The tetracyanoborate anion as a building block for the heterocubane cluster cage [Cr{B(CN)}]
The tetracyanoborate anion [B(CN) 4 ] − (TCB) was utilized as a building block for the synthesis of polynuclear chromium carbonyl compounds upon photolytic reaction with [Cr(CO) 6 ]. Up to four κN-coordinated cyano groups of TCB can be involved in binding to chromium, giving mixtures of [B(CN) 4− x...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2024-08, Vol.6 (65), p.8621-8624 |
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| container_title | Chemical communications (Cambridge, England) |
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| creator | Luff, Martin S Bertermann, Rüdiger Finze, Maik Radius, Udo |
| description | The tetracyanoborate anion [B(CN)
4
]
−
(TCB) was utilized as a building block for the synthesis of polynuclear chromium carbonyl compounds upon photolytic reaction with [Cr(CO)
6
]. Up to four κN-coordinated cyano groups of TCB can be involved in binding to chromium, giving mixtures of [B(CN)
4−
x
{CN-Cr(CO)
5
}
x
]
−
(
x
= 1-4;
1-4
) and [{Cr(CO)
4
(B(CN)
4
)}
2
]
2−
(
5
). The reaction of [B(CN)
4
]
−
with
fac
-[Cr(CO)
3
(MeCN)
3
] led to isolation of salts of the tetraanionic heterocubane cage [{Cr(CO)
3
(B(CN)
4
)}
4
]
4−
.
The tetracyanoborate anion [B(CN)
4
]
−
was used as a building block for the synthesis of polynuclear chromium carbonyls, such as the tetraanionic heterocubane cage [{Cr(CO)
3
(B(CN)
4
)}
4
]
4−
. |
| doi_str_mv | 10.1039/d4cc03022b |
| format | Article |
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4
]
−
(TCB) was utilized as a building block for the synthesis of polynuclear chromium carbonyl compounds upon photolytic reaction with [Cr(CO)
6
]. Up to four κN-coordinated cyano groups of TCB can be involved in binding to chromium, giving mixtures of [B(CN)
4−
x
{CN-Cr(CO)
5
}
x
]
−
(
x
= 1-4;
1-4
) and [{Cr(CO)
4
(B(CN)
4
)}
2
]
2−
(
5
). The reaction of [B(CN)
4
]
−
with
fac
-[Cr(CO)
3
(MeCN)
3
] led to isolation of salts of the tetraanionic heterocubane cage [{Cr(CO)
3
(B(CN)
4
)}
4
]
4−
.
The tetracyanoborate anion [B(CN)
4
]
−
was used as a building block for the synthesis of polynuclear chromium carbonyls, such as the tetraanionic heterocubane cage [{Cr(CO)
3
(B(CN)
4
)}
4
]
4−
.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/d4cc03022b</identifier><ispartof>Chemical communications (Cambridge, England), 2024-08, Vol.6 (65), p.8621-8624</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Luff, Martin S</creatorcontrib><creatorcontrib>Bertermann, Rüdiger</creatorcontrib><creatorcontrib>Finze, Maik</creatorcontrib><creatorcontrib>Radius, Udo</creatorcontrib><title>The tetracyanoborate anion as a building block for the heterocubane cluster cage [Cr{B(CN)}]</title><title>Chemical communications (Cambridge, England)</title><description>The tetracyanoborate anion [B(CN)
4
]
−
(TCB) was utilized as a building block for the synthesis of polynuclear chromium carbonyl compounds upon photolytic reaction with [Cr(CO)
6
]. Up to four κN-coordinated cyano groups of TCB can be involved in binding to chromium, giving mixtures of [B(CN)
4−
x
{CN-Cr(CO)
5
}
x
]
−
(
x
= 1-4;
1-4
) and [{Cr(CO)
4
(B(CN)
4
)}
2
]
2−
(
5
). The reaction of [B(CN)
4
]
−
with
fac
-[Cr(CO)
3
(MeCN)
3
] led to isolation of salts of the tetraanionic heterocubane cage [{Cr(CO)
3
(B(CN)
4
)}
4
]
4−
.
The tetracyanoborate anion [B(CN)
4
]
−
was used as a building block for the synthesis of polynuclear chromium carbonyls, such as the tetraanionic heterocubane cage [{Cr(CO)
3
(B(CN)
4
)}
4
]
4−
.</description><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFjj0LwjAYhIMo-Lm4C--oQzU1rR-rRXFy6iCoyJsY22pNJEkHEf-7FQRHb7l7OA6OkK5Phz5l89EpEIIyOh7zCmn4bBJ4YTDbVj85nHtTFoR10rT2Qkv54axB9nEqwUlnUDxQaa4NOgmoMq0ALSDwIstPmUqA51pc4awNuHKSSieNFgVHJUHkhS0RBCYSdpF5LvrRZvA6tEntjLmVna-3SG-1jKO1Z6w43k12Q_M4_i6zf_0bR6REig</recordid><startdate>20240809</startdate><enddate>20240809</enddate><creator>Luff, Martin S</creator><creator>Bertermann, Rüdiger</creator><creator>Finze, Maik</creator><creator>Radius, Udo</creator><scope/></search><sort><creationdate>20240809</creationdate><title>The tetracyanoborate anion as a building block for the heterocubane cluster cage [Cr{B(CN)}]</title><author>Luff, Martin S ; Bertermann, Rüdiger ; Finze, Maik ; Radius, Udo</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_d4cc03022b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><creationdate>2024</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Luff, Martin S</creatorcontrib><creatorcontrib>Bertermann, Rüdiger</creatorcontrib><creatorcontrib>Finze, Maik</creatorcontrib><creatorcontrib>Radius, Udo</creatorcontrib><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Luff, Martin S</au><au>Bertermann, Rüdiger</au><au>Finze, Maik</au><au>Radius, Udo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The tetracyanoborate anion as a building block for the heterocubane cluster cage [Cr{B(CN)}]</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><date>2024-08-09</date><risdate>2024</risdate><volume>6</volume><issue>65</issue><spage>8621</spage><epage>8624</epage><pages>8621-8624</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>The tetracyanoborate anion [B(CN)
4
]
−
(TCB) was utilized as a building block for the synthesis of polynuclear chromium carbonyl compounds upon photolytic reaction with [Cr(CO)
6
]. Up to four κN-coordinated cyano groups of TCB can be involved in binding to chromium, giving mixtures of [B(CN)
4−
x
{CN-Cr(CO)
5
}
x
]
−
(
x
= 1-4;
1-4
) and [{Cr(CO)
4
(B(CN)
4
)}
2
]
2−
(
5
). The reaction of [B(CN)
4
]
−
with
fac
-[Cr(CO)
3
(MeCN)
3
] led to isolation of salts of the tetraanionic heterocubane cage [{Cr(CO)
3
(B(CN)
4
)}
4
]
4−
.
The tetracyanoborate anion [B(CN)
4
]
−
was used as a building block for the synthesis of polynuclear chromium carbonyls, such as the tetraanionic heterocubane cage [{Cr(CO)
3
(B(CN)
4
)}
4
]
4−
.</abstract><doi>10.1039/d4cc03022b</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2024-08, Vol.6 (65), p.8621-8624 |
| issn | 1359-7345 1364-548X |
| language | |
| recordid | cdi_rsc_primary_d4cc03022b |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | The tetracyanoborate anion as a building block for the heterocubane cluster cage [Cr{B(CN)}] |
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