Educational series: characterizing crosslinked polymer networks

Characterization of polymer networks presents unique challenges due to the insolubility of the materials, but this also enables characterization by new techniques that take advantage of the bulk network structure. An overview of characterization methods for polymer networks is presented, including f...

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Veröffentlicht in:Polymer chemistry 2024-01, Vol.15 (4), p.219-247
Hauptverfasser: Rajawasam, Chamoni W. H, Dodo, Obed J, Weerasinghe, M. A. Sachini N, Raji, Ibrahim O, Wanasinghe, Shiwanka V, Konkolewicz, Dominik, De Alwis Watuthanthrige, Nethmi
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container_end_page 247
container_issue 4
container_start_page 219
container_title Polymer chemistry
container_volume 15
creator Rajawasam, Chamoni W. H
Dodo, Obed J
Weerasinghe, M. A. Sachini N
Raji, Ibrahim O
Wanasinghe, Shiwanka V
Konkolewicz, Dominik
De Alwis Watuthanthrige, Nethmi
description Characterization of polymer networks presents unique challenges due to the insolubility of the materials, but this also enables characterization by new techniques that take advantage of the bulk network structure. An overview of characterization methods for polymer networks is presented, including functionality by IR, swelling and gel fraction calculations, mechanical characterization, thermal characterization, evaluation of molar masses between crosslinks and surface properties. This contribution serves as a reference for researchers aiming to evaluate network properties for the first time, or to expand the range of techniques used in network characterization. Characterization of polymer networks presents unique challenges due to the insolubility of the materials, but this also enables characterization by new techniques that take advantage of the bulk network structure.
doi_str_mv 10.1039/d3py00914a
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source Royal Society Of Chemistry Journals 2008-
subjects Crosslinking
Mechanical properties
Networks
Polymers
Surface properties
Thermodynamic properties
title Educational series: characterizing crosslinked polymer networks
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