Fast synthesis of [1,2,3]-triazole derivatives on a Fe/Cu-embedded nano-catalytic substrate
Triazoles are biologically important compounds that play a crucial role in biomedical applications. In this study, we present an innovative and eco-friendly nanocatalyst system for synthesizing compounds via the click reaction. The system is composed of Arabic gum (AG), iron oxide magnetic nanoparti...
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| Veröffentlicht in: | Nanoscale advances 2023-09, Vol.5 (18), p.4911-4924 |
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| creator | Khaleghi, Nima Mojtabapour, Zahrasadat Rashvandi, Zahra Mohammadi, Adibeh Forouzandeh-Malati, Mohadeseh Ganjali, Fatemeh Zarei-Shokat, Simindokht Kashtiaray, Amir Taheri-Ledari, Reza Maleki, Ali |
| description | Triazoles are biologically important compounds that play a crucial role in biomedical applications. In this study, we present an innovative and eco-friendly nanocatalyst system for synthesizing compounds
via
the click reaction. The system is composed of Arabic gum (AG), iron oxide magnetic nanoparticles (Fe
3
O
4
MNPs), (3-chloropropyl) trimethoxysilane (CPTMS), 2-aminopyridine (AP), and Cu(
i
) ions. Using AP as an anchor for Cu(
i
) ions and Fe
3
O
4
MNPs allows facile separation using an external magnet. The hydrophilic nature of the Fe
3
O
4
@AG/AP-Cu(
i
) nanocomposite makes it highly efficient in water as a green solvent. The highest reaction efficiency (95.0%) was achieved in H
2
O solvent with 50.0 mg of nanocatalyst for 60 min at room temperature. The reaction yield remained consistent for six runs, demonstrating the stability and effectiveness of the catalyst.
Synthesis of [1,2,3]-triazole derivative by using a novel green magnetic nanocatalyst based on hydrophilic natural polymer Arabic gum and copper ions. |
| doi_str_mv | 10.1039/d3na00326d |
| format | Article |
| fullrecord | <record><control><sourceid>pubmed_rsc_p</sourceid><recordid>TN_cdi_rsc_primary_d3na00326d</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>37705809</sourcerecordid><originalsourceid>FETCH-LOGICAL-c368t-523a070e91616d20e25f0d88342060d3d41c2e402af78941777e98635091ccda3</originalsourceid><addsrcrecordid>eNpVkc1PwkAQxTdGIwS5eNfs2VCZ_Wi3PRkCoiZEL3oipll2p7IGWtJdSPCvt4oinmaS95v3kjeEnDO4ZiCyvhWlBhA8sUekzWOWRMAFHB_sLdL1_h0AOJNSquyUtIRSEKeQtcl0rH2gfluGOXrnaVXQKevxnniNQu30R7VAarF2Gx3cBhu9pJqOsT9cR7icobVoaanLKjI66MU2OEP9euZDrQOekZNCLzx2f2aHvIxvn4f30eTp7mE4mERGJGmIYi40KMCMJSyxHJDHBdg0FZJDAlZYyQxHCVwXKs0kU0phliYihowZY7XokJud72o9W6I1WDbxi3xVu6Wut3mlXf5fKd08f6s2OQOZJWmqGoernYOpK-9rLPbHDPKvmvOReBx81zxq4MvDuD36W2oDXOyA2pu9-vcn8Qkf5YE_</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Fast synthesis of [1,2,3]-triazole derivatives on a Fe/Cu-embedded nano-catalytic substrate</title><source>DOAJ Directory of Open Access Journals</source><source>EZB-FREE-00999 freely available EZB journals</source><source>PubMed Central</source><creator>Khaleghi, Nima ; Mojtabapour, Zahrasadat ; Rashvandi, Zahra ; Mohammadi, Adibeh ; Forouzandeh-Malati, Mohadeseh ; Ganjali, Fatemeh ; Zarei-Shokat, Simindokht ; Kashtiaray, Amir ; Taheri-Ledari, Reza ; Maleki, Ali</creator><creatorcontrib>Khaleghi, Nima ; Mojtabapour, Zahrasadat ; Rashvandi, Zahra ; Mohammadi, Adibeh ; Forouzandeh-Malati, Mohadeseh ; Ganjali, Fatemeh ; Zarei-Shokat, Simindokht ; Kashtiaray, Amir ; Taheri-Ledari, Reza ; Maleki, Ali</creatorcontrib><description>Triazoles are biologically important compounds that play a crucial role in biomedical applications. In this study, we present an innovative and eco-friendly nanocatalyst system for synthesizing compounds
via
the click reaction. The system is composed of Arabic gum (AG), iron oxide magnetic nanoparticles (Fe
3
O
4
MNPs), (3-chloropropyl) trimethoxysilane (CPTMS), 2-aminopyridine (AP), and Cu(
i
) ions. Using AP as an anchor for Cu(
i
) ions and Fe
3
O
4
MNPs allows facile separation using an external magnet. The hydrophilic nature of the Fe
3
O
4
@AG/AP-Cu(
i
) nanocomposite makes it highly efficient in water as a green solvent. The highest reaction efficiency (95.0%) was achieved in H
2
O solvent with 50.0 mg of nanocatalyst for 60 min at room temperature. The reaction yield remained consistent for six runs, demonstrating the stability and effectiveness of the catalyst.
