Direct conversion of carboxylic acids to free thiols radical relay acridine photocatalysis enabled by N-O bond cleavage

Carboxylic acids and thiols are basic chemical compounds with diverse utility and widespread reactivity. However, the direct conversion of unprotected acids to thiols is hampered due to a fundamental problem - free thiols are incompatible with the alkyl radicals formed on decarboxylation of carboxyl...

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Veröffentlicht in:	Chemical science (Cambridge) 2024-01, Vol.15 (2), p.644-65
Hauptverfasser:	Lipilin, Dmitry L, Zubkov, Mikhail O, Kosobokov, Mikhail D, Dilman, Alexander D
Format:	Artikel
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