B(3,4,5-FHC) Lewis acid-catalysed C3-allylation of indoles
Herein we report the B(3,4,5-F 3 H 2 C 6 ) 3 -catalysed C3-allylation of indoles using allylic esters. 25 examples of C3-allylated products are presented in up to 97% yield. The mechanism for the reaction was explored using detailed Density Functional Theory (DFT) studies. Herein we report the B(3,4...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2023-04, Vol.52 (16), p.539-543 |
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| container_end_page | 543 |
|---|---|
| container_issue | 16 |
| container_start_page | 539 |
| container_title | Dalton transactions : an international journal of inorganic chemistry |
| container_volume | 52 |
| creator | Alotaibi, Nusaybah Babaahmadi, Rasool Pramanik, Milan Kaehler, Tanja Dasgupta, Ayan Richards, Emma Ariafard, Alireza Wirth, Thomas Melen, Rebecca L |
| description | Herein we report the B(3,4,5-F
3
H
2
C
6
)
3
-catalysed C3-allylation of indoles using allylic esters. 25 examples of C3-allylated products are presented in up to 97% yield. The mechanism for the reaction was explored using detailed Density Functional Theory (DFT) studies.
Herein we report the B(3,4,5-F
3
H
2
C
6
)
3
-catalysed C3-allylation of indoles using allylic esters. |
| doi_str_mv | 10.1039/d3dt00745f |
| format | Article |
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3
H
2
C
6
)
3
-catalysed C3-allylation of indoles using allylic esters. 25 examples of C3-allylated products are presented in up to 97% yield. The mechanism for the reaction was explored using detailed Density Functional Theory (DFT) studies.
Herein we report the B(3,4,5-F
3
H
2
C
6
)
3
-catalysed C3-allylation of indoles using allylic esters.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/d3dt00745f</identifier><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2023-04, Vol.52 (16), p.539-543</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Alotaibi, Nusaybah</creatorcontrib><creatorcontrib>Babaahmadi, Rasool</creatorcontrib><creatorcontrib>Pramanik, Milan</creatorcontrib><creatorcontrib>Kaehler, Tanja</creatorcontrib><creatorcontrib>Dasgupta, Ayan</creatorcontrib><creatorcontrib>Richards, Emma</creatorcontrib><creatorcontrib>Ariafard, Alireza</creatorcontrib><creatorcontrib>Wirth, Thomas</creatorcontrib><creatorcontrib>Melen, Rebecca L</creatorcontrib><title>B(3,4,5-FHC) Lewis acid-catalysed C3-allylation of indoles</title><title>Dalton transactions : an international journal of inorganic chemistry</title><description>Herein we report the B(3,4,5-F
3
H
2
C
6
)
3
-catalysed C3-allylation of indoles using allylic esters. 25 examples of C3-allylated products are presented in up to 97% yield. The mechanism for the reaction was explored using detailed Density Functional Theory (DFT) studies.
Herein we report the B(3,4,5-F
3
H
2
C
6
)
3
-catalysed C3-allylation of indoles using allylic esters.</description><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNpjYBAyNNAzNDC21E8xTikxMDA3MU1jYuA0NDE317U0MjZhgbONzDgYuIqLswwMjIwMTI04GaycNIx1THRMdd08nDUVfFLLM4sVEpMzU3STE0sScyqLU1MUnI11E3NyKnMSSzLz8xTy0xQy81Lyc1KLeRhY0xJzilN5oTQ3g6yba4izh25RcXJ8QVFmbmJRZTzCQcaE5AEFuTZL</recordid><startdate>20230425</startdate><enddate>20230425</enddate><creator>Alotaibi, Nusaybah</creator><creator>Babaahmadi, Rasool</creator><creator>Pramanik, Milan</creator><creator>Kaehler, Tanja</creator><creator>Dasgupta, Ayan</creator><creator>Richards, Emma</creator><creator>Ariafard, Alireza</creator><creator>Wirth, Thomas</creator><creator>Melen, Rebecca L</creator><scope/></search><sort><creationdate>20230425</creationdate><title>B(3,4,5-FHC) Lewis acid-catalysed C3-allylation of indoles</title><author>Alotaibi, Nusaybah ; Babaahmadi, Rasool ; Pramanik, Milan ; Kaehler, Tanja ; Dasgupta, Ayan ; Richards, Emma ; Ariafard, Alireza ; Wirth, Thomas ; Melen, Rebecca L</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_d3dt00745f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><creationdate>2023</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Alotaibi, Nusaybah</creatorcontrib><creatorcontrib>Babaahmadi, Rasool</creatorcontrib><creatorcontrib>Pramanik, Milan</creatorcontrib><creatorcontrib>Kaehler, Tanja</creatorcontrib><creatorcontrib>Dasgupta, Ayan</creatorcontrib><creatorcontrib>Richards, Emma</creatorcontrib><creatorcontrib>Ariafard, Alireza</creatorcontrib><creatorcontrib>Wirth, Thomas</creatorcontrib><creatorcontrib>Melen, Rebecca L</creatorcontrib><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Alotaibi, Nusaybah</au><au>Babaahmadi, Rasool</au><au>Pramanik, Milan</au><au>Kaehler, Tanja</au><au>Dasgupta, Ayan</au><au>Richards, Emma</au><au>Ariafard, Alireza</au><au>Wirth, Thomas</au><au>Melen, Rebecca L</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>B(3,4,5-FHC) Lewis acid-catalysed C3-allylation of indoles</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><date>2023-04-25</date><risdate>2023</risdate><volume>52</volume><issue>16</issue><spage>539</spage><epage>543</epage><pages>539-543</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>Herein we report the B(3,4,5-F
3
H
2
C
6
)
3
-catalysed C3-allylation of indoles using allylic esters. 25 examples of C3-allylated products are presented in up to 97% yield. The mechanism for the reaction was explored using detailed Density Functional Theory (DFT) studies.
Herein we report the B(3,4,5-F
3
H
2
C
6
)
3
-catalysed C3-allylation of indoles using allylic esters.</abstract><doi>10.1039/d3dt00745f</doi><tpages>5</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2023-04, Vol.52 (16), p.539-543 |
| issn | 1477-9226 1477-9234 |
| language | |
| recordid | cdi_rsc_primary_d3dt00745f |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | B(3,4,5-FHC) Lewis acid-catalysed C3-allylation of indoles |
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