Planar bismuth triamides: a tunable platform for main group Lewis acidity and polymerization catalysis

Geometric deformation in main group compounds can be used to elicit unique properties including strong Lewis acidity. Here we report on a family of planar bismuth( iii ) complexes ( cf. typically pyramidal structure for such compounds), which show a geometric Lewis acidity that can be further tuned...

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Veröffentlicht in:	Chemical science (Cambridge) 2023-05, Vol.14 (17), p.4549-4563
Hauptverfasser:	Hannah, Tyler J, McCarvell, W. Michael, Kirsch, Tamina, Bedard, Joseph, Hynes, Toren, Mayho, Jacqueline, Bamford, Karlee L, Vos, Cyler W, Kozak, Christopher M, George, Tanner, Masuda, Jason D, Chitnis, S. S
Format:	Artikel
Sprache:	eng
Schlagworte:	Binding Bismuth Bonding strength Catalysis Catalysts Chemistry Deformation Esters Medical materials Polymerization Ring opening polymerization Substrates
Online-Zugang:	Volltext
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