Atomically precise Au and Ag nanoclusters doped with a single atom as model alloy catalysts
Gold and silver nanoclusters (NCs) composed of
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| Veröffentlicht in: | Nanoscale 2024-02, Vol.16 (9), p.4514-4528 |
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| container_title | Nanoscale |
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| creator | Masuda, Shinya Sakamoto, Kosuke Tsukuda, Tatsuya |
| description | Gold and silver nanoclusters (NCs) composed of |
| doi_str_mv | 10.1039/d3nr05857c |
| format | Article |
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This minireview focuses on single-atom doping effects on thermal catalysis, electrocatalysis, and photocatalysis of atomically precise gold or silver nanoclusters.</description><identifier>ISSN: 2040-3364</identifier><identifier>EISSN: 2040-3372</identifier><identifier>DOI: 10.1039/d3nr05857c</identifier><identifier>PMID: 38294320</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Atomic properties ; Catalysis ; Catalysts ; Chemical synthesis ; Dopants ; Doping ; Gold ; Ligands ; Nanoclusters ; Silver</subject><ispartof>Nanoscale, 2024-02, Vol.16 (9), p.4514-4528</ispartof><rights>Copyright Royal Society of Chemistry 2024</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c373t-ad25595279d09a9b1f63cbc80362d1f5ce043107e2c65821d05d76dc50dd3c6a3</citedby><cites>FETCH-LOGICAL-c373t-ad25595279d09a9b1f63cbc80362d1f5ce043107e2c65821d05d76dc50dd3c6a3</cites><orcidid>0000-0002-6319-3503 ; 0000-0002-0190-6379</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,778,782,27907,27908</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/38294320$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Masuda, Shinya</creatorcontrib><creatorcontrib>Sakamoto, Kosuke</creatorcontrib><creatorcontrib>Tsukuda, Tatsuya</creatorcontrib><title>Atomically precise Au and Ag nanoclusters doped with a single atom as model alloy catalysts</title><title>Nanoscale</title><addtitle>Nanoscale</addtitle><description>Gold and silver nanoclusters (NCs) composed of <200 atoms are novel catalysts because their catalytic properties differ significantly from those of the corresponding bulk surface and can be dramatically tuned by the size (number of atoms). Doping with other metals is a promising approach for improving the catalytic performance of Au and Ag NCs. However, elucidation of the origin of the doping effects and optimization of the catalytic performance are hampered by the technical challenge of controlling the number and location of the dopants. In this regard, atomically precise Au or Ag (Au/Ag) NCs protected by ligands or polymers have recently emerged as an ideal platform because they allow regioselective substitution of single Au/Ag constituent atoms while retaining the size and morphology of the NC. Heterogeneous Au/Ag NC catalysts doped with a single atom can also be prepared by controlled calcination of ligand-protected NCs on solid supports. Comparison of thermal catalysis, electrocatalysis, and photocatalysis between the single-atom-doped and undoped Au/Ag NCs has revealed that the single-atom doping effect can be attributed to an electronic or geometric origin, depending on the dopant element and position. This minireview summarizes the recent progress of the synthesis and catalytic application of single-atom-doped, atomically precise Au/Ag NC catalysts and provides future prospects for the rational development of active and selective metal NC catalysts.
