O reduction proton-coupled electron transfer by a V() aquo on a polyoxovanadate-alkoxide cluster
We report the transfer of H-atoms from a reduced polyoxovanadate alkoxide [ n Oct 4 N][V 6 O 6 (OH 2 )(OMe) 12 ] via concerted proton-electron transfer. Oxygen reduction is compared between bridging and terminal O-H bonds revealing similar mechanisms, providing new insight to design criteria for met...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2024-05, Vol.6 (43), p.561-5613 |
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| container_title | Chemical communications (Cambridge, England) |
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| creator | Cooney, Shannon E Schreiber, Eric Ferrigno, Baela M Matson, Ellen M |
| description | We report the transfer of H-atoms from a reduced polyoxovanadate alkoxide [
n
Oct
4
N][V
6
O
6
(OH
2
)(OMe)
12
]
via
concerted proton-electron transfer. Oxygen reduction is compared between bridging and terminal O-H bonds revealing similar mechanisms, providing new insight to design criteria for metal-oxide electrocatalysts that faciliate oxygen reduction by concerted-proton electron transfer.
We report the reduction of O
2
to H
2
O
2
via
concerted proton-electron transfer from the terminal V(
iii
)-OH
2
moiety of a reduced polyoxovanadate-alkoxide cluster. |
| doi_str_mv | 10.1039/d4cc01331j |
| format | Article |
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n
Oct
4
N][V
6
O
6
(OH
2
)(OMe)
12
]
via
concerted proton-electron transfer. Oxygen reduction is compared between bridging and terminal O-H bonds revealing similar mechanisms, providing new insight to design criteria for metal-oxide electrocatalysts that faciliate oxygen reduction by concerted-proton electron transfer.
We report the reduction of O
2
to H
2
O
2
via
concerted proton-electron transfer from the terminal V(
iii
)-OH
2
moiety of a reduced polyoxovanadate-alkoxide cluster.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/d4cc01331j</identifier><ispartof>Chemical communications (Cambridge, England), 2024-05, Vol.6 (43), p.561-5613</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Cooney, Shannon E</creatorcontrib><creatorcontrib>Schreiber, Eric</creatorcontrib><creatorcontrib>Ferrigno, Baela M</creatorcontrib><creatorcontrib>Matson, Ellen M</creatorcontrib><title>O reduction proton-coupled electron transfer by a V() aquo on a polyoxovanadate-alkoxide cluster</title><title>Chemical communications (Cambridge, England)</title><description>We report the transfer of H-atoms from a reduced polyoxovanadate alkoxide [
n
Oct
4
N][V
6
O
6
(OH
2
)(OMe)
12
]
via
concerted proton-electron transfer. Oxygen reduction is compared between bridging and terminal O-H bonds revealing similar mechanisms, providing new insight to design criteria for metal-oxide electrocatalysts that faciliate oxygen reduction by concerted-proton electron transfer.
We report the reduction of O
2
to H
2
O
2
via
concerted proton-electron transfer from the terminal V(
iii
)-OH
2
moiety of a reduced polyoxovanadate-alkoxide cluster.</description><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFjr9rAkEQhRcxEDVp0gtTxmKTW_bOH3WI2NmIpNPJ7ghn1ptzdi94_70XCFj6mvf4vuYp9WKyN5PZxbvPncuMtebYUwNjp7ku8vlX_28XCz2zefGohjEesy6mmA_Ufg1CvnGp5Apq4cSVdtzUgTxQIJek40mwigcS-G4BYfs6ATw3DJ1BqDm0fOFfrNBjIo3hhy-lJ3ChiYnkST0cMER6_u-RGi8_Nx8rLdHtailPKO3udtve81e3XEbj</recordid><startdate>20240523</startdate><enddate>20240523</enddate><creator>Cooney, Shannon E</creator><creator>Schreiber, Eric</creator><creator>Ferrigno, Baela M</creator><creator>Matson, Ellen M</creator><scope/></search><sort><creationdate>20240523</creationdate><title>O reduction proton-coupled electron transfer by a V() aquo on a polyoxovanadate-alkoxide cluster</title><author>Cooney, Shannon E ; Schreiber, Eric ; Ferrigno, Baela M ; Matson, Ellen M</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_d4cc01331j3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><creationdate>2024</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Cooney, Shannon E</creatorcontrib><creatorcontrib>Schreiber, Eric</creatorcontrib><creatorcontrib>Ferrigno, Baela M</creatorcontrib><creatorcontrib>Matson, Ellen M</creatorcontrib><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Cooney, Shannon E</au><au>Schreiber, Eric</au><au>Ferrigno, Baela M</au><au>Matson, Ellen M</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>O reduction proton-coupled electron transfer by a V() aquo on a polyoxovanadate-alkoxide cluster</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><date>2024-05-23</date><risdate>2024</risdate><volume>6</volume><issue>43</issue><spage>561</spage><epage>5613</epage><pages>561-5613</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>We report the transfer of H-atoms from a reduced polyoxovanadate alkoxide [
n
Oct
4
N][V
6
O
6
(OH
2
)(OMe)
12
]
via
concerted proton-electron transfer. Oxygen reduction is compared between bridging and terminal O-H bonds revealing similar mechanisms, providing new insight to design criteria for metal-oxide electrocatalysts that faciliate oxygen reduction by concerted-proton electron transfer.
We report the reduction of O
2
to H
2
O
2
via
concerted proton-electron transfer from the terminal V(
iii
)-OH
2
moiety of a reduced polyoxovanadate-alkoxide cluster.</abstract><doi>10.1039/d4cc01331j</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2024-05, Vol.6 (43), p.561-5613 |
| issn | 1359-7345 1364-548X |
| language | |
| recordid | cdi_rsc_primary_d4cc01331j |
| source | Royal Society Of Chemistry Journals; Alma/SFX Local Collection |
| title | O reduction proton-coupled electron transfer by a V() aquo on a polyoxovanadate-alkoxide cluster |
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