The elusive active species in nickel()-mediated oxidations of hydrocarbons by peracids: a Ni-oxyl species, an aroyloxy radical, or a Ni-peracid complex?
Nonheme nickel( ii )-mediated oxidations of hydrocarbons by meta -chloroperbenzoic acid ( m CPBA) show promising activity and selectivity; however, the active species and the reaction mechanism of these reactions are still elusive after decades of efforts. Herein, a novel free radical chain mechanis...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2023-06, Vol.52 (25), p.8676-8684 |
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| Hauptverfasser: | , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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