This minireview focuses on single-atom doping effects on thermal catalysis, electrocatalysis, and photocatalysis of atomically precise gold or silver nanoclusters.</description><subject>Atomic properties</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Chemical synthesis</subject><subject>Dopants</subject><subject>Doping</subject><subject>Gold</subject><subject>Ligands</subject><subject>Nanoclusters</subject><subject>Silver</subject><issn>2040-3364</issn><issn>2040-3372</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNpd0c1LwzAYBvAgitPpxbsS8CLCNM3btM2xzE8YCqInDyVL0tmRNjVpkf73Zm5OMJcE8svDyxOETiJyFRHg1woaR1jGUrmDDiiJyQQgpbvbcxKP0KH3S0ISDgnsoxFklMdAyQF6zztbV1IYM-DWaVl5jfMei0bhfIEb0Vhpet9p57GyrVb4q-o-sMC-ahZGYxFeY-FxbZU2OKTYAUvRCTP4zh-hvVIYr483-xi93d2-Th8ms-f7x2k-m0hIoZsIRRnjjKZcES74PCoTkHOZEUioikomNYkhIqmmMmEZjRRhKk2UZEQpkImAMbpY57bOfvbad0VdeamNEY22vS8op4SlDCgL9PwfXdreNWG6oGC1eJYGdblW0lnvnS6L1lW1cEMRkWJVeXEDTy8_lU8DPttE9vNaqy397TiA0zVwXm5v__4MvgFzl4Sw</recordid><startdate>20240229</startdate><enddate>20240229</enddate><creator>Masuda, Shinya</creator><creator>Sakamoto, Kosuke</creator><creator>Tsukuda, Tatsuya</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-6319-3503</orcidid><orcidid>https://orcid.org/0000-0002-0190-6379</orcidid></search><sort><creationdate>20240229</creationdate><title>Atomically precise Au and Ag nanoclusters doped with a single atom as model alloy catalysts</title><author>Masuda, Shinya ; Sakamoto, Kosuke ; Tsukuda, Tatsuya</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c373t-ad25595279d09a9b1f63cbc80362d1f5ce043107e2c65821d05d76dc50dd3c6a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Atomic properties</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Chemical synthesis</topic><topic>Dopants</topic><topic>Doping</topic><topic>Gold</topic><topic>Ligands</topic><topic>Nanoclusters</topic><topic>Silver</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Masuda, Shinya</creatorcontrib><creatorcontrib>Sakamoto, Kosuke</creatorcontrib><creatorcontrib>Tsukuda, Tatsuya</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Nanoscale</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Masuda, Shinya</au><au>Sakamoto, Kosuke</au><au>Tsukuda, Tatsuya</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Atomically precise Au and Ag nanoclusters doped with a single atom as model alloy catalysts</atitle><jtitle>Nanoscale</jtitle><addtitle>Nanoscale</addtitle><date>2024-02-29</date><risdate>2024</risdate><volume>16</volume><issue>9</issue><spage>4514</spage><epage>4528</epage><pages>4514-4528</pages><issn>2040-3364</issn><eissn>2040-3372</eissn><abstract>Gold and silver nanoclusters (NCs) composed of <200 atoms are novel catalysts because their catalytic properties differ significantly from those of the corresponding bulk surface and can be dramatically tuned by the size (number of atoms). Doping with other metals is a promising approach for improving the catalytic performance of Au and Ag NCs. However, elucidation of the origin of the doping effects and optimization of the catalytic performance are hampered by the technical challenge of controlling the number and location of the dopants. In this regard, atomically precise Au or Ag (Au/Ag) NCs protected by ligands or polymers have recently emerged as an ideal platform because they allow regioselective substitution of single Au/Ag constituent atoms while retaining the size and morphology of the NC. Heterogeneous Au/Ag NC catalysts doped with a single atom can also be prepared by controlled calcination of ligand-protected NCs on solid supports. Comparison of thermal catalysis, electrocatalysis, and photocatalysis between the single-atom-doped and undoped Au/Ag NCs has revealed that the single-atom doping effect can be attributed to an electronic or geometric origin, depending on the dopant element and position. This minireview summarizes the recent progress of the synthesis and catalytic application of single-atom-doped, atomically precise Au/Ag NC catalysts and provides future prospects for the rational development of active and selective metal NC catalysts.
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| fulltext | fulltext |
| identifier | ISSN: 2040-3364 |
| ispartof | Nanoscale, 2024-02, Vol.16 (9), p.4514-4528 |
| issn | 2040-3364 2040-3372 |
| language | eng |
| recordid | cdi_rsc_primary_d3nr05857c |
| source | Royal Society Of Chemistry Journals 2008- |
| subjects | Atomic properties Catalysis Catalysts Chemical synthesis Dopants Doping Gold Ligands Nanoclusters Silver |
| title | Atomically precise Au and Ag nanoclusters doped with a single atom as model alloy catalysts |
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