic><topic>Halides</topic><topic>Thermal decomposition</topic><topic>Thermal stability</topic><topic>X ray powder diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Dudko, Ekaterina M</creatorcontrib><creatorcontrib>Buikin, Petr A</creatorcontrib><creatorcontrib>Ilyukhin, Andey B</creatorcontrib><creatorcontrib>Korlyukov, Alexander A</creatorcontrib><creatorcontrib>Dorovatovskii, Pavel V</creatorcontrib><creatorcontrib>Simonenko, Nikolai P</creatorcontrib><creatorcontrib>Kotov, Vitalii Yu</creatorcontrib><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>CrystEngComm</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Dudko, Ekaterina M</au><au>Buikin, Petr A</au><au>Ilyukhin, Andey B</au><au>Korlyukov, Alexander A</au><au>Dorovatovskii, Pavel V</au><au>Simonenko, Nikolai P</au><au>Kotov, Vitalii Yu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Thermal decomposition of DMSO or DMF solvates: an advanced method for obtaining new hybrid bismuth() halides</atitle><jtitle>CrystEngComm</jtitle><date>2024-07-01</date><risdate>2024</risdate><volume>26</volume><issue>26</issue><spage>349</spage><epage>35</epage><pages>349-35</pages><issn>1466-8033</issn><eissn>1466-8033</eissn><abstract>Eight new solvates of 1,1′-(1,4-phenylenebis(methylene))bis(1-pyridinium) hybrid halobismuthates were obtained from dimethyl sulfoxide (DMSO) and dimethylformamide (DMF) solutions and structurally characterized. The thermal stability of the solvates was studied using TGA/DSC methods, and the appropriate conditions for the solvent molecule loss were defined. As a result, five new hybrid halobismuthates were prepared by the thermal decomposition of the obtained solvates. Based on the synchrotron powder X-ray diffraction data, the structure of the anionic part of the crystal products produced by the thermal decomposition of solvates was determined. The optical band gap values were defined for all the prepared products. The proposed method for obtaining new hybrid halobismuthates is prospective for the synthesis of compounds, which cannot be prepared from solutions.
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| fulltext | fulltext |
| identifier | ISSN: 1466-8033 |
| ispartof | CrystEngComm, 2024-07, Vol.26 (26), p.349-35 |
| issn | 1466-8033 1466-8033 |
| language | eng |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Bismuth Dimethyl sulfoxide Dimethylformamide Halides Thermal decomposition Thermal stability X ray powder diffraction |
| title | Thermal decomposition of DMSO or DMF solvates: an advanced method for obtaining new hybrid bismuth() halides |
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