Diaryl hypervalent bromines and chlorines: synthesis, structures and reactivities

In the field of modern organic chemistry, hypervalent compounds have become indispensable tools for synthetic chemists, finding widespread applications in both academic research and industrial settings. While iodine-based reagents have historically dominated this research field, recent focus has shifted to the potent yet relatively unexplored chemistry of diaryl λ 3 -bromanes and -chloranes. Despite their unique reactivities, the progress in their development and application within organic synthesis has been hampered by the absence of straightforward, reliable, and widely applicable preparative methods. However, recent investigations have uncovered innovative approaches and novel reactivity patterns associated with these specialized compounds. These discoveries suggest that we have only begun to tap into their potential, implying that there is much more to be explored in this captivating area of chemistry. Diaryl hypervalent bromines and chlorines emerge as a novel foundation for advancing organic chemistry. This article provides an overview of the synthetic methodology, structural variations, and the latest transformations unearthed in this context.