Reversible CO insertion into the silicon-nitrogen σ-bond of an N-heterocyclic iminosilane
The reversible insertion of carbon dioxide into the silicon-nitrogen bond of an N-heterocyclic iminosilane is reported. Solution-phase thermodynamic investigations indicate that this process is thermoneutral and reversible, whereas in the solid-phase CO 2 can be stored for extended periods and is on...
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Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2024-11, Vol.6 (89), p.1351-1354 |
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creator | Wang, Jingyan Hwang, Gi Byoung Knapp, Caroline E Wilson, Daniel W. N |
description | The reversible insertion of carbon dioxide into the silicon-nitrogen bond of an N-heterocyclic iminosilane is reported. Solution-phase thermodynamic investigations indicate that this process is thermoneutral and reversible, whereas in the solid-phase CO
2
can be stored for extended periods and is only released upon heating to 133 °C.
The reversible insertion of carbon dioxide into the silicon-nitrogen bond of an N-heterocyclic iminosilane is reported. |
doi_str_mv | 10.1039/d4cc04798b |
format | Article |
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2
can be stored for extended periods and is only released upon heating to 133 °C.
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2
can be stored for extended periods and is only released upon heating to 133 °C.
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2
can be stored for extended periods and is only released upon heating to 133 °C.
The reversible insertion of carbon dioxide into the silicon-nitrogen bond of an N-heterocyclic iminosilane is reported.</abstract><doi>10.1039/d4cc04798b</doi><tpages>4</tpages></addata></record> |
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source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
title | Reversible CO insertion into the silicon-nitrogen σ-bond of an N-heterocyclic iminosilane |
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