Synthesis of [1,2,3]-triazole derivative by using a novel green magnetic nanocatalyst based on hydrophilic natural polymer Arabic gum and copper ions.</description><identifier>ISSN: 2516-0230</identifier><identifier>EISSN: 2516-0230</identifier><identifier>DOI: 10.1039/d3na00326d</identifier><identifier>PMID: 37705809</identifier><language>eng</language><publisher>England: RSC</publisher><subject>Chemistry</subject><ispartof>Nanoscale advances, 2023-09, Vol.5 (18), p.4911-4924</ispartof><rights>This journal is © The Royal Society of Chemistry.</rights><rights>This journal is © The Royal Society of Chemistry 2023 RSC</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c368t-523a070e91616d20e25f0d88342060d3d41c2e402af78941777e98635091ccda3</citedby><cites>FETCH-LOGICAL-c368t-523a070e91616d20e25f0d88342060d3d41c2e402af78941777e98635091ccda3</cites><orcidid>0000-0001-5490-3350 ; 0000-0002-6511-9411 ; 0000-0002-3813-7147</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC10496887/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC10496887/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,727,780,784,864,885,27924,27925,53791,53793</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/37705809$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Khaleghi, Nima</creatorcontrib><creatorcontrib>Mojtabapour, Zahrasadat</creatorcontrib><creatorcontrib>Rashvandi, Zahra</creatorcontrib><creatorcontrib>Mohammadi, Adibeh</creatorcontrib><creatorcontrib>Forouzandeh-Malati, Mohadeseh</creatorcontrib><creatorcontrib>Ganjali, Fatemeh</creatorcontrib><creatorcontrib>Zarei-Shokat, Simindokht</creatorcontrib><creatorcontrib>Kashtiaray, Amir</creatorcontrib><creatorcontrib>Taheri-Ledari, Reza</creatorcontrib><creatorcontrib>Maleki, Ali</creatorcontrib><title>Fast synthesis of [1,2,3]-triazole derivatives on a Fe/Cu-embedded nano-catalytic substrate</title><title>Nanoscale advances</title><addtitle>Nanoscale Adv</addtitle><description>Triazoles are biologically important compounds that play a crucial role in biomedical applications. In this study, we present an innovative and eco-friendly nanocatalyst system for synthesizing compounds
via
the click reaction. The system is composed of Arabic gum (AG), iron oxide magnetic nanoparticles (Fe
3
O
4
MNPs), (3-chloropropyl) trimethoxysilane (CPTMS), 2-aminopyridine (AP), and Cu(
i
) ions. Using AP as an anchor for Cu(
i
) ions and Fe
3
O
4
MNPs allows facile separation using an external magnet. The hydrophilic nature of the Fe
3
O
4
@AG/AP-Cu(
i
) nanocomposite makes it highly efficient in water as a green solvent. The highest reaction efficiency (95.0%) was achieved in H
2
O solvent with 50.0 mg of nanocatalyst for 60 min at room temperature. The reaction yield remained consistent for six runs, demonstrating the stability and effectiveness of the catalyst.
