Cationic tetranuclear macrocyclic CaCo complexes as highly active catalysts for alternating copolymerization of propylene oxide and carbon dioxide

We found that a cationic hetero tetranuclear complex including a calcium and three cobalts exhibited high catalytic activity toward alternating copolymerization of propylene oxide (PO) and carbon dioxide (CO 2 ). The tertiary anilinium salt [PhNMe 2 H][B(C 6 F 5 ) 4 ] was the best additive to genera...

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Veröffentlicht in:	Chemical science (Cambridge) 2023-08, Vol.14 (31), p.8262-8268
Hauptverfasser:	Nagae, Haruki, Matsushiro, Saki, Okuda, Jun, Mashima, Kazushi
Format:	Artikel
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