Remote control of anion binding by CH-based receptors

We show that the substitution of tetra(benzimidazole)resorcin[4]arenes with electron withdrawing groups on the upper rim enhances anion binding at the opposite edge by more than three orders of magnitude. Moreover, selective anion binding at either the OH/NH or CH binding sites is demonstrated. We s...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2024-03, Vol.6 (25), p.3417-342
Hauptverfasser: Jurek, Paulina, Szyma ski, Marek P, Szumna, Agnieszka
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creator Jurek, Paulina
Szyma ski, Marek P
Szumna, Agnieszka
description We show that the substitution of tetra(benzimidazole)resorcin[4]arenes with electron withdrawing groups on the upper rim enhances anion binding at the opposite edge by more than three orders of magnitude. Moreover, selective anion binding at either the OH/NH or CH binding sites is demonstrated. We show that the substitution of tetra(benzimidazole)resorcin[4]arenes with electron withdrawing groups on the upper rim enhances anion binding at the opposite edge by more than three orders of magnitude.
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Anions
Aromatic compounds
Binding sites
Remote control
title Remote control of anion binding by CH-based receptors
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