Sequential Dieckmann cyclization enables the total synthesis of 7--clusianone and 18-hydroxy-7--clusianone

A unified approach for the construction of the bicyclo[3.3.1]nonane-2,4,9-trione core of polycyclic polyprenylated acylphloroglucinols (PPAPs) was reported. This approach involves a sequential process of two distinct Dieckmann condensation reactions from the linear precursor. Using this method, the...

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Veröffentlicht in:	Organic & biomolecular chemistry 2024-01, Vol.22 (3), p.529-537
Hauptverfasser:	Wan, Yunhui, Wu, Huaimo, Xia, Linhao, Liu, Song, Ren, Yi, Xu, Hongxi, Zheng, Changwu
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