First comparison of catalytic CO reduction to CO over molybdenum carbide, nitride and phosphide catalysts
Carbonization, nitridation and phosphorization of Mo/CNT precursors can lead to the formation of β-Mo 2 C, a γ-Mo 2 N/β-Mo 2 C mixture and MoP, respectively, on the CNT support. It was proposed that the γ-Mo 2 N phase showed better reverse water gas shift (RWGS) performance than the β-Mo 2 C and MoP...
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| Veröffentlicht in: | Catalysis science & technology 2023-11, Vol.13 (22), p.636-6365 |
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| container_title | Catalysis science & technology |
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| creator | Rong, Qingshan Ding, Wei Liu, Guogang Zhang, Zhiqiang Yao, Zhiwei |
| description | Carbonization, nitridation and phosphorization of Mo/CNT precursors can lead to the formation of β-Mo
2
C, a γ-Mo
2
N/β-Mo
2
C mixture and MoP, respectively, on the CNT support. It was proposed that the γ-Mo
2
N phase showed better reverse water gas shift (RWGS) performance than the β-Mo
2
C and MoP phases, which can be due to its higher oxophilicity and weaker affinity with CO. Noticeably, this nitrided Mo/CNT catalyst showed comparable RWGS performance to bimetallic Cu/β-Mo
2
C (recently known to be the most excellent non-noble metal catalyst for the RWGS).
The nitrided Mo/CNT catalyst can show comparable reverse water gas shift (RWGS) performance to the bimetallic Cu/β-Mo
2
C catalyst under similar conditions. |
| doi_str_mv | 10.1039/d3cy00979c |
| format | Article |
| fullrecord | <record><control><sourceid>rsc</sourceid><recordid>TN_cdi_rsc_primary_d3cy00979c</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>d3cy00979c</sourcerecordid><originalsourceid>FETCH-rsc_primary_d3cy00979c3</originalsourceid><addsrcrecordid>eNqFT8EKgkAUXKKgqC7dg_cBWWta5lmSbl26y7q74oa68t4a-PcZRR2by8www8AwtvL51udBvFOB7DmPo1iO2GzPw9ALo6M__upDMGVLojsfEMY-P-1nzKQGyYG0dSvQkG3AFiCFE1XvjITkCqhVJ50ZEmdf3j40Qm2rPle66eqhjLlRegONcTgIEI2CtrTUli_33iJHCzYpREV6-eE5W6fnW3LxkGTWoqkF9tnvQvAvfwIBGEr8</addsrcrecordid><sourcetype>Publisher</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>First comparison of catalytic CO reduction to CO over molybdenum carbide, nitride and phosphide catalysts</title><source>Royal Society Of Chemistry Journals 2008-</source><creator>Rong, Qingshan ; Ding, Wei ; Liu, Guogang ; Zhang, Zhiqiang ; Yao, Zhiwei</creator><creatorcontrib>Rong, Qingshan ; Ding, Wei ; Liu, Guogang ; Zhang, Zhiqiang ; Yao, Zhiwei</creatorcontrib><description>Carbonization, nitridation and phosphorization of Mo/CNT precursors can lead to the formation of β-Mo
2
C, a γ-Mo
2
N/β-Mo
2
C mixture and MoP, respectively, on the CNT support. It was proposed that the γ-Mo
2
N phase showed better reverse water gas shift (RWGS) performance than the β-Mo
2
C and MoP phases, which can be due to its higher oxophilicity and weaker affinity with CO. Noticeably, this nitrided Mo/CNT catalyst showed comparable RWGS performance to bimetallic Cu/β-Mo
2
C (recently known to be the most excellent non-noble metal catalyst for the RWGS).
