Rhodium-catalyzed annulation of hydrazines with vinylene carbonate to synthesize unsubstituted 1-aminoindole derivatives

Herein, we describe rhodium-catalysed C-H bond activation for [3 + 2] annulation using hydrazide and vinylene carbonate, providing an efficient method for synthesising unsubstituted 1-aminoindole compounds. Characterised by high yields, mild reaction conditions, and no need for external oxidants, th...

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Veröffentlicht in:	RSC advances 2024-01, Vol.14 (7), p.484-489
Hauptverfasser:	Chen, Yichun, Lu, Ziqi, He, Wenfen, Zhu, Huanyi, Lu, Weilong, Shi, Junjun, Sheng, Jie, Xie, Wucheng
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Chemical reactions Chemistry Functional groups Hydrazines Hydrogen bonds Organic chemistry Oxidizing agents Regioselectivity Rhodium
Online-Zugang:	Volltext
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