Reversible CO insertion into the silicon-nitrogen σ-bond of an N-heterocyclic iminosilane

The reversible insertion of carbon dioxide into the silicon-nitrogen bond of an N-heterocyclic iminosilane is reported. Solution-phase thermodynamic investigations indicate that this process is thermoneutral and reversible, whereas in the solid-phase CO 2 can be stored for extended periods and is on...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2024-11, Vol.6 (89), p.1351-1354
Hauptverfasser: Wang, Jingyan, Hwang, Gi Byoung, Knapp, Caroline E, Wilson, Daniel W. N
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creator Wang, Jingyan
Hwang, Gi Byoung
Knapp, Caroline E
Wilson, Daniel W. N
description The reversible insertion of carbon dioxide into the silicon-nitrogen bond of an N-heterocyclic iminosilane is reported. Solution-phase thermodynamic investigations indicate that this process is thermoneutral and reversible, whereas in the solid-phase CO 2 can be stored for extended periods and is only released upon heating to 133 °C. The reversible insertion of carbon dioxide into the silicon-nitrogen bond of an N-heterocyclic iminosilane is reported.
doi_str_mv 10.1039/d4cc04798b
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title Reversible CO insertion into the silicon-nitrogen σ-bond of an N-heterocyclic iminosilane
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