The nitrided Mo/CNT catalyst can show comparable reverse water gas shift (RWGS) performance to the bimetallic Cu/β-Mo
2
C catalyst under similar conditions.</description><identifier>ISSN: 2044-4753</identifier><identifier>EISSN: 2044-4761</identifier><identifier>DOI: 10.1039/d3cy00979c</identifier><ispartof>Catalysis science & technology, 2023-11, Vol.13 (22), p.636-6365</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Rong, Qingshan</creatorcontrib><creatorcontrib>Ding, Wei</creatorcontrib><creatorcontrib>Liu, Guogang</creatorcontrib><creatorcontrib>Zhang, Zhiqiang</creatorcontrib><creatorcontrib>Yao, Zhiwei</creatorcontrib><title>First comparison of catalytic CO reduction to CO over molybdenum carbide, nitride and phosphide catalysts</title><title>Catalysis science & technology</title><description>Carbonization, nitridation and phosphorization of Mo/CNT precursors can lead to the formation of β-Mo
2
C, a γ-Mo
2
N/β-Mo
2
C mixture and MoP, respectively, on the CNT support. It was proposed that the γ-Mo
2
N phase showed better reverse water gas shift (RWGS) performance than the β-Mo
2
C and MoP phases, which can be due to its higher oxophilicity and weaker affinity with CO. Noticeably, this nitrided Mo/CNT catalyst showed comparable RWGS performance to bimetallic Cu/β-Mo
2
C (recently known to be the most excellent non-noble metal catalyst for the RWGS).
The nitrided Mo/CNT catalyst can show comparable reverse water gas shift (RWGS) performance to the bimetallic Cu/β-Mo
2
C catalyst under similar conditions.</description><issn>2044-4753</issn><issn>2044-4761</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFT8EKgkAUXKKgqC7dg_cBWWta5lmSbl26y7q74oa68t4a-PcZRR2by8www8AwtvL51udBvFOB7DmPo1iO2GzPw9ALo6M__upDMGVLojsfEMY-P-1nzKQGyYG0dSvQkG3AFiCFE1XvjITkCqhVJ50ZEmdf3j40Qm2rPle66eqhjLlRegONcTgIEI2CtrTUli_33iJHCzYpREV6-eE5W6fnW3LxkGTWoqkF9tnvQvAvfwIBGEr8</recordid><startdate>20231113</startdate><enddate>20231113</enddate><creator>Rong, Qingshan</creator><creator>Ding, Wei</creator><creator>Liu, Guogang</creator><creator>Zhang, Zhiqiang</creator><creator>Yao, Zhiwei</creator><scope/></search><sort><creationdate>20231113</creationdate><title>First comparison of catalytic CO reduction to CO over molybdenum carbide, nitride and phosphide catalysts</title><author>Rong, Qingshan ; Ding, Wei ; Liu, Guogang ; Zhang, Zhiqiang ; Yao, Zhiwei</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_d3cy00979c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><creationdate>2023</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Rong, Qingshan</creatorcontrib><creatorcontrib>Ding, Wei</creatorcontrib><creatorcontrib>Liu, Guogang</creatorcontrib><creatorcontrib>Zhang, Zhiqiang</creatorcontrib><creatorcontrib>Yao, Zhiwei</creatorcontrib><jtitle>Catalysis science & technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Rong, Qingshan</au><au>Ding, Wei</au><au>Liu, Guogang</au><au>Zhang, Zhiqiang</au><au>Yao, Zhiwei</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>First comparison of catalytic CO reduction to CO over molybdenum carbide, nitride and phosphide catalysts</atitle><jtitle>Catalysis science & technology</jtitle><date>2023-11-13</date><risdate>2023</risdate><volume>13</volume><issue>22</issue><spage>636</spage><epage>6365</epage><pages>636-6365</pages><issn>2044-4753</issn><eissn>2044-4761</eissn><abstract>Carbonization, nitridation and phosphorization of Mo/CNT precursors can lead to the formation of β-Mo
2
C, a γ-Mo
2
N/β-Mo
2
C mixture and MoP, respectively, on the CNT support. It was proposed that the γ-Mo
2
N phase showed better reverse water gas shift (RWGS) performance than the β-Mo
2
C and MoP phases, which can be due to its higher oxophilicity and weaker affinity with CO. Noticeably, this nitrided Mo/CNT catalyst showed comparable RWGS performance to bimetallic Cu/β-Mo
2
C (recently known to be the most excellent non-noble metal catalyst for the RWGS).
The nitrided Mo/CNT catalyst can show comparable reverse water gas shift (RWGS) performance to the bimetallic Cu/β-Mo
2
C catalyst under similar conditions.</abstract><doi>10.1039/d3cy00979c</doi><tpages>6</tpages></addata></record> |
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| ispartof | Catalysis science & technology, 2023-11, Vol.13 (22), p.636-6365 |
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| source | Royal Society Of Chemistry Journals 2008- |
| title | First comparison of catalytic CO reduction to CO over molybdenum carbide, nitride and phosphide catalysts |
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