Synthesis of [1,2,3]-triazole derivative by using a novel green magnetic nanocatalyst based on hydrophilic natural polymer Arabic gum and copper ions.</description><subject>Chemistry</subject><issn>2516-0230</issn><issn>2516-0230</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNpVkc1PwkAQxTdGIwS5eNfs2VCZ_Wi3PRkCoiZEL3oipll2p7IGWtJdSPCvt4oinmaS95v3kjeEnDO4ZiCyvhWlBhA8sUekzWOWRMAFHB_sLdL1_h0AOJNSquyUtIRSEKeQtcl0rH2gfluGOXrnaVXQKevxnniNQu30R7VAarF2Gx3cBhu9pJqOsT9cR7icobVoaanLKjI66MU2OEP9euZDrQOekZNCLzx2f2aHvIxvn4f30eTp7mE4mERGJGmIYi40KMCMJSyxHJDHBdg0FZJDAlZYyQxHCVwXKs0kU0phliYihowZY7XokJud72o9W6I1WDbxi3xVu6Wut3mlXf5fKd08f6s2OQOZJWmqGoernYOpK-9rLPbHDPKvmvOReBx81zxq4MvDuD36W2oDXOyA2pu9-vcn8Qkf5YE_</recordid><startdate>20230912</startdate><enddate>20230912</enddate><creator>Khaleghi, Nima</creator><creator>Mojtabapour, Zahrasadat</creator><creator>Rashvandi, Zahra</creator><creator>Mohammadi, Adibeh</creator><creator>Forouzandeh-Malati, Mohadeseh</creator><creator>Ganjali, Fatemeh</creator><creator>Zarei-Shokat, Simindokht</creator><creator>Kashtiaray, Amir</creator><creator>Taheri-Ledari, Reza</creator><creator>Maleki, Ali</creator><general>RSC</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0001-5490-3350</orcidid><orcidid>https://orcid.org/0000-0002-6511-9411</orcidid><orcidid>https://orcid.org/0000-0002-3813-7147</orcidid></search><sort><creationdate>20230912</creationdate><title>Fast synthesis of [1,2,3]-triazole derivatives on a Fe/Cu-embedded nano-catalytic substrate</title><author>Khaleghi, Nima ; Mojtabapour, Zahrasadat ; Rashvandi, Zahra ; Mohammadi, Adibeh ; Forouzandeh-Malati, Mohadeseh ; Ganjali, Fatemeh ; Zarei-Shokat, Simindokht ; Kashtiaray, Amir ; Taheri-Ledari, Reza ; Maleki, Ali</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c368t-523a070e91616d20e25f0d88342060d3d41c2e402af78941777e98635091ccda3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Khaleghi, Nima</creatorcontrib><creatorcontrib>Mojtabapour, Zahrasadat</creatorcontrib><creatorcontrib>Rashvandi, Zahra</creatorcontrib><creatorcontrib>Mohammadi, Adibeh</creatorcontrib><creatorcontrib>Forouzandeh-Malati, Mohadeseh</creatorcontrib><creatorcontrib>Ganjali, Fatemeh</creatorcontrib><creatorcontrib>Zarei-Shokat, Simindokht</creatorcontrib><creatorcontrib>Kashtiaray, Amir</creatorcontrib><creatorcontrib>Taheri-Ledari, Reza</creatorcontrib><creatorcontrib>Maleki, Ali</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Nanoscale advances</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Khaleghi, Nima</au><au>Mojtabapour, Zahrasadat</au><au>Rashvandi, Zahra</au><au>Mohammadi, Adibeh</au><au>Forouzandeh-Malati, Mohadeseh</au><au>Ganjali, Fatemeh</au><au>Zarei-Shokat, Simindokht</au><au>Kashtiaray, Amir</au><au>Taheri-Ledari, Reza</au><au>Maleki, Ali</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Fast synthesis of [1,2,3]-triazole derivatives on a Fe/Cu-embedded nano-catalytic substrate</atitle><jtitle>Nanoscale advances</jtitle><addtitle>Nanoscale Adv</addtitle><date>2023-09-12</date><risdate>2023</risdate><volume>5</volume><issue>18</issue><spage>4911</spage><epage>4924</epage><pages>4911-4924</pages><issn>2516-0230</issn><eissn>2516-0230</eissn><abstract>Triazoles are biologically important compounds that play a crucial role in biomedical applications. In this study, we present an innovative and eco-friendly nanocatalyst system for synthesizing compounds
via
the click reaction. The system is composed of Arabic gum (AG), iron oxide magnetic nanoparticles (Fe
3
O
4
MNPs), (3-chloropropyl) trimethoxysilane (CPTMS), 2-aminopyridine (AP), and Cu(
i
) ions. Using AP as an anchor for Cu(
i
) ions and Fe
3
O
4
MNPs allows facile separation using an external magnet. The hydrophilic nature of the Fe
3
O
4
@AG/AP-Cu(
i
) nanocomposite makes it highly efficient in water as a green solvent. The highest reaction efficiency (95.0%) was achieved in H
2
O solvent with 50.0 mg of nanocatalyst for 60 min at room temperature. The reaction yield remained consistent for six runs, demonstrating the stability and effectiveness of the catalyst.
Synthesis of [1,2,3]-triazole derivative by using a novel green magnetic nanocatalyst based on hydrophilic natural polymer Arabic gum and copper ions.</abstract><cop>England</cop><pub>RSC</pub><pmid>37705809</pmid><doi>10.1039/d3na00326d</doi><tpages>14</tpages><orcidid>https://orcid.org/0000-0001-5490-3350</orcidid><orcidid>https://orcid.org/0000-0002-6511-9411</orcidid><orcidid>https://orcid.org/0000-0002-3813-7147</orcidid><oa>free_for_read</oa></addata></record> |
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| subjects | Chemistry |
| title | Fast synthesis of [1,2,3]-triazole derivatives on a Fe/Cu-embedded nano-catalytic substrate |
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