Methane capture with α-cyclodextrins
α-cyclodextrin dissolved in water binds methane giving crystals of a 1 : 1 complex in up to 57% yield. The binding constant was K a = 21 (± 1.0) M −1 . 3 A ,6 A ,3 D ,6 D -dianhydro-α-cyclodextrin which has a smaller cavity than α-cyclodextrin binds methane three fold better ( K a = 75 (± 25) M −1 )...
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| Veröffentlicht in: | New journal of chemistry 2023-08, Vol.47 (31), p.14624-14629 |
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| container_end_page | 14629 |
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| container_issue | 31 |
| container_start_page | 14624 |
| container_title | New journal of chemistry |
| container_volume | 47 |
| creator | Jessen, Cecilie Høgfeldt Bendix, Jesper Nannestad, Theis Brock Bordallo, Heloisa N Pedersen, Martin Jæger Pedersen, Christian Marcus Bols, Mikael |
| description | α-cyclodextrin dissolved in water binds methane giving crystals of a 1 : 1 complex in up to 57% yield. The binding constant was
K
a
= 21 (± 1.0) M
−1
. 3
A
,6
A
,3
D
,6
D
-dianhydro-α-cyclodextrin which has a smaller cavity than α-cyclodextrin binds methane three fold better (
K
a
= 75 (± 25) M
−1
)
α-cyclodextrin forms a crystalline 1 : 1 complex with methane that release the gas upon addition of water. |
| doi_str_mv | 10.1039/d3nj01843a |
| format | Article |
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K
a
= 21 (± 1.0) M
−1
. 3
A
,6
A
,3
D
,6
D
-dianhydro-α-cyclodextrin which has a smaller cavity than α-cyclodextrin binds methane three fold better (
K
a
= 75 (± 25) M
−1
)
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K
a
= 21 (± 1.0) M
−1
. 3
A
,6
A
,3
D
,6
D
-dianhydro-α-cyclodextrin which has a smaller cavity than α-cyclodextrin binds methane three fold better (
K
a
= 75 (± 25) M
−1
)
α-cyclodextrin forms a crystalline 1 : 1 complex with methane that release the gas upon addition of water.</description><subject>Cyclodextrins</subject><subject>Methane</subject><issn>1144-0546</issn><issn>1369-9261</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNpFkM1KxDAUhYMoOI5u3AsFcSNEc5s0TZbD-M-oG12XJL1hWsa2Ji06j-WL-ExWR3Rzz118nAMfIYfAzoBxfV7ypmagBDdbZAJcaqpTCdvjD0JQlgm5S_ZirBkDyCVMyMk99kvTYOJM1w8Bk7eqXyafH9St3aot8b0PVRP3yY43q4gHvzklz1eXT_Mbuni8vp3PFtSlCnqqpECPOtdKICLLlLEstyiUyVnKOHhrtVUlF7nMvHapR2tyYY0HXzIlNJ-S401vF9rXAWNf1O0QmnGySJWQSo1HjNTphnKhjTGgL7pQvZiwLoAV3xqKC_5w96NhNsJHGzhE98f9a-JfradZYA</recordid><startdate>20230807</startdate><enddate>20230807</enddate><creator>Jessen, Cecilie Høgfeldt</creator><creator>Bendix, Jesper</creator><creator>Nannestad, Theis Brock</creator><creator>Bordallo, Heloisa N</creator><creator>Pedersen, Martin Jæger</creator><creator>Pedersen, Christian Marcus</creator><creator>Bols, Mikael</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>H9R</scope><scope>JG9</scope><scope>KA0</scope><orcidid>https://orcid.org/0000-0003-0750-0553</orcidid><orcidid>https://orcid.org/0000-0003-4661-4895</orcidid><orcidid>https://orcid.org/0000-0002-6561-6952</orcidid></search><sort><creationdate>20230807</creationdate><title>Methane capture with α-cyclodextrins</title><author>Jessen, Cecilie Høgfeldt ; Bendix, Jesper ; Nannestad, Theis Brock ; Bordallo, Heloisa N ; Pedersen, Martin Jæger ; Pedersen, Christian Marcus ; Bols, Mikael</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c281t-864efe97984eee058ab07be48a702031fbb9b8d34765f9c2feba74baf1fd08493</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Cyclodextrins</topic><topic>Methane</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Jessen, Cecilie Høgfeldt</creatorcontrib><creatorcontrib>Bendix, Jesper</creatorcontrib><creatorcontrib>Nannestad, Theis Brock</creatorcontrib><creatorcontrib>Bordallo, Heloisa N</creatorcontrib><creatorcontrib>Pedersen, Martin Jæger</creatorcontrib><creatorcontrib>Pedersen, Christian Marcus</creatorcontrib><creatorcontrib>Bols, Mikael</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Illustrata: Natural Sciences</collection><collection>Materials Research Database</collection><collection>ProQuest Illustrata: Technology Collection</collection><jtitle>New journal of chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Jessen, Cecilie Høgfeldt</au><au>Bendix, Jesper</au><au>Nannestad, Theis Brock</au><au>Bordallo, Heloisa N</au><au>Pedersen, Martin Jæger</au><au>Pedersen, Christian Marcus</au><au>Bols, Mikael</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Methane capture with α-cyclodextrins</atitle><jtitle>New journal of chemistry</jtitle><date>2023-08-07</date><risdate>2023</risdate><volume>47</volume><issue>31</issue><spage>14624</spage><epage>14629</epage><pages>14624-14629</pages><issn>1144-0546</issn><eissn>1369-9261</eissn><abstract>α-cyclodextrin dissolved in water binds methane giving crystals of a 1 : 1 complex in up to 57% yield. The binding constant was
K
a
= 21 (± 1.0) M
−1
. 3
A
,6
A
,3
D
,6
D
-dianhydro-α-cyclodextrin which has a smaller cavity than α-cyclodextrin binds methane three fold better (
K
a
= 75 (± 25) M
−1
)
α-cyclodextrin forms a crystalline 1 : 1 complex with methane that release the gas upon addition of water.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d3nj01843a</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0003-0750-0553</orcidid><orcidid>https://orcid.org/0000-0003-4661-4895</orcidid><orcidid>https://orcid.org/0000-0002-6561-6952</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1144-0546 |
| ispartof | New journal of chemistry, 2023-08, Vol.47 (31), p.14624-14629 |
| issn | 1144-0546 1369-9261 |
| language | eng |
| recordid | cdi_rsc_primary_d3nj01843a |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Cyclodextrins Methane |
| title | Methane capture with α-cyclodextrins |
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