formation of a ZnS/In interphase for reversible Zn metal anodes at ultrahigh currents and capacities

Aqueous zinc-ion batteries (AZIBs) have been considered next-generation promising high-energy storage systems due to their cost-effectiveness and high safety. Nevertheless, the instability of the Zn metal anode posed by dendrite growth and volume changes presents a significant hurdle for AZIB commercialization. Here, we introduce a novel approach using a ZnIn 2 S 4 nanoflower-coated carbon cloth (ZISG-CC) with hierarchical spatial channels to guide the nucleation and deposition of Zn, thereby constructing a stable Zn metal anode. The designed ZISG-CC electrode exhibits distinctive features, including an enlarged surface area, enhanced zincophilicity, and in situ formation of a ZnS/In interphase during the initial discharge process. These characteristics facilitate uniform Zn nucleation and the formation of a stable electrolyte-anode interface, enabling excellent reversibility of the Zn anode. As a result, the Zn/ZISG-CC anode demonstrates outstanding charge-discharge cycling performance in a symmetric cell, achieving 550 cycles at 10 mA cm −2 /5 mA h cm −2 and 500 cycles at 20 mA cm −2 /10 mA h cm −2 . Furthermore, the Zn/ZISG-CC|MnO 2 -graphene full cell exhibits a high capacity retention of 87.5% after 1000 cycles at 1 A g −1 , along with favorable flexibility. This study introduces a novel strategy that utilizes the interaction between the electrode and electrolyte to stabilize the electrolyte-anode interface, enabling advanced Zn anodes in high-performance AZIBs. The ZnIn 2 S 4 coated carbon cloth can in situ form a ZnS/In interphase layer, which can promote homogeneous Zn deposition and improve Zn reversibility during the Zn plating/stripping process.