RAFT solution polymerisation of bio-based γ-methyl-α-methylene-γ-butyrolactone monomer in DMSO and Cyrene
Reversible addition fragmentation chain transfer (RAFT) solution polymerisation of the bio-based lactone monomer γ-methyl-α-methylene-γ-butyrolactone (γMeMBL) has been demonstrated in DMSO and Cyrene. RAFT control was evidenced by control over molecular weights, low disperisites, and kinetic evaluat...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2024-12, Vol.6 (97), p.14399-1442 |
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| container_title | Chemical communications (Cambridge, England) |
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| creator | Harris, Oliver J Larder, Ryan R Jordan, Beth Prior, Imogen El-Khoury, Rita Sebakhy, Khaled O Hatton, Fiona L |
| description | Reversible addition fragmentation chain transfer (RAFT) solution polymerisation of the bio-based lactone monomer γ-methyl-α-methylene-γ-butyrolactone (γMeMBL) has been demonstrated in DMSO and Cyrene. RAFT control was evidenced by control over molecular weights, low disperisites, and kinetic evaluation. Purified P(γMeMBL) homopolymers exhibited high glass transition temperatures (206-221 °C) and excellent thermal stabilities. This work demonstrates the first RAFT solution polymerisation of γMeMBL and the first example of RAFT polymerisation in Cyrene.
We report the RAFT solution polymerisation of bio-based monomer γ-methyl-α-methylene-γ-butyrolactone in DMSO and the more sustainable solvent Cyrene. |
| doi_str_mv | 10.1039/d4cc04571h |
| format | Article |
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We report the RAFT solution polymerisation of bio-based monomer γ-methyl-α-methylene-γ-butyrolactone in DMSO and the more sustainable solvent Cyrene.</description><subject>Addition polymerization</subject><subject>Butyrolactone</subject><subject>Chain transfer</subject><subject>Glass transition temperature</subject><subject>Methylene</subject><subject>Monomers</subject><subject>Solution polymerization</subject><issn>1359-7345</issn><issn>1364-548X</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNpd0ctKxDAUBuAgipfRjXsl4EaEaNLcl0O9jKAIXsBdaZMUK20zJu2ijyW-h89kxxkVzCYnycfPIQeAfYJPCab6zDJjMOOSvKyBbUIFQ5yp5_VFzTWSlPEtsBPjKx4X4WoTbFHNuVKCb4P6fnr5CKOv-67yLZz7emhcqGL-ffQlLCqPijw6Cz8_UOO6l6FGn--ryrUOjddF3w3B17npfOtg41s_ZsCqhee3D3cwby1MhzDaXbBR5nV0e6t9Ap4uLx7TGbq5u7pOpzfIJCLpkKUMG6wl1aWjiTCslLkoLE4I1U6rgipFtJbYEkYtKZwSsmBW8ERwy3WC6QQcL3Pnwb_1LnZZU0Xj6jpvne9jRgnFCZaSL-jRP_rq-9CO3S0Ux1IIrEZ1slQm-BiDK7N5qJo8DBnB2WIG2TlL0-8ZzEZ8uIrsi8bZX_rz6SM4WIIQze_r3xDpF64ujEU</recordid><startdate>20241203</startdate><enddate>20241203</enddate><creator>Harris, Oliver J</creator><creator>Larder, Ryan R</creator><creator>Jordan, Beth</creator><creator>Prior, Imogen</creator><creator>El-Khoury, Rita</creator><creator>Sebakhy, Khaled O</creator><creator>Hatton, Fiona L</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0009-0002-3897-134X</orcidid><orcidid>https://orcid.org/0000-0002-0638-9702</orcidid><orcidid>https://orcid.org/0000-0002-0105-7530</orcidid><orcidid>https://orcid.org/0000-0002-3412-2570</orcidid></search><sort><creationdate>20241203</creationdate><title>RAFT solution polymerisation of bio-based γ-methyl-α-methylene-γ-butyrolactone monomer in DMSO and Cyrene</title><author>Harris, Oliver J ; Larder, Ryan R ; Jordan, Beth ; Prior, Imogen ; El-Khoury, Rita ; Sebakhy, Khaled O ; Hatton, Fiona L</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c262t-d340c09739fe326c4f7a6bd02139e98b38819970d143d1be867b4d65265d59203</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Addition polymerization</topic><topic>Butyrolactone</topic><topic>Chain transfer</topic><topic>Glass transition temperature</topic><topic>Methylene</topic><topic>Monomers</topic><topic>Solution polymerization</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Harris, Oliver J</creatorcontrib><creatorcontrib>Larder, Ryan R</creatorcontrib><creatorcontrib>Jordan, Beth</creatorcontrib><creatorcontrib>Prior, Imogen</creatorcontrib><creatorcontrib>El-Khoury, Rita</creatorcontrib><creatorcontrib>Sebakhy, Khaled O</creatorcontrib><creatorcontrib>Hatton, Fiona L</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Harris, Oliver J</au><au>Larder, Ryan R</au><au>Jordan, Beth</au><au>Prior, Imogen</au><au>El-Khoury, Rita</au><au>Sebakhy, Khaled O</au><au>Hatton, Fiona L</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>RAFT solution polymerisation of bio-based γ-methyl-α-methylene-γ-butyrolactone monomer in DMSO and Cyrene</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><addtitle>Chem Commun (Camb)</addtitle><date>2024-12-03</date><risdate>2024</risdate><volume>6</volume><issue>97</issue><spage>14399</spage><epage>1442</epage><pages>14399-1442</pages><issn>1359-7345</issn><issn>1364-548X</issn><eissn>1364-548X</eissn><abstract>Reversible addition fragmentation chain transfer (RAFT) solution polymerisation of the bio-based lactone monomer γ-methyl-α-methylene-γ-butyrolactone (γMeMBL) has been demonstrated in DMSO and Cyrene. RAFT control was evidenced by control over molecular weights, low disperisites, and kinetic evaluation. Purified P(γMeMBL) homopolymers exhibited high glass transition temperatures (206-221 °C) and excellent thermal stabilities. This work demonstrates the first RAFT solution polymerisation of γMeMBL and the first example of RAFT polymerisation in Cyrene.
We report the RAFT solution polymerisation of bio-based monomer γ-methyl-α-methylene-γ-butyrolactone in DMSO and the more sustainable solvent Cyrene.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>39558865</pmid><doi>10.1039/d4cc04571h</doi><tpages>4</tpages><orcidid>https://orcid.org/0009-0002-3897-134X</orcidid><orcidid>https://orcid.org/0000-0002-0638-9702</orcidid><orcidid>https://orcid.org/0000-0002-0105-7530</orcidid><orcidid>https://orcid.org/0000-0002-3412-2570</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2024-12, Vol.6 (97), p.14399-1442 |
| issn | 1359-7345 1364-548X 1364-548X |
| language | eng |
| recordid | cdi_rsc_primary_d4cc04571h |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Addition polymerization Butyrolactone Chain transfer Glass transition temperature Methylene Monomers Solution polymerization |
| title | RAFT solution polymerisation of bio-based γ-methyl-α-methylene-γ-butyrolactone monomer in DMSO and Cyrene |
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