B(CF)-catalyzed regio- and stereoselective thiosulfonylation of terminal alkynes with thiosulfonates
Herein, a metal-free main-group catalysis system for thiosulfonylation of terminal alkynes with thiosulfonates has been established by using commercially available B(C 6 F 5 ) 3 as a catalyst. The protocol provides a highly regio- and stereoselective route for the synthesis of diverse ( E )-(β)-aryl...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2023-06, Vol.59 (51), p.7951-7954 |
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| container_issue | 51 |
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| container_title | Chemical communications (Cambridge, England) |
| container_volume | 59 |
| creator | Qin, Wenjie Ni, Qian Jiao, Wenjun Ma, Yuanhong |
| description | Herein, a metal-free main-group catalysis system for thiosulfonylation of terminal alkynes with thiosulfonates has been established by using commercially available B(C
6
F
5
)
3
as a catalyst. The protocol provides a highly regio- and stereoselective route for the synthesis of diverse (
E
)-(β)-arylthiolvinyl sulfones under mild conditions with 100% atom-economy and exceptional functional group compatibility.
Herein, we report a B(C
6
F
5
)
3
-catalyzed highly regio- and stereoselective thiosulfonylation of terminal alkynes with thiosulfonates to access diverse (
E
)-(β)-arylthiolvinyl sulfones. |
| doi_str_mv | 10.1039/d3cc02151c |
| format | Article |
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6
F
5
)
3
as a catalyst. The protocol provides a highly regio- and stereoselective route for the synthesis of diverse (
E
)-(β)-arylthiolvinyl sulfones under mild conditions with 100% atom-economy and exceptional functional group compatibility.
Herein, we report a B(C
6
F
5
)
3
-catalyzed highly regio- and stereoselective thiosulfonylation of terminal alkynes with thiosulfonates to access diverse (
E
)-(β)-arylthiolvinyl sulfones.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/d3cc02151c</identifier><ispartof>Chemical communications (Cambridge, England), 2023-06, Vol.59 (51), p.7951-7954</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Qin, Wenjie</creatorcontrib><creatorcontrib>Ni, Qian</creatorcontrib><creatorcontrib>Jiao, Wenjun</creatorcontrib><creatorcontrib>Ma, Yuanhong</creatorcontrib><title>B(CF)-catalyzed regio- and stereoselective thiosulfonylation of terminal alkynes with thiosulfonates</title><title>Chemical communications (Cambridge, England)</title><description>Herein, a metal-free main-group catalysis system for thiosulfonylation of terminal alkynes with thiosulfonates has been established by using commercially available B(C
6
F
5
)
3
as a catalyst. The protocol provides a highly regio- and stereoselective route for the synthesis of diverse (
E
)-(β)-arylthiolvinyl sulfones under mild conditions with 100% atom-economy and exceptional functional group compatibility.
Herein, we report a B(C
6
F
5
)
3
-catalyzed highly regio- and stereoselective thiosulfonylation of terminal alkynes with thiosulfonates to access diverse (
E
)-(β)-arylthiolvinyl sulfones.</description><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFjrFuwjAURa2qSKWFhR3JYxncxjgGsjYC8QEM3aIn54UYHBv5uUXh60ulSmXjLvdK5wyXsYnM3mSmivdaGZPNpZbmgQ2lWuRC56vPx9-tC7FUuX5iz0SH7BqpV0NWf7yWm5kwkMD1F6x5xL0NgoOvOSWMGAgdmmS_kafWBvpyTfC9g2SD56HhV6ezHhwHd-w9Ej_b1N6okJBGbNCAIxz_9Qubbta7cisimeoUbQexr_6vq3v8Bx00SSI</recordid><startdate>20230622</startdate><enddate>20230622</enddate><creator>Qin, Wenjie</creator><creator>Ni, Qian</creator><creator>Jiao, Wenjun</creator><creator>Ma, Yuanhong</creator><scope/></search><sort><creationdate>20230622</creationdate><title>B(CF)-catalyzed regio- and stereoselective thiosulfonylation of terminal alkynes with thiosulfonates</title><author>Qin, Wenjie ; Ni, Qian ; Jiao, Wenjun ; Ma, Yuanhong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_d3cc02151c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><creationdate>2023</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Qin, Wenjie</creatorcontrib><creatorcontrib>Ni, Qian</creatorcontrib><creatorcontrib>Jiao, Wenjun</creatorcontrib><creatorcontrib>Ma, Yuanhong</creatorcontrib><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Qin, Wenjie</au><au>Ni, Qian</au><au>Jiao, Wenjun</au><au>Ma, Yuanhong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>B(CF)-catalyzed regio- and stereoselective thiosulfonylation of terminal alkynes with thiosulfonates</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><date>2023-06-22</date><risdate>2023</risdate><volume>59</volume><issue>51</issue><spage>7951</spage><epage>7954</epage><pages>7951-7954</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>Herein, a metal-free main-group catalysis system for thiosulfonylation of terminal alkynes with thiosulfonates has been established by using commercially available B(C
6
F
5
)
3
as a catalyst. The protocol provides a highly regio- and stereoselective route for the synthesis of diverse (
E
)-(β)-arylthiolvinyl sulfones under mild conditions with 100% atom-economy and exceptional functional group compatibility.
Herein, we report a B(C
6
F
5
)
3
-catalyzed highly regio- and stereoselective thiosulfonylation of terminal alkynes with thiosulfonates to access diverse (
E
)-(β)-arylthiolvinyl sulfones.</abstract><doi>10.1039/d3cc02151c</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2023-06, Vol.59 (51), p.7951-7954 |
| issn | 1359-7345 1364-548X |
| language | |
| recordid | cdi_rsc_primary_d3cc02151c |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | B(CF)-catalyzed regio- and stereoselective thiosulfonylation of terminal alkynes with thiosulfonates |
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