Optical grade transformation of monolayer transition metal dichalcogenides encapsulation annealing

Monolayer transition metal dichalcogenides (TMDs) have emerged as highly promising candidates for optoelectronic applications due to their direct band gap and strong light-matter interactions. However, exfoliated TMDs have demonstrated optical characteristics that fall short of expectations, primarily because of significant defects and associated doping in the synthesized TMD crystals. Here, we report the improvement of optical properties in monolayer TMDs of MoS 2 , MoSe 2 , WS 2 , and WSe 2 , by hBN-encapsulation annealing. Monolayer WSe 2 showed 2000% enhanced photoluminescence quantum yield (PLQY) and 1000% increased lifetime after encapsulation annealing at 1000 °C, which are attributed to dominant radiative recombination of excitons through dedoping of monolayer TMDs. Furthermore, after encapsulation annealing, the transport characteristics of monolayer WS 2 changed from n-type to ambipolar, along with an enhanced hole transport, which also support dedoping of annealed TMDs. This work provides an innovative approach to elevate the optical grade of monolayer TMDs, enabling the fabrication of high-performance optoelectronic devices. hBN-encapsulation annealing notably enhances the optical properties of monolayer TMDs by dedoping and improved crystallinity, offering a straightforward way to acquire optical grade TMDs and elucidating the fundamental mechanism for PL enhancement.